Cobalt (II), nickel (II), copper (II) and zinc (II) complexes of 1-(phenyl(phenylamino) methyl)pyrrolidine-2,5-dione and 2-((phenylamino)methyl) isoindoline-1,3-dione and their biological activity

Detalhes bibliográficos
Autor(a) principal: Vendan, D. Tamil
Data de Publicação: 2010
Outros Autores: Rajeswari, S., Ilavenil, S., Prabhu, G. Venkatesa
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFMS
Texto Completo: https://repositorio.ufms.br/handle/123456789/5330
Resumo: The new Mannich bases 1-(phenyl(phenylamino)methyl)pyrrolidine-2,5- dione (SBA) was synthesized from the condensation of succinimide, benzaldehyde and aniline. 2-((phenylamino)methyl)isoindoline-1,3-dione (PFA) was derived from pthalimide, formaldehyde and aniline. The general formula of the Co(II), Ni(II), Cu(II) and Zn(II) chloro complexes, ML2X2 are reported. The ligands and the complexes have been characterized by various physical-chemical techniques such as elemental analysis, molar conductance, magnetic susceptibility measurements, infrared and electronic spectra. The spectral analysis to ascertain mode of bonding and overall geometry of the complexes revealed octahedral geometries.
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spelling 2022-10-28T14:39:56Z2022-10-28T14:39:56Z2010-12-021984-6428https://repositorio.ufms.br/handle/123456789/5330The new Mannich bases 1-(phenyl(phenylamino)methyl)pyrrolidine-2,5- dione (SBA) was synthesized from the condensation of succinimide, benzaldehyde and aniline. 2-((phenylamino)methyl)isoindoline-1,3-dione (PFA) was derived from pthalimide, formaldehyde and aniline. The general formula of the Co(II), Ni(II), Cu(II) and Zn(II) chloro complexes, ML2X2 are reported. The ligands and the complexes have been characterized by various physical-chemical techniques such as elemental analysis, molar conductance, magnetic susceptibility measurements, infrared and electronic spectra. The spectral analysis to ascertain mode of bonding and overall geometry of the complexes revealed octahedral geometries.engFundação Universidade Federal de Mato Grosso do SulBrasilOrbital: The Electronic Journal of ChemistryAttribution-NonCommercial-NoDerivs 3.0 Brazilhttp://creativecommons.org/licenses/by-nc-nd/3.0/br/info:eu-repo/semantics/openAccessCNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICABases de MannichComplexos de CoordenaçãoGeometria Molecular OctaédricaCoordination ComplexesMannich BasesOctahedral Molecular GeometryAminasAminesCobalt (II), nickel (II), copper (II) and zinc (II) complexes of 1-(phenyl(phenylamino) methyl)pyrrolidine-2,5-dione and 2-((phenylamino)methyl) isoindoline-1,3-dione and their biological activityinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleVendan, D. TamilRajeswari, S.Ilavenil, S.Prabhu, G. Venkatesareponame:Repositório Institucional da UFMSinstname:Universidade Federal de Mato Grosso do Sul (UFMS)instacron:UFMSLICENSElicense.txtlicense.txttext/plain; charset=utf-82031https://repositorio.ufms.br/bitstream/123456789/5330/3/license.txt9671aa5ac42cb06edaf75013367dfe04MD53CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8811https://repositorio.ufms.br/bitstream/123456789/5330/2/license_rdfe39d27027a6cc9cb039ad269a5db8e34MD52ORIGINALCobalt (II), nickel (II), copper (II) and zinc (II) complexes of 1-(phenyl(phenylamino) methyl)pyrrolidine-2,5-dione and 2-((phenylamino)methyl) isoindoline-1,3-dione and their biological activity.pdfCobalt (II), nickel (II), copper (II) and zinc (II) complexes of 1-(phenyl(phenylamino) methyl)pyrrolidine-2,5-dione and 2-((phenylamino)methyl) isoindoline-1,3-dione and their biological activity.pdfapplication/pdf309601https://repositorio.ufms.br/bitstream/123456789/5330/1/Cobalt%20%28II%29%2c%20nickel%20%28II%29%2c%20copper%20%28II%29%20and%20zinc%20%28II%29%20complexes%20of%201-%28phenyl%28phenylamino%29%20methyl%29pyrrolidine-2%2c5-dione%20and%202-%28%28phenylamino%29methyl%29%20isoindoline-1%2c3-dione%20and%20their%20biological%20activity.pdf25e010c50a458b597312056d06d7817bMD51123456789/53302022-10-28 10:43:58.725oai:repositorio.ufms.br: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ório InstitucionalPUBhttps://repositorio.ufms.br/oai/requestri.prograd@ufms.bropendoar:21242022-10-28T14:43:58Repositório Institucional da UFMS - Universidade Federal de Mato Grosso do Sul (UFMS)false
dc.title.pt_BR.fl_str_mv Cobalt (II), nickel (II), copper (II) and zinc (II) complexes of 1-(phenyl(phenylamino) methyl)pyrrolidine-2,5-dione and 2-((phenylamino)methyl) isoindoline-1,3-dione and their biological activity
