Surface tensions and surface potentials of acid solutions
Autor(a) principal: | |
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Data de Publicação: | 2010 |
Outros Autores: | |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRGS |
Texto Completo: | http://hdl.handle.net/10183/205124 |
Resumo: | A theory is presented which allows us to quantitatively calculate the excess surface tension of acid solutions. The H+, in the form of hydronium ion, is found to be strongly adsorbed to the solution-air interface. To account for the electrostatic potential difference measured experimentally, it is necessary to assume that the hydronium ion is oriented with its hydrogens pointing into the bulk water. The theory is quantitatively accurate for surface tensions and is qualitative for electrostatic potential difference across the air-water interface. |
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Santos, Alexandre Pereira dosLevin, Yan2020-01-30T04:09:57Z20100021-9606http://hdl.handle.net/10183/205124000761642A theory is presented which allows us to quantitatively calculate the excess surface tension of acid solutions. The H+, in the form of hydronium ion, is found to be strongly adsorbed to the solution-air interface. To account for the electrostatic potential difference measured experimentally, it is necessary to assume that the hydronium ion is oriented with its hydrogens pointing into the bulk water. The theory is quantitatively accurate for surface tensions and is qualitative for electrostatic potential difference across the air-water interface.application/pdfengThe journal of chemical physics. New York. Vol. 133, no. 15 (Oct. 2010), 154107, 5 p.Física da matéria condensadaPotencial de superfícieTensão superficialSurface tensions and surface potentials of acid solutionsEstrangeiroinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFRGSinstname:Universidade Federal do Rio Grande do Sul (UFRGS)instacron:UFRGSTEXT000761642.pdf.txt000761642.pdf.txtExtracted Texttext/plain24331http://www.lume.ufrgs.br/bitstream/10183/205124/2/000761642.pdf.txtd3f3f4064513e5ef63442cbfbcd2221cMD52ORIGINAL000761642.pdfTexto completo (inglês)application/pdf484839http://www.lume.ufrgs.br/bitstream/10183/205124/1/000761642.pdf8a8657e58012f5ef296f6418f24333d0MD5110183/2051242023-06-14 03:31:27.410251oai:www.lume.ufrgs.br:10183/205124Repositório de PublicaçõesPUBhttps://lume.ufrgs.br/oai/requestopendoar:2023-06-14T06:31:27Repositório Institucional da UFRGS - Universidade Federal do Rio Grande do Sul (UFRGS)false |
dc.title.pt_BR.fl_str_mv |
Surface tensions and surface potentials of acid solutions |
title |
Surface tensions and surface potentials of acid solutions |
spellingShingle |
Surface tensions and surface potentials of acid solutions Santos, Alexandre Pereira dos Física da matéria condensada Potencial de superfície Tensão superficial |
title_short |
Surface tensions and surface potentials of acid solutions |
title_full |
Surface tensions and surface potentials of acid solutions |
title_fullStr |
Surface tensions and surface potentials of acid solutions |
title_full_unstemmed |
Surface tensions and surface potentials of acid solutions |
title_sort |
Surface tensions and surface potentials of acid solutions |
author |
Santos, Alexandre Pereira dos |
author_facet |
Santos, Alexandre Pereira dos Levin, Yan |
author_role |
author |
author2 |
Levin, Yan |
author2_role |
author |
dc.contributor.author.fl_str_mv |
Santos, Alexandre Pereira dos Levin, Yan |
dc.subject.por.fl_str_mv |
Física da matéria condensada Potencial de superfície Tensão superficial |
topic |
Física da matéria condensada Potencial de superfície Tensão superficial |
description |
A theory is presented which allows us to quantitatively calculate the excess surface tension of acid solutions. The H+, in the form of hydronium ion, is found to be strongly adsorbed to the solution-air interface. To account for the electrostatic potential difference measured experimentally, it is necessary to assume that the hydronium ion is oriented with its hydrogens pointing into the bulk water. The theory is quantitatively accurate for surface tensions and is qualitative for electrostatic potential difference across the air-water interface. |
publishDate |
2010 |
dc.date.issued.fl_str_mv |
2010 |
dc.date.accessioned.fl_str_mv |
2020-01-30T04:09:57Z |
dc.type.driver.fl_str_mv |
Estrangeiro info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://hdl.handle.net/10183/205124 |
dc.identifier.issn.pt_BR.fl_str_mv |
0021-9606 |
dc.identifier.nrb.pt_BR.fl_str_mv |
000761642 |
identifier_str_mv |
0021-9606 000761642 |
url |
http://hdl.handle.net/10183/205124 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.ispartof.pt_BR.fl_str_mv |
The journal of chemical physics. New York. Vol. 133, no. 15 (Oct. 2010), 154107, 5 p. |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
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application/pdf |
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reponame:Repositório Institucional da UFRGS instname:Universidade Federal do Rio Grande do Sul (UFRGS) instacron:UFRGS |
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UFRGS |
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Repositório Institucional da UFRGS |
collection |
Repositório Institucional da UFRGS |
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