Kinetic and wet oxidation of phenol catalyzed by non-promoted and potassium-promoted manganese/cerium oxide
Autor(a) principal: | |
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Data de Publicação: | 2006 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRN |
Texto Completo: | https://repositorio.ufrn.br/handle/123456789/40838 |
Resumo: | The wet oxidation of organic compounds to CO2 and H2O has been shown to be a very efficient technique in the outflows treatment. This work focuses on the interaction of the chemical element potassium with the catalyst MnO2–CeO2 in the wet degradation of phenol. The reaction has been carried out in an autoclave with a controlled system of agitation, pressure, temperature and sampling of the liquid phase. The experiments were performed in the presence of the catalysts MnO2–CeO2 and K–MnO2–CeO2 in the following operational conditions: temperature of 130 °C, P = 20.4 atm, catalyst concentration in the range 1.5–5.0 g/L, initial phenol concentration of 0.5 g/L, initial pH varying between 6.8 and 8.5, and percentage of potassium in the catalyst MnO2–CeO2 ranging between 0% and 10%. Curves indicating the profile of conversion of total organic carbon show that the phenol degradation is favored when the potassium quantity is reduced. This behaviour is confirmed by BET analysis, whereby the catalyst presents larger specific area when compared to the percentages of other components. Regardless of the catalyst used in the phenol oxidation, the kinetic constant of reaction had the same order of magnitude for two parallel stages proposed by a first-order kinetic model |
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Santiago, Aristides Felipe J.Sousa, João Fernandes deGuedes, Rodrigo CaetanoJerônimo, Carlos Enrique de MedeirosBenachour, Mohand2021-09-29T19:53:05Z2021-09-29T19:53:05Z2006-11-10SANTIAGO, Aristides Felipe; SOUSA, J. F.; GUEDES, Rodrigo Caetano; JERÔNIMO, Carlos Enrique de Medeiros ; BENACHOUR, Mohand . Kinetic and wet oxidation of phenol catalyzed by non-promoted and potassium-promoted manganese/cerium oxide.. Journal of Hazardous Materials (Print), v. B1, p. 325-330, 2006. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0304389406007916#!. Acesso em: 29 set. 2021. https://doi.org/10.1016/j.jhazmat.2006.05.1180304-3894https://repositorio.ufrn.br/handle/123456789/4083810.1016/j.jhazmat.2006.05.118ElsevierAttribution 3.0 Brazilhttp://creativecommons.org/licenses/by/3.0/br/info:eu-repo/semantics/openAccessSlurry reactorKinetic modelPhenolPotassiumCatalytic wet oxidationKinetic and wet oxidation of phenol catalyzed by non-promoted and potassium-promoted manganese/cerium oxideinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleThe wet oxidation of organic compounds to CO2 and H2O has been shown to be a very efficient technique in the outflows treatment. This work focuses on the interaction of the chemical element potassium with the catalyst MnO2–CeO2 in the wet degradation of phenol. The reaction has been carried out in an autoclave with a controlled system of agitation, pressure, temperature and sampling of the liquid phase. The experiments were performed in the presence of the catalysts MnO2–CeO2 and K–MnO2–CeO2 in the following operational conditions: temperature of 130 °C, P = 20.4 atm, catalyst concentration in the range 1.5–5.0 g/L, initial phenol concentration of 0.5 g/L, initial pH varying between 6.8 and 8.5, and percentage of potassium in the catalyst MnO2–CeO2 ranging between 0% and 10%. Curves indicating the profile of conversion of total organic carbon show that the phenol degradation is favored when the potassium quantity is reduced. This behaviour is confirmed by BET analysis, whereby the catalyst presents larger specific area when compared to the percentages of other components. Regardless of the catalyst used in the phenol oxidation, the kinetic constant of reaction had the same order of magnitude for two parallel stages proposed by a first-order kinetic modelengreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNORIGINALKineticAndWetOxidationOfPhenol_Sousa_2006 (1).pdfKineticAndWetOxidationOfPhenol_Sousa_2006 (1).pdfapplication/pdf362055https://repositorio.ufrn.br/bitstream/123456789/40838/1/KineticAndWetOxidationOfPhenol_Sousa_2006%20%281%29.pdf8976a241c21a002fc4aa8173e969b9e5MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8914https://repositorio.ufrn.br/bitstream/123456789/40838/2/license_rdf4d2950bda3d176f570a9f8b328dfbbefMD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/40838/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53123456789/408382021-09-29 16:53:06.894oai:https://repositorio.ufrn.br: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Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2021-09-29T19:53:06Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false |
dc.title.pt_BR.fl_str_mv |
Kinetic and wet oxidation of phenol catalyzed by non-promoted and potassium-promoted manganese/cerium oxide |
title |
