Surface tensions and surface potentials of acid solutions

Detalhes bibliográficos
Autor(a) principal: Santos, Alexandre Pereira dos
Data de Publicação: 2010
Outros Autores: Levin, Yan
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFRGS
Texto Completo: http://hdl.handle.net/10183/205124
Resumo: A theory is presented which allows us to quantitatively calculate the excess surface tension of acid solutions. The H+, in the form of hydronium ion, is found to be strongly adsorbed to the solution-air interface. To account for the electrostatic potential difference measured experimentally, it is necessary to assume that the hydronium ion is oriented with its hydrogens pointing into the bulk water. The theory is quantitatively accurate for surface tensions and is qualitative for electrostatic potential difference across the air-water interface.
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spelling Santos, Alexandre Pereira dosLevin, Yan2020-01-30T04:09:57Z20100021-9606http://hdl.handle.net/10183/205124000761642A theory is presented which allows us to quantitatively calculate the excess surface tension of acid solutions. The H+, in the form of hydronium ion, is found to be strongly adsorbed to the solution-air interface. To account for the electrostatic potential difference measured experimentally, it is necessary to assume that the hydronium ion is oriented with its hydrogens pointing into the bulk water. The theory is quantitatively accurate for surface tensions and is qualitative for electrostatic potential difference across the air-water interface.application/pdfengThe journal of chemical physics. New York. Vol. 133, no. 15 (Oct. 2010), 154107, 5 p.Física da matéria condensadaPotencial de superfícieTensão superficialSurface tensions and surface potentials of acid solutionsEstrangeiroinfo:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/openAccessreponame:Repositório Institucional da UFRGSinstname:Universidade Federal do Rio Grande do Sul (UFRGS)instacron:UFRGSTEXT000761642.pdf.txt000761642.pdf.txtExtracted Texttext/plain24331http://www.lume.ufrgs.br/bitstream/10183/205124/2/000761642.pdf.txtd3f3f4064513e5ef63442cbfbcd2221cMD52ORIGINAL000761642.pdfTexto completo (inglês)application/pdf484839http://www.lume.ufrgs.br/bitstream/10183/205124/1/000761642.pdf8a8657e58012f5ef296f6418f24333d0MD5110183/2051242023-06-14 03:31:27.410251oai:www.lume.ufrgs.br:10183/205124Repositório de PublicaçõesPUBhttps://lume.ufrgs.br/oai/requestopendoar:2023-06-14T06:31:27Repositório Institucional da UFRGS - Universidade Federal do Rio Grande do Sul (UFRGS)false
dc.title.pt_BR.fl_str_mv Surface tensions and surface potentials of acid solutions
title Surface tensions and surface potentials of acid solutions
spellingShingle Surface tensions and surface potentials of acid solutions
Santos, Alexandre Pereira dos
Física da matéria condensada
Potencial de superfície
Tensão superficial
title_short Surface tensions and surface potentials of acid solutions
title_full Surface tensions and surface potentials of acid solutions
title_fullStr Surface tensions and surface potentials of acid solutions
title_full_unstemmed Surface tensions and surface potentials of acid solutions
title_sort Surface tensions and surface potentials of acid solutions
author Santos, Alexandre Pereira dos
author_facet Santos, Alexandre Pereira dos
Levin, Yan
author_role author
author2 Levin, Yan
author2_role author
dc.contributor.author.fl_str_mv Santos, Alexandre Pereira dos
Levin, Yan
dc.subject.por.fl_str_mv Física da matéria condensada
Potencial de superfície
Tensão superficial
topic Física da matéria condensada
Potencial de superfície
Tensão superficial
description A theory is presented which allows us to quantitatively calculate the excess surface tension of acid solutions. The H+, in the form of hydronium ion, is found to be strongly adsorbed to the solution-air interface. To account for the electrostatic potential difference measured experimentally, it is necessary to assume that the hydronium ion is oriented with its hydrogens pointing into the bulk water. The theory is quantitatively accurate for surface tensions and is qualitative for electrostatic potential difference across the air-water interface.
publishDate 2010
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dc.relation.ispartof.pt_BR.fl_str_mv The journal of chemical physics. New York. Vol. 133, no. 15 (Oct. 2010), 154107, 5 p.
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