Thermogravimetric and UV–vis spectroscopic studies of chromium redox reactions in rutile pigments
Autor(a) principal: | |
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Data de Publicação: | 2009 |
Outros Autores: | , , , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFRN |
Texto Completo: | https://repositorio.ufrn.br/handle/123456789/32185 |
Resumo: | In this study undoped and Cr, Sb or Mo doped TiO2 were synthesized by polymeric precursor method and characterized by X-ray diffraction, UV–VIS spectroscopy, infrared spectroscopy and thermogravimetry (TG). The TG curves showed a continuous mass loss assigned to the hydroxyl elimination and Cr6? reduction. Doped TiO2 samples showed a higher mass loss assigned to water and gas elimination at lower temperatures. In these doped materials a decrease in the anatase–rutile phase transition temperature was observed. After calcination at 1,000 C, rutile was obtained as a single phase material without the presence of Cr6? |
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Vieira, Fagner Ticiano GomesSouza, Soraia C.Oliveira, A. L. M.Lima, Severino Jackson GuedesSilva, Elson Longo daPaskocimas, Carlos AlbertoSoledade, Luiz Edmundo BastosSouza, Antônio Gouveia deSantos, Ieda Maria Garcia dos2021-04-13T13:37:12Z2021-04-13T13:37:12Z2009-06-24VIEIRA, F. T. G.; SOUZA, Soraia C.; OLIVEIRA, A. L. M.; LIMA, S. J. G.; LONGO, E.; PASKOCIMAS, C. A.; SOLEDADE, L. E. B.; SOUZA, A. G.; SANTOS, Iêda M. G.. Thermogravimetric and UV–vis spectroscopic studies of chromium redox reactions in rutile pigments. Journal of Thermal Analysis And Calorimetry, [S.L.], v. 97, n. 1, p. 99-103, 24 jun. 2009. Disponível em: https://link.springer.com/article/10.1007%2Fs10973-009-0074-8. Acesso em: 08 mar. 2021. http://dx.doi.org/10.1007/s10973-009-0074-8.1388-61501572-894310.1007/s10973-009-0074-8https://repositorio.ufrn.br/handle/123456789/32185SpringerAttribution-NonCommercial 3.0 Brazilhttp://creativecommons.org/licenses/by-nc/3.0/br/info:eu-repo/semantics/openAccessPechiniThermal analysisTiO2Redox reactionsThermogravimetric and UV–vis spectroscopic studies of chromium redox reactions in rutile pigmentsinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleIn this study undoped and Cr, Sb or Mo doped TiO2 were synthesized by polymeric precursor method and characterized by X-ray diffraction, UV–VIS spectroscopy, infrared spectroscopy and thermogravimetry (TG). The TG curves showed a continuous mass loss assigned to the hydroxyl elimination and Cr6? reduction. Doped TiO2 samples showed a higher mass loss assigned to water and gas elimination at lower temperatures. In these doped materials a decrease in the anatase–rutile phase transition temperature was observed. After calcination at 1,000 C, rutile was obtained as a single phase material without the presence of Cr6?engreponame:Repositório Institucional da UFRNinstname:Universidade Federal do Rio Grande do Norte (UFRN)instacron:UFRNORIGINALThermogravimetricUV–visSpectroscopic_PASKOCIMAS_2009.pdfThermogravimetricUV–visSpectroscopic_PASKOCIMAS_2009.pdfArtigoapplication/pdf381696https://repositorio.ufrn.br/bitstream/123456789/32185/1/ThermogravimetricUV%e2%80%93visSpectroscopic_PASKOCIMAS_2009.pdfa94d3b2bdb2cc05975904c0730407bfeMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81484https://repositorio.ufrn.br/bitstream/123456789/32185/3/license.txte9597aa2854d128fd968be5edc8a28d9MD53CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-8920https://repositorio.ufrn.br/bitstream/123456789/32185/2/license_rdf728dfda2fa81b274c619d08d1dfc1a03MD52TEXTThermogravimetricUV–visSpectroscopic_PASKOCIMAS_2009.pdf.txtThermogravimetricUV–visSpectroscopic_PASKOCIMAS_2009.pdf.txtExtracted texttext/plain20935https://repositorio.ufrn.br/bitstream/123456789/32185/4/ThermogravimetricUV%e2%80%93visSpectroscopic_PASKOCIMAS_2009.pdf.txtd3c473c412000e3e52ca61be3da8c89aMD54THUMBNAILThermogravimetricUV–visSpectroscopic_PASKOCIMAS_2009.pdf.jpgThermogravimetricUV–visSpectroscopic_PASKOCIMAS_2009.pdf.jpgGenerated Thumbnailimage/jpeg1677https://repositorio.ufrn.br/bitstream/123456789/32185/5/ThermogravimetricUV%e2%80%93visSpectroscopic_PASKOCIMAS_2009.pdf.jpg448635abd23c043ed53a119ace315b4cMD55123456789/321852021-04-18 06:06:04.241oai:https://repositorio.ufrn.br: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Repositório de PublicaçõesPUBhttp://repositorio.ufrn.br/oai/opendoar:2021-04-18T09:06:04Repositório Institucional da UFRN - Universidade Federal do Rio Grande do Norte (UFRN)false |
dc.title.pt_BR.fl_str_mv |
Thermogravimetric and UV–vis spectroscopic studies of chromium redox reactions in rutile pigments |
title |
Thermogravimetric and UV–vis spectroscopic studies of chromium redox reactions in rutile pigments |
