Amido modificado de taro (Colocasia esculenta L. Schott): propriedades funcionais

Detalhes bibliográficos
Autor(a) principal: Almeida, Elisândra Costa
Data de Publicação: 2012
Tipo de documento: Tese
Idioma: por
Título da fonte: Biblioteca Digital de Teses e Dissertações da UFPB
Texto Completo: https://repositorio.ufpb.br/jspui/handle/tede/4029
Resumo: Taro has economic and industrial potential to justify investment in this culture because it is a food with excellent nutritional quality, especially starch, important source of energy, frequently used in the food industry, particularly as gelling and thickening agent, applied in the development of several products. However the starch in its native form has limitations for use, requiring modifications to improve its functional properties and increasing its possibilities for use in the food industry. The objective of this research was to study and compare the properties of native starch extract from taro (Colocasia esculenta L. Schott) clone Macaquinho with its modified starch by oxidation, acid hydrolysis, succinylation, intercross and combination of hydrolysis, succinylation and intercross for use in the food industry. After extraction of the starch, it was modified by oxidation using sodium hypochlorite, hydrolysis with hydrochloric acid, succinylation with succinic anhydride and intercrossing with trimetaphosphate and sodium tripolyphosphate. According to the experiments, it was verified that the native starch extracted from Macaquinho clone contains considerable percentage of starch, low amount of substances contaminants, like proteins or lipids, without influences on the functional properties. After the modifications and combinations occurred in the native starch, they did not showed degree of substitution beyond that permitted by regulatory agencies, being in accordance with Brazilian law. The addition of the substituent groups was decisive in the characterization of the functional properties of taro starch, modified and combined. Microscopy revealed that the starch granules presented circular and polyhedral shapes. The hydrolyzed, succinylated and intercrossed starches suffered major visible alterations in their morphology due to the modifications conducted. The swelling of the granules occurred above 75oC, with prominence for the native, oxidized, succinylated and intercrossed starches, which had their swelling power increased with the increase of temperature. The highest solubility was observed in hydrolyzed starches. The higher water absorption capacity was verified in intercrossed starch and the hydrolyzed starches demonstrated higher oil absorption and paste clarity. The best paste properties were obtained to the oxidized starch, followed by native and succinylated starches, with maximum viscosity at low temperatures. However, the oxidized starch showed higher retrogradation tendency, differently from hydrolyzed starches, more stables. The functional profiles noted in native, modified and combined starches of taro were variables, which provide a lot of possibilities for their use in the food industry.
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spelling Amido modificado de taro (Colocasia esculenta L. Schott): propriedades funcionaisAmido modificadoColocasia esculentaPropriedades funcionaisModified starchColocasia esculentaFunctional propertiesCIENCIA E TECNOLOGIA DE ALIMENTOS::TECNOLOGIA DE ALIMENTOSTaro has economic and industrial potential to justify investment in this culture because it is a food with excellent nutritional quality, especially starch, important source of energy, frequently used in the food industry, particularly as gelling and thickening agent, applied in the development of several products. However the starch in its native form has limitations for use, requiring modifications to improve its functional properties and increasing its possibilities for use in the food industry. The objective of this research was to study and compare the properties of native starch extract from taro (Colocasia esculenta L. Schott) clone Macaquinho with its modified starch by oxidation, acid hydrolysis, succinylation, intercross and combination of hydrolysis, succinylation and intercross for use in the food industry. After extraction of the starch, it was modified by oxidation using sodium hypochlorite, hydrolysis with hydrochloric acid, succinylation with succinic anhydride and intercrossing with trimetaphosphate and sodium tripolyphosphate. According to the experiments, it was verified that the native starch extracted from Macaquinho clone contains considerable percentage of starch, low amount of substances contaminants, like proteins or lipids, without influences on the functional properties. After the modifications and combinations occurred in the native starch, they did not showed degree of substitution beyond that permitted by regulatory agencies, being in accordance with Brazilian law. The addition of the substituent groups was decisive in the characterization of the functional properties of taro starch, modified and combined. Microscopy revealed that the starch granules presented circular and polyhedral shapes. The hydrolyzed, succinylated and intercrossed starches suffered major visible alterations in their morphology due to the modifications conducted. The swelling of the granules occurred above 75oC, with prominence for the native, oxidized, succinylated and