A vibrational spectroscopic study of the silicate mineral pectolite – NaCa2Si3O8(OH).

Detalhes bibliográficos
Autor(a) principal: Frost, Ray Leslie
Data de Publicação: 2015
Outros Autores: López, Andrés, Theiss, Frederick L., Romano, Antônio Wilson, Cipriano, Ricardo Augusto Scholz
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFOP
Texto Completo: http://www.repositorio.ufop.br/handle/123456789/6052
https://doi.org/10.1016/j.saa.2014.06.097
Resumo: The mineral pectolite NaCa2Si3O8(OH) is a crystalline sodium calcium silicate which has the potential to be used in plaster boards and in other industrial applications. Raman bands at 974 and 1026 cm 1 are assigned to the SiO stretching vibrations of linked units of Si3O8 units. Raman bands at 974 and 998 cm 1 serve to identify Si3O8 units. The broad Raman band at around 936 cm 1 is attributed to hydroxyl deformation modes. Intense Raman band at 653 cm 1 is assigned to OSiO bending vibration. Intense Raman bands in the 2700–3000 cm 1 spectral range are assigned to OH stretching vibrations of the OH units in pectolite. Infrared spectra are in harmony with the Raman spectra. Raman spectroscopy with complimentary infrared spectroscopy enables the characterisation of the silicate mineral pectolite.
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spelling A vibrational spectroscopic study of the silicate mineral pectolite – NaCa2Si3O8(OH).SilicateRaman spectroscopyPectoliteInfrared spectroscopyMolecular structureThe mineral pectolite NaCa2Si3O8(OH) is a crystalline sodium calcium silicate which has the potential to be used in plaster boards and in other industrial applications. Raman bands at 974 and 1026 cm 1 are assigned to the SiO stretching vibrations of linked units of Si3O8 units. Raman bands at 974 and 998 cm 1 serve to identify Si3O8 units. The broad Raman band at around 936 cm 1 is attributed to hydroxyl deformation modes. Intense Raman band at 653 cm 1 is assigned to OSiO bending vibration. Intense Raman bands in the 2700–3000 cm 1 spectral range are assigned to OH stretching vibrations of the OH units in pectolite. Infrared spectra are in harmony with the Raman spectra. Raman spectroscopy with complimentary infrared spectroscopy enables the characterisation of the silicate mineral pectolite.2016-01-14T18:22:17Z2016-01-14T18:22:17Z2015info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfFROST, R. L. et al. A vibrational spectroscopic study of the silicate mineral pectolite – NaCa2Si3O8(OH). Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, v. 134, p. 58-62, 2015. Disponível em: <http://www.sciencedirect.com/science/article/pii/S1386142514009962>. Acesso em: 08 set. 2015.1386-1425http://www.repositorio.ufop.br/handle/123456789/6052https://doi.org/10.1016/j.saa.2014.06.097O periódico Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença: 3727590371433.info:eu-repo/semantics/openAccessFrost, Ray LeslieLópez, AndrésTheiss, Frederick L.Romano, Antônio WilsonCipriano, Ricardo Augusto Scholzengreponame:Repositório Institucional da UFOPinstname:Universidade Federal de Ouro Preto (UFOP)instacron:UFOP2024-11-11T03:23:29Zoai:repositorio.ufop.br:123456789/6052Repositório InstitucionalPUBhttp://www.repositorio.ufop.br/oai/requestrepositorio@ufop.edu.bropendoar:32332024-11-11T03:23:29Repositório Institucional da UFOP - Universidade Federal de Ouro Preto (UFOP)false
dc.title.none.fl_str_mv A vibrational spectroscopic study of the silicate mineral pectolite – NaCa2Si3O8(OH).
title A vibrational spectroscopic study of the silicate mineral pectolite – NaCa2Si3O8(OH).
spellingShingle A vibrational spectroscopic study of the silicate mineral pectolite – NaCa2Si3O8(OH).
