Salt solubility and saturated electrical conductivity data for water + monoethylene glycol + NaCl in a wide temperature range
Autor(a) principal: | |
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Data de Publicação: | 2021 |
Outros Autores: | , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRN |
Texto Completo: | https://repositorio.ufrn.br/handle/123456789/44840 |
Resumo: | 2030-12 |
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Chiavone Filho, OsvaldoMonteiro, Mateus FernandesMoura Neto, Mário Hermes deMota, André Luis NovaisFigueiredo, Camila S.Ciambelli, João Rafael PerroniNascimento, Jailton Ferreira doPereira, Leonardo S.2021-11-09T14:49:25Z2021-03-08MONTEIRO, M. F. ; MOURA-NETO, MARIO H. ; MOTA, A. L. N. ; FIGUEIREDO, CAMILA SENNA ; CIAMBELLI, J. R. P. ; NASCIMENTO, J. F. ; PEREIRA, L. S. ; CHIAVONE-FILHO, OSVALDO . Salt Solubility and Saturated Electrical Conductivity Data for Water + Monoethylene Glycol + NaCl in a Wide Temperature Range. JOURNAL OF CHEMICAL AND ENGINEERING DATA, v. 1, p. 1, 2021. Disponível em: https://pubs.acs.org/doi/10.1021/acs.jced.0c00975. Acesso em: 14 jun. 2021. https://doi.org/10.1021/acs.jced.0c00975.0021-95681520-5134https://repositorio.ufrn.br/handle/123456789/44840org/10.1021/acs.jced.0c00975ACS publicationsSalt SolubilitySolubilitySolventsElectrical conductivityMixturesSalt solubility and saturated electrical conductivity data for water + monoethylene glycol + NaCl in a wide temperature rangeinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article2030-12Monoethylene glycol (MEG) is used to prevent hydrate formation in subsea pipelines of natural gas production. MEG is recovered at an offshore regeneration unit. Sodium chloride is the predominant salt in the water−MEG streams. Thus, knowledge of NaCl solubilities in the process conditions is relevant for the design and operation of a MEG regeneration unit. Six isotherms of NaCl solubility were measured (76 data points) from T = (293.15 to 403.15) K in the whole solvent concentration range. The analytical method for salt solubility was based on the reproducibility of the concentration of two successive samples. Density measurements were accurately applied for these analyses. The temperature dependence on NaCl solubility is relatively weak. A reverse behavior with increasing temperature was observed for MEG contents higher than 90 wt %. Salt solubilities were successfully correlated with Redlich−Kister expansion (AADwNaCl = 0.0006 and ΔwNaCl = 0.47%). Electrical conductivity of NaCl - saturated solutions were measured (44 data points) at T = (293.15 to 363.15) K and correlated with a semiempirical model. A large difference in electrical conductivity for the two solvents was observed. The correlation adequately represented the data set (AADκ = 5.67 mS·cm−1 and Δκ = 5.94%). NaCl solubilities and electrical conductivities were accurately determined and are useful for the MEG regeneration processengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNinfo:eu-repo/semantics/openAccessCC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8811https://repositorio.ufrn.br/bitstream/123456789/44840/2/license_rdfe39d27027a6cc9cb039ad269a5db8e34MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/44840/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53123456789/448402024-03-19 01:06:56.387oai:https://repositorio.ufrn.br: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Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2024-03-19T04:06:56Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false |
dc.title.pt_BR.fl_str_mv |
Salt solubility and saturated electrical conductivity data for water + monoethylene glycol + NaCl in a wide temperature range |
title |
Salt solubility and saturated electrical conductivity data for water + monoethylene glycol + NaCl in a wide temperature range |
spellingShingle |