intercrossed starches, which had their swelling power increased with the increase of temperature. The highest solubility was observed in hydrolyzed starches. The higher water absorption capacity was verified in intercrossed starch and the hydrolyzed starches demonstrated higher oil absorption and paste clarity. The best paste properties were obtained to the oxidized starch, followed by native and succinylated starches, with maximum viscosity at low temperatures. However, the oxidized starch showed higher retrogradation tendency, differently from hydrolyzed starches, more stables. The functional profiles noted in native, modified and combined starches of taro were variables, which provide a lot of possibilities for their use in the food industry.Coordenação de Aperfeiçoamento de Pessoal de Nível Superior - CAPESO taro apresenta potencialidades econômicas e industriais que justificam investimentos nesta cultura, pois se trata de um alimento com excelente qualidade nutricional, especialmente em amido, importante fonte energética, muito utilizado na indústria de alimentos, especialmente como agente espessante e gelificante, aplicado no desenvolvimento de inúmeros produtos. Porém o amido na sua forma nativa apresenta limitações de uso, sendo necessária sua modificação, visando a melhoria das suas propriedades funcionais e aumentando as possibilidades de utilização na indústria alimentícia. O objetivo desta pesquisa foi estudar e comparar as propriedades do amido nativo de taro (Colocasia esculenta L. Schott) clone Macaquinho com o seu amido modificado por oxidação, hidrólise ácida, succinilação, intercruzamento, e por combinação da hidrólise com succinilação e intercruzamento para utilização na indústria alimentícia. Após a extração do amido, este foi modificado por oxidação utilizando o hipoclorito de sódio, hidrólise com ácido clorídrico, succinilação com anidrido succínico e intercruzamento com trimetafosfato e tripolifosfato de sódio. Com base nos experimentos realizados constatou-se que o extrato amiláceo nativo do clone Macaquinho contém considerável percentual de amido, com baixo teor de substâncias consideradas contaminantes, não influenciando nas suas propriedades funcionais. Após as modificações e combinações conduzidas no amido nativo, os mesmos não apresentaram grau de substituição além do permitido pelos órgãos reguladores, estando em conformidade com a legislação brasileira. A inclusão dos grupos substituintes foi determinante na caracterização das propriedades funcionais do amido de taro, modificados e combinados. A microscopia revelou que os amidos apresentavam grânulos com formatos circulares e poliédricos. Os amidos hidrolisados, succinilados e intercruzados, sofreram maiores alterações visíveis em sua morfologia, devido às modificações conduzidas. O intumescimento dos grânulos ocorreu acima de 75ºC, com destaque para os amidos nativo, oxidado, succinilado e intercruzado, que tiveram seu poder de inchamento aumentado com a elevação da temperatura. Os maiores perfis de solubilidade foram constatados nos amidos hidrolisados. A maior capacidade de absorção de água foi observada nos amidos intercruzados e a absorção de óleo foi mais evidenciada nos amidos hidrolisados, que também apresentaram maior claridade da pasta. As melhores propriedades de pasta foram obtidas no amido oxidado, seguido dos amidos nativo e succinilado, com viscosidades máximas em temperaturas mais baixas. Porém o amido oxidado apresentou maior tendência à retrogradação, diferentemente dos amidos hidrolisados com pastas mais estáveis. Os perfis funcionais constatados nos amidos nativo, modificados e combinados de taro foram variáveis, o que propicia uma série de possibilidades para a sua utilização na indústria alimentícia.Universidade Federal da Paraí­baBrasilQuímica e Bioquímica de AlimentosPrograma de Pós-Graduação em Ciência e Tecnologia de AlimentosUFPBBora, Pushkar Singhhttp://lattes.cnpq.br/0307847946305802Almeida, Elisândra Costa2015-04-17T14:49:19Z2018-07-20T23:42:09Z2012-05-182018-07-20T23:42:09Z2012-04-20info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/doctoralThesisapplication/pdfALMEIDA, Elisândra Costa. Amido modificado de taro (Colocasia esculenta L. Schott): propriedades funcionais. 2012. 144 f. Tese (Doutorado em Ciência e Tecnologia de Alimentos) - Universidade Federal da Paraí­ba, João Pessoa, 2012.https://repositorio.ufpb.br/jspui/handle/tede/4029porinfo:eu-repo/semantics/openAccessreponame:Biblioteca Digital de Teses e Dissertações da UFPBinstname:Universidade Federal da Paraíba (UFPB)instacron:UFPB2018-09-05T23:57:00Zoai:repositorio.ufpb.br:tede/4029Biblioteca Digital de Teses e Dissertaçõeshttps://repositorio.ufpb.br/PUBhttp://tede.biblioteca.ufpb.br:8080/oai/requestdiretoria@ufpb.br|| diretoria@ufpb.bropendoar:2018-09-05T23:57Biblioteca Digital de Teses e Dissertações da UFPB - Universidade Federal da Paraíba (UFPB)false
dc.title.none.fl_str_mv Amido modificado de taro (Colocasia esculenta L. Schott): propriedades funcionais
title Amido modificado de taro (Colocasia esculenta L. Schott): propriedades funcionais
spellingShingle Amido modificado de taro (Colocasia esculenta L. Schott): propriedades funcionais
Almeida, Elisândra Costa
Amido modificado
Colocasia esculenta
Propriedades funcionais
Modified starch
Colocasia esculenta
Functional properties
CIENCIA E TECNOLOGIA DE ALIMENTOS::TECNOLOGIA DE ALIMENTOS
