A vibrational spectroscopic study of the copper bearing silicate mineral luddenite.

Detalhes bibliográficos
Autor(a) principal: Frost, Ray Leslie
Data de Publicação: 2015
Outros Autores: López, Andrés, Xi, Yunfei, Cipriano, Ricardo Augusto Scholz
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFOP
Texto Completo: http://www.repositorio.ufop.br/handle/123456789/6051
https://doi.org/10.1016/j.saa.2014.08.026
Resumo: The molecular structure of the copper–lead silicate mineral luddenite has been analysed using vibrational spectroscopy. The mineral is only one of many silicate minerals containing copper. The intense Raman band at 978 cm 1 is assigned to the m1 (A1g) symmetric stretching vibration of Si5O14 units. Raman bands at 1122, 1148 and 1160 cm 1 are attributed to the m3 SiO4 antisymmetric stretching vibrations. The bands in the 678–799 cm 1 are assigned to OSiO bending modes of the (SiO3)n chains. Raman bands at 3317 and 3329 cm 1 are attributed to water stretching bands. Bands at 3595 and 3629 cm 1 are associated with the stretching vibrations of hydroxyl units suggesting that hydroxyl units exist in the structure of luddenite.
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spelling A vibrational spectroscopic study of the copper bearing silicate mineral luddenite.LuddeniteCopper silicateRaman spectroscopyInfrared spectroscopyThe molecular structure of the copper–lead silicate mineral luddenite has been analysed using vibrational spectroscopy. The mineral is only one of many silicate minerals containing copper. The intense Raman band at 978 cm 1 is assigned to the m1 (A1g) symmetric stretching vibration of Si5O14 units. Raman bands at 1122, 1148 and 1160 cm 1 are attributed to the m3 SiO4 antisymmetric stretching vibrations. The bands in the 678–799 cm 1 are assigned to OSiO bending modes of the (SiO3)n chains. Raman bands at 3317 and 3329 cm 1 are attributed to water stretching bands. Bands at 3595 and 3629 cm 1 are associated with the stretching vibrations of hydroxyl units suggesting that hydroxyl units exist in the structure of luddenite.2016-01-14T18:20:50Z2016-01-14T18:20:50Z2015info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfFROST, R. L. et al. A vibrational spectroscopic study of the copper bearing silicate mineral luddenite. Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, v. 137, p. 717-720, 2015. Disponível em: <http://www.sciencedirect.com/science/article/pii/S1386142514012177>. Acesso em: 08 set. 2015.1386-1425http://www.repositorio.ufop.br/handle/123456789/6051https://doi.org/10.1016/j.saa.2014.08.026O periódico Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy concede permissão para depósito deste artigo no Repositório Institucional da UFOP. Número da licença: 3727590247685.info:eu-repo/semantics/openAccessFrost, Ray LeslieLópez, AndrésXi, YunfeiCipriano, Ricardo Augusto Scholzengreponame:Repositório Institucional da UFOPinstname:Universidade Federal de Ouro Preto (UFOP)instacron:UFOP2019-08-26T15:11:23Zoai:repositorio.ufop.br:123456789/6051Repositório InstitucionalPUBhttp://www.repositorio.ufop.br/oai/requestrepositorio@ufop.edu.bropendoar:32332019-08-26T15:11:23Repositório Institucional da UFOP - Universidade Federal de Ouro Preto (UFOP)false
dc.title.none.fl_str_mv A vibrational spectroscopic study of the copper bearing silicate mineral luddenite.
title A vibrational spectroscopic study of the copper bearing silicate mineral luddenite.
spellingShingle A vibrational spectroscopic study of the copper bearing silicate mineral luddenite.
Frost, Ray Leslie
Luddenite
Copper silicate
Raman spectroscopy
Infrared spectroscopy
title_short A vibrational spectroscopic study of the copper bearing silicate mineral luddenite.
title_full A vibrational spectroscopic study of the copper bearing silicate mineral luddenite.
title_fullStr A vibrational spectroscopic study of the copper bearing silicate mineral luddenite.
title_full_unstemmed A vibrational spectroscopic study of the copper bearing silicate mineral luddenite.
title_sort A vibrational spectroscopic study of the copper bearing silicate mineral luddenite.
author Frost, Ray Leslie
author_facet Frost, Ray Leslie
López, Andrés
Xi, Yunfei
Cipriano, Ricardo Augusto Scholz
author_role author
author2 López, Andrés
Xi, Yunfei
Cipriano, Ricardo Augusto Scholz
author2_role author
author
author
dc.contributor.author.fl_str_mv Frost, Ray Leslie
López, Andrés
Xi, Yunfei
Cipriano, Ricardo Augusto Scholz
dc.subject.por.fl_str_mv Luddenite
Copper silicate
Raman spectroscopy
Infrared spectroscopy
topic Luddenite
Copper silicate
Raman spectroscopy
Infrared spectroscopy
description The molecular structure of the copper–lead silicate mineral luddenite has been analysed using vibrational spectroscopy. The mineral is only one of many silicate minerals containing copper. The intense Raman band at 978 cm 1 is assigned to the m1 (A1g) symmetric stretching vibration of Si5O14 units. Raman bands at 1122, 1148 and 1160 cm 1 are attributed to the m3 SiO4 antisymmetric stretching vibrations. The bands in the 678–799 cm 1 are assigned to OSiO bending modes of the (SiO3)n chains. Raman bands at 3317 and 3329 cm 1 are attributed to water stretching bands. Bands at 3595 and 3629 cm 1 are associated with the stretching vibrations of hydroxyl units suggesting that hydroxyl units exist in the structure of luddenite.
publishDate 2015
dc.date.none.fl_str_mv 2015
2016-01-14T18:20:50Z
2016-01-14T18:20:50Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv FROST, R. L. et al. A vibrational spectroscopic study of the copper bearing silicate mineral luddenite. Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, v. 137, p. 717-720, 2015. Disponível em: <http://www.sciencedirect.com/science/article/pii/S1386142514012177>. Acesso em: 08 set. 2015.
1386-1425
http://www.repositorio.ufop.br/handle/123456789/6051
https://doi.org/10.1016/j.saa.2014.08.026
identifier_str_mv FROST, R. L. et al. A vibrational spectroscopic study of the copper bearing silicate mineral luddenite. Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, v. 137, p. 717-720, 2015. Disponível em: <http://www.sciencedirect.com/science/article/pii/S1386142514012177>. Acesso em: 08 set. 2015.
1386-1425
url http://www.repositorio.ufop.br/handle/123456789/6051
https://doi.org/10.1016/j.saa.2014.08.026
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFOP
instname:Universidade Federal de Ouro Preto (UFOP)
instacron:UFOP
instname_str Universidade Federal de Ouro Preto (UFOP)
instacron_str UFOP
institution UFOP
reponame_str Repositório Institucional da UFOP
collection Repositório Institucional da UFOP
repository.name.fl_str_mv Repositório Institucional da UFOP - Universidade Federal de Ouro Preto (UFOP)
repository.mail.fl_str_mv repositorio@ufop.edu.br
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