Influence of the morphology and viscoelasticity on the thermomechanical properties of poly(lactic acid)/thermoplastic polyurethane blends compatibilized with ethylene‐ester copolymer
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRGS |
Texto Completo: | http://hdl.handle.net/10183/219768 |
Resumo: | Viscoelastic, interfacial properties, and morphological data were employed to predict the thermal and mechanical properties of compatibilized poly(lactic acid) (PLA)/thermoplastic polyurethane (TPU) blends. The combination of interfacial thickness measured by contact angle and entanglement density determined by dynamical mechanical analysis analyze data was employed to evaluate the mechanical behavior of PLA/TPU blends with and without ethylene‐butyl acrylate‐glycidyl methacrylate (EBG) compatibilization agent. The PLA/TPU blend (70/30 wt %) was prepared in a Haake internal mixer at 190 °C and compatibilized with different contents of EBG. The evaluation of the interfacial properties revealed an increase in the interfacial layer thickness of the PLA/TPU blend with EBG. The scanning electronic microscopy images showed a drastic reduction in the size of the dispersed phase by increasing the compatibilizer agent EBG content in the blend. The compatibilization of the PLA/TPU blends improved both the Izod impact strength and yield stress by 38 and 33%, respectively, in comparison with neat PLA/TPU blend. The addition of EBG into PLA/TPU blends significantly increased the entanglement density and the PLA toughening but resulted in a decrease of PLA deformation at break. The PLA and TPU glass transitions were affected by the EBG, suggesting that the PLA and TPU domains were partially miscible. |
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Bernardes, Giordano PierozanLuiz, Nathalia da RosaSantana, Ruth Marlene CampomanesForte, Maria Madalena de Camargo2021-04-09T04:25:42Z20200021-8995http://hdl.handle.net/10183/219768001123821Viscoelastic, interfacial properties, and morphological data were employed to predict the thermal and mechanical properties of compatibilized poly(lactic acid) (PLA)/thermoplastic polyurethane (TPU) blends. The combination of interfacial thickness measured by contact angle and entanglement density determined by dynamical mechanical analysis analyze data was employed to evaluate the mechanical behavior of PLA/TPU blends with and without ethylene‐butyl acrylate‐glycidyl methacrylate (EBG) compatibilization agent. The PLA/TPU blend (70/30 wt %) was prepared in a Haake internal mixer at 190 °C and compatibilized with different contents of EBG. The evaluation of the interfacial properties revealed an increase in the interfacial layer thickness of the PLA/TPU blend with EBG. The scanning electronic microscopy images showed a drastic reduction in the size of the dispersed phase by increasing the compatibilizer agent EBG content in the blend. The compatibilization of the PLA/TPU blends improved both the Izod impact strength and yield stress by 38 and 33%, respectively, in comparison with neat PLA/TPU blend. The addition of EBG into PLA/TPU blends significantly increased the entanglement density and the PLA toughening but resulted in a decrease of PLA deformation at break. The PLA and TPU glass transitions were affected by the EBG, suggesting that the PLA and TPU domains were partially miscible.application/pdfengJournal of applied polymer science. New York. Vol. 137, n. 31 (2020), [Article] 48926, p. 1-11BlendasPoli(ácido lático)PoliuretanosPropriedades dos materiaisBiodegradableElastomersMorphologySurfaces and interfacesStructure–property relationshipsInfluence of the morphology and viscoelasticity on the thermomechanical properties of poly(lactic acid)/thermoplastic polyurethane blends compatibilized with ethylene‐ester copolymerEstrangeiroinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFRGSinstname:Universidade Federal do Rio Grande do Sul (UFRGS)instacron:UFRGSTEXT001123821.pdf.txt001123821.pdf.txtExtracted Texttext/plain52130http://www.lume.ufrgs.br/bitstream/10183/219768/2/001123821.pdf.txt9255dc34eba04b70214e07f920d44317MD52ORIGINAL001123821.pdfTexto completo (inglês)application/pdf1626042http://www.lume.ufrgs.br/bitstream/10183/219768/1/001123821.pdf3a324edc2d13623873fd56b35a08771bMD5110183/2197682021-05-07 05:14:10.479445oai:www.lume.ufrgs.br:10183/219768Repositório de PublicaçõesPUBhttps://lume.ufrgs.br/oai/requestopendoar:2021-05-07T08:14:10Repositório Institucional da UFRGS - Universidade Federal do Rio Grande do Sul (UFRGS)false |
dc.title.pt_BR.fl_str_mv |
Influence of the morphology and viscoelasticity on the thermomechanical properties of poly(lactic acid)/thermoplastic polyurethane blends compatibilized with ethylene‐ester copolymer |
title |