title_short Amido modificado de taro (Colocasia esculenta L. Schott): propriedades funcionais
title_full Amido modificado de taro (Colocasia esculenta L. Schott): propriedades funcionais
title_fullStr Amido modificado de taro (Colocasia esculenta L. Schott): propriedades funcionais
title_full_unstemmed Amido modificado de taro (Colocasia esculenta L. Schott): propriedades funcionais
title_sort Amido modificado de taro (Colocasia esculenta L. Schott): propriedades funcionais
author Almeida, Elisândra Costa
author_facet Almeida, Elisândra Costa
author_role author
dc.contributor.none.fl_str_mv Bora, Pushkar Singh
http://lattes.cnpq.br/0307847946305802
dc.contributor.author.fl_str_mv Almeida, Elisândra Costa
dc.subject.por.fl_str_mv Amido modificado
Colocasia esculenta
Propriedades funcionais
Modified starch
Colocasia esculenta
Functional properties
CIENCIA E TECNOLOGIA DE ALIMENTOS::TECNOLOGIA DE ALIMENTOS
topic Amido modificado
Colocasia esculenta
Propriedades funcionais
Modified starch
Colocasia esculenta
Functional properties
CIENCIA E TECNOLOGIA DE ALIMENTOS::TECNOLOGIA DE ALIMENTOS
description Taro has economic and industrial potential to justify investment in this culture because it is a food with excellent nutritional quality, especially starch, important source of energy, frequently used in the food industry, particularly as gelling and thickening agent, applied in the development of several products. However the starch in its native form has limitations for use, requiring modifications to improve its functional properties and increasing its possibilities for use in the food industry. The objective of this research was to study and compare the properties of native starch extract from taro (Colocasia esculenta L. Schott) clone Macaquinho with its modified starch by oxidation, acid hydrolysis, succinylation, intercross and combination of hydrolysis, succinylation and intercross for use in the food industry. After extraction of the starch, it was modified by oxidation using sodium hypochlorite, hydrolysis with hydrochloric acid, succinylation with succinic anhydride and intercrossing with trimetaphosphate and sodium tripolyphosphate. According to the experiments, it was verified that the native starch extracted from Macaquinho clone contains considerable percentage of starch, low amount of substances contaminants, like proteins or lipids, without influences on the functional properties. After the modifications and combinations occurred in the native starch, they did not showed degree of substitution beyond that permitted by regulatory agencies, being in accordance with Brazilian law. The addition of the substituent groups was decisive in the characterization of the functional properties of taro starch, modified and combined. Microscopy revealed that the starch granules presented circular and polyhedral shapes. The hydrolyzed, succinylated and intercrossed starches suffered major visible alterations in their morphology due to the modifications conducted. The swelling of the granules occurred above 75oC, with prominence for the native, oxidized, succinylated and intercrossed starches, which had their swelling power increased with the increase of temperature. The highest solubility was observed in hydrolyzed starches. The higher water absorption capacity was verified in intercrossed starch and the hydrolyzed starches demonstrated higher oil absorption and paste clarity. The best paste properties were obtained to the oxidized starch, followed by native and succinylated starches, with maximum viscosity at low temperatures. However, the oxidized starch showed higher retrogradation tendency, differently from hydrolyzed starches, more stables. The functional profiles noted in native, modified and combined starches of taro were variables, which provide a lot of possibilities for their use in the food industry.
publishDate 2012
dc.date.none.fl_str_mv 2012-05-18
2012-04-20
2015-04-17T14:49:19Z
2018-07-20T23:42:09Z
2018-07-20T23:42:09Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/doctoralThesis
format doctoralThesis
status_str publishedVersion
dc.identifier.uri.fl_str_mv ALMEIDA, Elisândra Costa. Amido modificado de taro (Colocasia esculenta L. Schott): propriedades funcionais. 2012. 144 f. Tese (Doutorado em Ciência e Tecnologia de Alimentos) - Universidade Federal da Paraí­ba, João Pessoa, 2012.
https://repositorio.ufpb.br/jspui/handle/tede/4029
identifier_str_mv ALMEIDA, Elisândra Costa. Amido modificado de taro (Colocasia esculenta L. Schott): propriedades funcionais. 2012. 144 f. Tese (Doutorado em Ciência e Tecnologia de Alimentos) - Universidade Federal da Paraí­ba, João Pessoa, 2012.
url https://repositorio.ufpb.br/jspui/handle/tede/4029
dc.language.iso.fl_str_mv por
language por
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Federal da Paraí­ba
Brasil
Química e Bioquímica de Alimentos
Programa de Pós-Graduação em Ciência e Tecnologia de Alimentos
UFPB
publisher.none.fl_str_mv Universidade Federal da Paraí­ba
Brasil
Química e Bioquímica de Alimentos
Programa de Pós-Graduação em Ciência e Tecnologia de Alimentos
UFPB
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reponame_str Biblioteca Digital de Teses e Dissertações da UFPB
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repository.name.fl_str_mv Biblioteca Digital de Teses e Dissertações da UFPB - Universidade Federal da Paraíba (UFPB)
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