spellingShingle |
Thermogravimetric and UV–vis spectroscopic studies of chromium redox reactions in rutile pigments Vieira, Fagner Ticiano Gomes Pechini Thermal analysis TiO2 Redox reactions |
title_short |
Thermogravimetric and UV–vis spectroscopic studies of chromium redox reactions in rutile pigments |
title_full |
Thermogravimetric and UV–vis spectroscopic studies of chromium redox reactions in rutile pigments |
title_fullStr |
Thermogravimetric and UV–vis spectroscopic studies of chromium redox reactions in rutile pigments |
title_full_unstemmed |
Thermogravimetric and UV–vis spectroscopic studies of chromium redox reactions in rutile pigments |
title_sort |
Thermogravimetric and UV–vis spectroscopic studies of chromium redox reactions in rutile pigments |
author |
Vieira, Fagner Ticiano Gomes |
author_facet |
Vieira, Fagner Ticiano Gomes Souza, Soraia C. Oliveira, A. L. M. Lima, Severino Jackson Guedes Silva, Elson Longo da Paskocimas, Carlos Alberto Soledade, Luiz Edmundo Bastos Souza, Antônio Gouveia de Santos, Ieda Maria Garcia dos |
author_role |
author |
author2 |
Souza, Soraia C. Oliveira, A. L. M. Lima, Severino Jackson Guedes Silva, Elson Longo da Paskocimas, Carlos Alberto Soledade, Luiz Edmundo Bastos Souza, Antônio Gouveia de Santos, Ieda Maria Garcia dos |
author2_role |
author author author author author author author author |
dc.contributor.author.fl_str_mv |
Vieira, Fagner Ticiano Gomes Souza, Soraia C. Oliveira, A. L. M. Lima, Severino Jackson Guedes Silva, Elson Longo da Paskocimas, Carlos Alberto Soledade, Luiz Edmundo Bastos Souza, Antônio Gouveia de Santos, Ieda Maria Garcia dos |
dc.subject.por.fl_str_mv |
Pechini Thermal analysis TiO2 Redox reactions |
topic |
Pechini Thermal analysis TiO2 Redox reactions |
description |
In this study undoped and Cr, Sb or Mo doped TiO2 were synthesized by polymeric precursor method and characterized by X-ray diffraction, UV–VIS spectroscopy, infrared spectroscopy and thermogravimetry (TG). The TG curves showed a continuous mass loss assigned to the hydroxyl elimination and Cr6? reduction. Doped TiO2 samples showed a higher mass loss assigned to water and gas elimination at lower temperatures. In these doped materials a decrease in the anatase–rutile phase transition temperature was observed. After calcination at 1,000 C, rutile was obtained as a single phase material without the presence of Cr6? |
publishDate |
2009 |
dc.date.issued.fl_str_mv |
2009-06-24 |
dc.date.accessioned.fl_str_mv |
2021-04-13T13:37:12Z |
dc.date.available.fl_str_mv |
2021-04-13T13:37:12Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
VIEIRA, F. T. G.; SOUZA, Soraia C.; OLIVEIRA, A. L. M.; LIMA, S. J. G.; LONGO, E.; PASKOCIMAS, C. A.; SOLEDADE, L. E. B.; SOUZA, A. G.; SANTOS, Iêda M. G.. Thermogravimetric and UV–vis spectroscopic studies of chromium redox reactions in rutile pigments. Journal of Thermal Analysis And Calorimetry, [S.L.], v. 97, n. 1, p. 99-103, 24 jun. 2009. Disponível em: https://link.springer.com/article/10.1007%2Fs10973-009-0074-8. Acesso em: 08 mar. 2021. http://dx.doi.org/10.1007/s10973-009-0074-8. |
dc.identifier.uri.fl_str_mv |
https://repositorio.ufrn.br/handle/123456789/32185 |
dc.identifier.issn.none.fl_str_mv |
1388-6150 1572-8943 10.1007/s10973-009-0074-8 |
identifier_str_mv |
VIEIRA, F. T. G.; SOUZA, Soraia C.; OLIVEIRA, A. L. M.; LIMA, S. J. G.; LONGO, E.; PASKOCIMAS, C. A.; SOLEDADE, L. E. B.; SOUZA, A. G.; SANTOS, Iêda M. G.. Thermogravimetric and UV–vis spectroscopic studies of chromium redox reactions in rutile pigments. Journal of Thermal Analysis And Calorimetry, [S.L.], v. 97, n. 1, p. 99-103, 24 jun. 2009. Disponível em: https://link.springer.com/article/10.1007%2Fs10973-009-0074-8. Acesso em: 08 mar. 2021. http://dx.doi.org/10.1007/s10973-009-0074-8. 1388-6150 1572-8943 10.1007/s10973-009-0074-8 |
url |
https://repositorio.ufrn.br/handle/123456789/32185 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
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Attribution-NonCommercial 3.0 Brazil http://creativecommons.org/licenses/by-nc/3.0/br/ info:eu-repo/semantics/openAccess |
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Attribution-NonCommercial 3.0 Brazil http://creativecommons.org/licenses/by-nc/3.0/br/ |
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openAccess |
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Springer |
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Springer |
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UFRN |
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Repositório Institucional da UFRN |
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