title Cobalt (II), nickel (II), copper (II) and zinc (II) complexes of 1-(phenyl(phenylamino) methyl)pyrrolidine-2,5-dione and 2-((phenylamino)methyl) isoindoline-1,3-dione and their biological activity
spellingShingle Cobalt (II), nickel (II), copper (II) and zinc (II) complexes of 1-(phenyl(phenylamino) methyl)pyrrolidine-2,5-dione and 2-((phenylamino)methyl) isoindoline-1,3-dione and their biological activity
Vendan, D. Tamil
CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA
Bases de Mannich
Complexos de Coordenação
Geometria Molecular Octaédrica
Coordination Complexes
Mannich Bases
Octahedral Molecular Geometry
Aminas
Amines
title_short Cobalt (II), nickel (II), copper (II) and zinc (II) complexes of 1-(phenyl(phenylamino) methyl)pyrrolidine-2,5-dione and 2-((phenylamino)methyl) isoindoline-1,3-dione and their biological activity
title_full Cobalt (II), nickel (II), copper (II) and zinc (II) complexes of 1-(phenyl(phenylamino) methyl)pyrrolidine-2,5-dione and 2-((phenylamino)methyl) isoindoline-1,3-dione and their biological activity
title_fullStr Cobalt (II), nickel (II), copper (II) and zinc (II) complexes of 1-(phenyl(phenylamino) methyl)pyrrolidine-2,5-dione and 2-((phenylamino)methyl) isoindoline-1,3-dione and their biological activity
title_full_unstemmed Cobalt (II), nickel (II), copper (II) and zinc (II) complexes of 1-(phenyl(phenylamino) methyl)pyrrolidine-2,5-dione and 2-((phenylamino)methyl) isoindoline-1,3-dione and their biological activity
title_sort Cobalt (II), nickel (II), copper (II) and zinc (II) complexes of 1-(phenyl(phenylamino) methyl)pyrrolidine-2,5-dione and 2-((phenylamino)methyl) isoindoline-1,3-dione and their biological activity
author Vendan, D. Tamil
author_facet Vendan, D. Tamil
Rajeswari, S.
Ilavenil, S.
Prabhu, G. Venkatesa
author_role author
author2 Rajeswari, S.
Ilavenil, S.
Prabhu, G. Venkatesa
author2_role author
author
author
dc.contributor.author.fl_str_mv Vendan, D. Tamil
Rajeswari, S.
Ilavenil, S.
Prabhu, G. Venkatesa
dc.subject.cnpq.fl_str_mv CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA
topic CNPQ::CIENCIAS EXATAS E DA TERRA::QUIMICA
Bases de Mannich
Complexos de Coordenação
Geometria Molecular Octaédrica
Coordination Complexes
Mannich Bases
Octahedral Molecular Geometry
Aminas
Amines
dc.subject.por.fl_str_mv Bases de Mannich
Complexos de Coordenação
Geometria Molecular Octaédrica
Coordination Complexes
Mannich Bases
Octahedral Molecular Geometry
Aminas
Amines
description The new Mannich bases 1-(phenyl(phenylamino)methyl)pyrrolidine-2,5- dione (SBA) was synthesized from the condensation of succinimide, benzaldehyde and aniline. 2-((phenylamino)methyl)isoindoline-1,3-dione (PFA) was derived from pthalimide, formaldehyde and aniline. The general formula of the Co(II), Ni(II), Cu(II) and Zn(II) chloro complexes, ML2X2 are reported. The ligands and the complexes have been characterized by various physical-chemical techniques such as elemental analysis, molar conductance, magnetic susceptibility measurements, infrared and electronic spectra. The spectral analysis to ascertain mode of bonding and overall geometry of the complexes revealed octahedral geometries.
publishDate 2010
dc.date.issued.fl_str_mv 2010-12-02
dc.date.accessioned.fl_str_mv 2022-10-28T14:39:56Z
dc.date.available.fl_str_mv 2022-10-28T14:39:56Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://repositorio.ufms.br/handle/123456789/5330
dc.identifier.issn.pt_BR.fl_str_mv 1984-6428
identifier_str_mv 1984-6428
url https://repositorio.ufms.br/handle/123456789/5330
dc.language.iso.fl_str_mv eng
language eng
dc.relation.ispartof.pt_BR.fl_str_mv Orbital: The Electronic Journal of Chemistry
dc.rights.driver.fl_str_mv Attribution-NonCommercial-NoDerivs 3.0 Brazil
http://creativecommons.org/licenses/by-nc-nd/3.0/br/
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Attribution-NonCommercial-NoDerivs 3.0 Brazil
http://creativecommons.org/licenses/by-nc-nd/3.0/br/
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv Fundação Universidade Federal de Mato Grosso do Sul
dc.publisher.country.fl_str_mv Brasil
publisher.none.fl_str_mv Fundação Universidade Federal de Mato Grosso do Sul
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFMS
instname:Universidade Federal de Mato Grosso do Sul (UFMS)
instacron:UFMS
instname_str Universidade Federal de Mato Grosso do Sul (UFMS)
instacron_str UFMS
institution UFMS
reponame_str Repositório Institucional da UFMS
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