Frost, Ray Leslie
Silicate
Raman spectroscopy
Pectolite
Infrared spectroscopy
Molecular structure
title_short A vibrational spectroscopic study of the silicate mineral pectolite – NaCa2Si3O8(OH).
title_full A vibrational spectroscopic study of the silicate mineral pectolite – NaCa2Si3O8(OH).
title_fullStr A vibrational spectroscopic study of the silicate mineral pectolite – NaCa2Si3O8(OH).
title_full_unstemmed A vibrational spectroscopic study of the silicate mineral pectolite – NaCa2Si3O8(OH).
title_sort A vibrational spectroscopic study of the silicate mineral pectolite – NaCa2Si3O8(OH).
author Frost, Ray Leslie
author_facet Frost, Ray Leslie
López, Andrés
Theiss, Frederick L.
Romano, Antônio Wilson
Cipriano, Ricardo Augusto Scholz
author_role author
author2 López, Andrés
Theiss, Frederick L.
Romano, Antônio Wilson
Cipriano, Ricardo Augusto Scholz
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Frost, Ray Leslie
López, Andrés
Theiss, Frederick L.
Romano, Antônio Wilson
Cipriano, Ricardo Augusto Scholz
dc.subject.por.fl_str_mv Silicate
Raman spectroscopy
Pectolite
Infrared spectroscopy
Molecular structure
topic Silicate
Raman spectroscopy
Pectolite
Infrared spectroscopy
Molecular structure
description The mineral pectolite NaCa2Si3O8(OH) is a crystalline sodium calcium silicate which has the potential to be used in plaster boards and in other industrial applications. Raman bands at 974 and 1026 cm 1 are assigned to the SiO stretching vibrations of linked units of Si3O8 units. Raman bands at 974 and 998 cm 1 serve to identify Si3O8 units. The broad Raman band at around 936 cm 1 is attributed to hydroxyl deformation modes. Intense Raman band at 653 cm 1 is assigned to OSiO bending vibration. Intense Raman bands in the 2700–3000 cm 1 spectral range are assigned to OH stretching vibrations of the OH units in pectolite. Infrared spectra are in harmony with the Raman spectra. Raman spectroscopy with complimentary infrared spectroscopy enables the characterisation of the silicate mineral pectolite.
publishDate 2015
dc.date.none.fl_str_mv 2015
2016-01-14T18:22:17Z
2016-01-14T18:22:17Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv FROST, R. L. et al. A vibrational spectroscopic study of the silicate mineral pectolite – NaCa2Si3O8(OH). Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, v. 134, p. 58-62, 2015. Disponível em: <http://www.sciencedirect.com/science/article/pii/S1386142514009962>. Acesso em: 08 set. 2015.
1386-1425
http://www.repositorio.ufop.br/handle/123456789/6052
https://doi.org/10.1016/j.saa.2014.06.097
identifier_str_mv FROST, R. L. et al. A vibrational spectroscopic study of the silicate mineral pectolite – NaCa2Si3O8(OH). Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, v. 134, p. 58-62, 2015. Disponível em: <http://www.sciencedirect.com/science/article/pii/S1386142514009962>. Acesso em: 08 set. 2015.
1386-1425
url http://www.repositorio.ufop.br/handle/123456789/6052
https://doi.org/10.1016/j.saa.2014.06.097
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFOP
instname:Universidade Federal de Ouro Preto (UFOP)
instacron:UFOP
instname_str Universidade Federal de Ouro Preto (UFOP)
instacron_str UFOP
institution UFOP
reponame_str Repositório Institucional da UFOP
collection Repositório Institucional da UFOP
repository.name.fl_str_mv Repositório Institucional da UFOP - Universidade Federal de Ouro Preto (UFOP)
repository.mail.fl_str_mv repositorio@ufop.edu.br
_version_ 1823329463477207040

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