Kinetic and wet oxidation of phenol catalyzed by non-promoted and potassium-promoted manganese/cerium oxide |
spellingShingle |
Kinetic and wet oxidation of phenol catalyzed by non-promoted and potassium-promoted manganese/cerium oxide Santiago, Aristides Felipe J. Slurry reactor Kinetic model Phenol Potassium Catalytic wet oxidation |
title_short |
Kinetic and wet oxidation of phenol catalyzed by non-promoted and potassium-promoted manganese/cerium oxide |
title_full |
Kinetic and wet oxidation of phenol catalyzed by non-promoted and potassium-promoted manganese/cerium oxide |
title_fullStr |
Kinetic and wet oxidation of phenol catalyzed by non-promoted and potassium-promoted manganese/cerium oxide |
title_full_unstemmed |
Kinetic and wet oxidation of phenol catalyzed by non-promoted and potassium-promoted manganese/cerium oxide |
title_sort |
Kinetic and wet oxidation of phenol catalyzed by non-promoted and potassium-promoted manganese/cerium oxide |
author |
Santiago, Aristides Felipe J. |
author_facet |
Santiago, Aristides Felipe J. Sousa, João Fernandes de Guedes, Rodrigo Caetano Jerônimo, Carlos Enrique de Medeiros Benachour, Mohand |
author_role |
author |
author2 |
Sousa, João Fernandes de Guedes, Rodrigo Caetano Jerônimo, Carlos Enrique de Medeiros Benachour, Mohand |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Santiago, Aristides Felipe J. Sousa, João Fernandes de Guedes, Rodrigo Caetano Jerônimo, Carlos Enrique de Medeiros Benachour, Mohand |
dc.subject.por.fl_str_mv |
Slurry reactor Kinetic model Phenol Potassium Catalytic wet oxidation |
topic |
Slurry reactor Kinetic model Phenol Potassium Catalytic wet oxidation |
description |
The wet oxidation of organic compounds to CO2 and H2O has been shown to be a very efficient technique in the outflows treatment. This work focuses on the interaction of the chemical element potassium with the catalyst MnO2–CeO2 in the wet degradation of phenol. The reaction has been carried out in an autoclave with a controlled system of agitation, pressure, temperature and sampling of the liquid phase. The experiments were performed in the presence of the catalysts MnO2–CeO2 and K–MnO2–CeO2 in the following operational conditions: temperature of 130 °C, P = 20.4 atm, catalyst concentration in the range 1.5–5.0 g/L, initial phenol concentration of 0.5 g/L, initial pH varying between 6.8 and 8.5, and percentage of potassium in the catalyst MnO2–CeO2 ranging between 0% and 10%. Curves indicating the profile of conversion of total organic carbon show that the phenol degradation is favored when the potassium quantity is reduced. This behaviour is confirmed by BET analysis, whereby the catalyst presents larger specific area when compared to the percentages of other components. Regardless of the catalyst used in the phenol oxidation, the kinetic constant of reaction had the same order of magnitude for two parallel stages proposed by a first-order kinetic model |
publishDate |
2006 |
dc.date.issued.fl_str_mv |
2006-11-10 |
dc.date.accessioned.fl_str_mv |
2021-09-29T19:53:05Z |
dc.date.available.fl_str_mv |
2021-09-29T19:53:05Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
SANTIAGO, Aristides Felipe; SOUSA, J. F.; GUEDES, Rodrigo Caetano; JERÔNIMO, Carlos Enrique de Medeiros ; BENACHOUR, Mohand . Kinetic and wet oxidation of phenol catalyzed by non-promoted and potassium-promoted manganese/cerium oxide.. Journal of Hazardous Materials (Print), v. B1, p. 325-330, 2006. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0304389406007916#!. Acesso em: 29 set. 2021. https://doi.org/10.1016/j.jhazmat.2006.05.118 |
dc.identifier.uri.fl_str_mv |
https://repositorio.ufrn.br/handle/123456789/40838 |
dc.identifier.issn.none.fl_str_mv |
0304-3894 |
dc.identifier.doi.none.fl_str_mv |
10.1016/j.jhazmat.2006.05.118 |
identifier_str_mv |
SANTIAGO, Aristides Felipe; SOUSA, J. F.; GUEDES, Rodrigo Caetano; JERÔNIMO, Carlos Enrique de Medeiros ; BENACHOUR, Mohand . Kinetic and wet oxidation of phenol catalyzed by non-promoted and potassium-promoted manganese/cerium oxide.. Journal of Hazardous Materials (Print), v. B1, p. 325-330, 2006. Disponível em: https://www.sciencedirect.com/science/article/abs/pii/S0304389406007916#!. Acesso em: 29 set. 2021. https://doi.org/10.1016/j.jhazmat.2006.05.118 0304-3894 10.1016/j.jhazmat.2006.05.118 |
url |
https://repositorio.ufrn.br/handle/123456789/40838 |
dc.language.iso.fl_str_mv |
eng |
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eng |
dc.rights.driver.fl_str_mv |
Attribution 3.0 Brazil http://creativecommons.org/licenses/by/3.0/br/ info:eu-repo/semantics/openAccess |
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Attribution 3.0 Brazil http://creativecommons.org/licenses/by/3.0/br/ |
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openAccess |
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Elsevier |
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Elsevier |
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