Influence of the morphology and viscoelasticity on the thermomechanical properties of poly(lactic acid)/thermoplastic polyurethane blends compatibilized with ethylene‐ester copolymer |
spellingShingle |
Influence of the morphology and viscoelasticity on the thermomechanical properties of poly(lactic acid)/thermoplastic polyurethane blends compatibilized with ethylene‐ester copolymer Bernardes, Giordano Pierozan Blendas Poli(ácido lático) Poliuretanos Propriedades dos materiais Biodegradable Elastomers Morphology Surfaces and interfaces Structure–property relationships |
title_short |
Influence of the morphology and viscoelasticity on the thermomechanical properties of poly(lactic acid)/thermoplastic polyurethane blends compatibilized with ethylene‐ester copolymer |
title_full |
Influence of the morphology and viscoelasticity on the thermomechanical properties of poly(lactic acid)/thermoplastic polyurethane blends compatibilized with ethylene‐ester copolymer |
title_fullStr |
Influence of the morphology and viscoelasticity on the thermomechanical properties of poly(lactic acid)/thermoplastic polyurethane blends compatibilized with ethylene‐ester copolymer |
title_full_unstemmed |
Influence of the morphology and viscoelasticity on the thermomechanical properties of poly(lactic acid)/thermoplastic polyurethane blends compatibilized with ethylene‐ester copolymer |
title_sort |
Influence of the morphology and viscoelasticity on the thermomechanical properties of poly(lactic acid)/thermoplastic polyurethane blends compatibilized with ethylene‐ester copolymer |
author |
Bernardes, Giordano Pierozan |
author_facet |
Bernardes, Giordano Pierozan Luiz, Nathalia da Rosa Santana, Ruth Marlene Campomanes Forte, Maria Madalena de Camargo |
author_role |
author |
author2 |
Luiz, Nathalia da Rosa Santana, Ruth Marlene Campomanes Forte, Maria Madalena de Camargo |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Bernardes, Giordano Pierozan Luiz, Nathalia da Rosa Santana, Ruth Marlene Campomanes Forte, Maria Madalena de Camargo |
dc.subject.por.fl_str_mv |
Blendas Poli(ácido lático) Poliuretanos Propriedades dos materiais |
topic |
Blendas Poli(ácido lático) Poliuretanos Propriedades dos materiais Biodegradable Elastomers Morphology Surfaces and interfaces Structure–property relationships |
dc.subject.eng.fl_str_mv |
Biodegradable Elastomers Morphology Surfaces and interfaces Structure–property relationships |
description |
Viscoelastic, interfacial properties, and morphological data were employed to predict the thermal and mechanical properties of compatibilized poly(lactic acid) (PLA)/thermoplastic polyurethane (TPU) blends. The combination of interfacial thickness measured by contact angle and entanglement density determined by dynamical mechanical analysis analyze data was employed to evaluate the mechanical behavior of PLA/TPU blends with and without ethylene‐butyl acrylate‐glycidyl methacrylate (EBG) compatibilization agent. The PLA/TPU blend (70/30 wt %) was prepared in a Haake internal mixer at 190 °C and compatibilized with different contents of EBG. The evaluation of the interfacial properties revealed an increase in the interfacial layer thickness of the PLA/TPU blend with EBG. The scanning electronic microscopy images showed a drastic reduction in the size of the dispersed phase by increasing the compatibilizer agent EBG content in the blend. The compatibilization of the PLA/TPU blends improved both the Izod impact strength and yield stress by 38 and 33%, respectively, in comparison with neat PLA/TPU blend. The addition of EBG into PLA/TPU blends significantly increased the entanglement density and the PLA toughening but resulted in a decrease of PLA deformation at break. The PLA and TPU glass transitions were affected by the EBG, suggesting that the PLA and TPU domains were partially miscible. |
publishDate |
2020 |
dc.date.issued.fl_str_mv |
2020 |
dc.date.accessioned.fl_str_mv |
2021-04-09T04:25:42Z |
dc.type.driver.fl_str_mv |
Estrangeiro info:eu-repo/semantics/article |
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info:eu-repo/semantics/publishedVersion |
format |
article |
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publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10183/219768 |
dc.identifier.issn.pt_BR.fl_str_mv |
0021-8995 |
dc.identifier.nrb.pt_BR.fl_str_mv |
001123821 |
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0021-8995 001123821 |
url |
http://hdl.handle.net/10183/219768 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.ispartof.pt_BR.fl_str_mv |
Journal of applied polymer science. New York. Vol. 137, n. 31 (2020), [Article] 48926, p. 1-11 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
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application/pdf |
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