Salt solubility and saturated electrical conductivity data for water + monoethylene glycol + NaCl in a wide temperature range Chiavone Filho, Osvaldo Salt Solubility Solubility Solvents Electrical conductivity Mixtures |
title_short |
Salt solubility and saturated electrical conductivity data for water + monoethylene glycol + NaCl in a wide temperature range |
title_full |
Salt solubility and saturated electrical conductivity data for water + monoethylene glycol + NaCl in a wide temperature range |
title_fullStr |
Salt solubility and saturated electrical conductivity data for water + monoethylene glycol + NaCl in a wide temperature range |
title_full_unstemmed |
Salt solubility and saturated electrical conductivity data for water + monoethylene glycol + NaCl in a wide temperature range |
title_sort |
Salt solubility and saturated electrical conductivity data for water + monoethylene glycol + NaCl in a wide temperature range |
author |
Chiavone Filho, Osvaldo |
author_facet |
Chiavone Filho, Osvaldo Monteiro, Mateus Fernandes Moura Neto, Mário Hermes de Mota, André Luis Novais Figueiredo, Camila S. Ciambelli, João Rafael Perroni Nascimento, Jailton Ferreira do Pereira, Leonardo S. |
author_role |
author |
author2 |
Monteiro, Mateus Fernandes Moura Neto, Mário Hermes de Mota, André Luis Novais Figueiredo, Camila S. Ciambelli, João Rafael Perroni Nascimento, Jailton Ferreira do Pereira, Leonardo S. |
author2_role |
author author author author author author author |
dc.contributor.author.fl_str_mv |
Chiavone Filho, Osvaldo Monteiro, Mateus Fernandes Moura Neto, Mário Hermes de Mota, André Luis Novais Figueiredo, Camila S. Ciambelli, João Rafael Perroni Nascimento, Jailton Ferreira do Pereira, Leonardo S. |
dc.subject.por.fl_str_mv |
Salt Solubility Solubility Solvents Electrical conductivity Mixtures |
topic |
Salt Solubility Solubility Solvents Electrical conductivity Mixtures |
description |
2030-12 |
publishDate |
2021 |
dc.date.accessioned.fl_str_mv |
2021-11-09T14:49:25Z |
dc.date.issued.fl_str_mv |
2021-03-08 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
MONTEIRO, M. F. ; MOURA-NETO, MARIO H. ; MOTA, A. L. N. ; FIGUEIREDO, CAMILA SENNA ; CIAMBELLI, J. R. P. ; NASCIMENTO, J. F. ; PEREIRA, L. S. ; CHIAVONE-FILHO, OSVALDO . Salt Solubility and Saturated Electrical Conductivity Data for Water + Monoethylene Glycol + NaCl in a Wide Temperature Range. JOURNAL OF CHEMICAL AND ENGINEERING DATA, v. 1, p. 1, 2021. Disponível em: https://pubs.acs.org/doi/10.1021/acs.jced.0c00975. Acesso em: 14 jun. 2021. https://doi.org/10.1021/acs.jced.0c00975. |
dc.identifier.uri.fl_str_mv |
https://repositorio.ufrn.br/handle/123456789/44840 |
dc.identifier.issn.none.fl_str_mv |
0021-9568 1520-5134 |
dc.identifier.doi.none.fl_str_mv |
org/10.1021/acs.jced.0c00975 |
identifier_str_mv |
MONTEIRO, M. F. ; MOURA-NETO, MARIO H. ; MOTA, A. L. N. ; FIGUEIREDO, CAMILA SENNA ; CIAMBELLI, J. R. P. ; NASCIMENTO, J. F. ; PEREIRA, L. S. ; CHIAVONE-FILHO, OSVALDO . Salt Solubility and Saturated Electrical Conductivity Data for Water + Monoethylene Glycol + NaCl in a Wide Temperature Range. JOURNAL OF CHEMICAL AND ENGINEERING DATA, v. 1, p. 1, 2021. Disponível em: https://pubs.acs.org/doi/10.1021/acs.jced.0c00975. Acesso em: 14 jun. 2021. https://doi.org/10.1021/acs.jced.0c00975. 0021-9568 1520-5134 org/10.1021/acs.jced.0c00975 |
url |
https://repositorio.ufrn.br/handle/123456789/44840 |
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eng |
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eng |
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info:eu-repo/semantics/openAccess |
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openAccess |
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ACS publications |
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ACS publications |
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