Thermal processes for lead removal from the funnel glass of CRT monitors

• Autor(a) principal: Veit, Hugo Marcelo
• Data de Publicação: 2015
• Outros Autores: Oliveira, Erich Lopes Braitback de, Richter, Guilherme Muller
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Institucional da UFRGS
• Texto Completo: http://hdl.handle.net/10183/129448
• topic: Chumbo; Reciclagem; Lixo eletrônico; Meio ambiente; Lead removal; CRT monitors; Electrical waste; Eelectronic equipment

The disposal of CRT monitors increases each year, generating millions of tons of waste containing various types of materials. The glass present in CRT tubes displayed about 20%–25% of lead oxide. If improperly disposed of, this glass can be leached directly in nature or may cause environmental contamination, especially with lead. Because of this leaching possibility, this waste is classified as Class I solid waste, according to the NBR 10004. Thermal processing of these glass tubes was seen as an alternative to remove lead from the glass matrix. Parameters such as reaction time, percentage of reducing agent, the reaction temperature, and atmospheric environment of the system were analyzed in this work. It was concluded that it is possible to remove the lead from the glass matrix by thermal processing. The removal of 92% of the lead from the glass was obtained at 800°C, a vacuum of 1.3 kPa, with 5% carbon as a reducing agent, and 18 hours of thermal processing.