N'-[3-(Hydroxyimino)butan-2-ylidene]-4-methylbenzene-1-sulfonohydrazide

Bibliographic Details
Main Author: Bulhosa, Maria C. S.
Publication Date: 2012
Other Authors: Gervini, Vanessa Carratu, Bresolin, Leandro, Locatelli, Aline, Oliveira, Adriano Bof de
Format: Article
Language: eng
Source: Repositório Institucional da UFS
Download full: https://ri.ufs.br/handle/riufs/633
Summary: In the title compound, C11H15N3O3S, the C-S-N(H)-N linkage is nonplanar, the torsion angle being 75.70 (12)°. The compound has two almost planar fragments linked to the S atom: the hydrazone-derivative fragment [(HONC4H6)N-N(H)-] and the tolyl fragment (C7H7-) have maximum deviations from the mean plane through the non-H atoms of 0.0260 (10) and 0.0148 (14) Å, respectively. The two planar fragments make an interplanar angle of 79.47 (5)°. In the crystal, molecules are connected through inversion centers via pairs of N-HO and O-HN hydrogen bonds.
id UFS-2_8c80b445679e33dd3285feeca45090c1
oai_identifier_str oai:ufs.br:riufs/633
network_acronym_str UFS-2
network_name_str Repositório Institucional da UFS
repository_id_str
spelling Bulhosa, Maria C. S.Gervini, Vanessa CarratuBresolin, LeandroLocatelli, AlineOliveira, Adriano Bof de2013-07-12T21:43:06Z2013-07-12T21:43:06Z2012-03BULHOSA, M. C. S. et al. N'-[3-(Hydroxyimino)butan-2-ylidene]-4-methylbenzene-1-sulfonohydrazide. Acta Crystallographica Section E, Chester, v. 68, n. 3, p. o592-o592, mar. 2012. Disponível em: <http://journals.iucr.org/e/issues/2012/03/00/fy2042/index.html>. Acesso em: 12 jul. 2013.1600-5368https://ri.ufs.br/handle/riufs/633Copyright © International Union of CrystallographyIn the title compound, C11H15N3O3S, the C-S-N(H)-N linkage is nonplanar, the torsion angle being 75.70 (12)°. The compound has two almost planar fragments linked to the S atom: the hydrazone-derivative fragment [(HONC4H6)N-N(H)-] and the tolyl fragment (C7H7-) have maximum deviations from the mean plane through the non-H atoms of 0.0260 (10) and 0.0148 (14) Å, respectively. The two planar fragments make an interplanar angle of 79.47 (5)°. In the crystal, molecules are connected through inversion centers via pairs of N-HO and O-HN hydrogen bonds.International Union of CrystallographyC11H15N3O3SC-S-N(H)-NN'-[3-(Hydroxyimino)butan-2-ylidene]-4-methylbenzene-1-sulfonohydrazideinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleengreponame:Repositório Institucional da UFSinstname:Universidade Federal de Sergipe (UFS)instacron:UFSinfo:eu-repo/semantics/openAccessTHUMBNAILN'-[3-(Hydroxyimino).pdf.jpgN'-[3-(Hydroxyimino).pdf.jpgGenerated Thumbnailimage/jpeg1629https://ri.ufs.br/jspui/bitstream/riufs/633/4/N%27-%5b3-%28Hydroxyimino%29.pdf.jpga4c9f39eafe35eccfa78e134bbb72bf8MD54ORIGINALN'-[3-(Hydroxyimino).pdfN'-[3-(Hydroxyimino).pdfapplication/pdf346215https://ri.ufs.br/jspui/bitstream/riufs/633/1/N%27-%5b3-%28Hydroxyimino%29.pdff292b1868fd2da58e257be0525c28309MD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://ri.ufs.br/jspui/bitstream/riufs/633/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52TEXTN'-[3-(Hydroxyimino).pdf.txtN'-[3-(Hydroxyimino).pdf.txtExtracted texttext/plain15891https://ri.ufs.br/jspui/bitstream/riufs/633/3/N%27-%5b3-%28Hydroxyimino%29.pdf.txt5c71f109f845a36b8bd0796a6cb4cfb1MD53riufs/6332013-07-13 02:00:09.414oai:ufs.br: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Repositório InstitucionalPUBhttps://ri.ufs.br/oai/requestrepositorio@academico.ufs.bropendoar:2013-07-13T05:00:09Repositório Institucional da UFS - Universidade Federal de Sergipe (UFS)false
dc.title.pt_BR.fl_str_mv N'-[3-(Hydroxyimino)butan-2-ylidene]-4-methylbenzene-1-sulfonohydrazide
title N'-[3-(Hydroxyimino)butan-2-ylidene]-4-methylbenzene-1-sulfonohydrazide
spellingShingle N'-[3-(Hydroxyimino)butan-2-ylidene]-4-methylbenzene-1-sulfonohydrazide
Bulhosa, Maria C. S.
C11H15N3O3S
C-S-N(H)-N
title_short N'-[3-(Hydroxyimino)butan-2-ylidene]-4-methylbenzene-1-sulfonohydrazide
title_full N'-[3-(Hydroxyimino)butan-2-ylidene]-4-methylbenzene-1-sulfonohydrazide
title_fullStr N'-[3-(Hydroxyimino)butan-2-ylidene]-4-methylbenzene-1-sulfonohydrazide
title_full_unstemmed N'-[3-(Hydroxyimino)butan-2-ylidene]-4-methylbenzene-1-sulfonohydrazide
title_sort N'-[3-(Hydroxyimino)butan-2-ylidene]-4-methylbenzene-1-sulfonohydrazide
author Bulhosa, Maria C. S.
author_facet Bulhosa, Maria C. S.
Gervini, Vanessa Carratu
Bresolin, Leandro
Locatelli, Aline
Oliveira, Adriano Bof de
author_role author
author2 Gervini, Vanessa Carratu
Bresolin, Leandro
Locatelli, Aline
Oliveira, Adriano Bof de
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Bulhosa, Maria C. S.
Gervini, Vanessa Carratu
Bresolin, Leandro
Locatelli, Aline
Oliveira, Adriano Bof de
dc.subject.por.fl_str_mv C11H15N3O3S
C-S-N(H)-N
topic C11H15N3O3S
C-S-N(H)-N
description In the title compound, C11H15N3O3S, the C-S-N(H)-N linkage is nonplanar, the torsion angle being 75.70 (12)°. The compound has two almost planar fragments linked to the S atom: the hydrazone-derivative fragment [(HONC4H6)N-N(H)-] and the tolyl fragment (C7H7-) have maximum deviations from the mean plane through the non-H atoms of 0.0260 (10) and 0.0148 (14) Å, respectively. The two planar fragments make an interplanar angle of 79.47 (5)°. In the crystal, molecules are connected through inversion centers via pairs of N-HO and O-HN hydrogen bonds.
publishDate 2012
dc.date.issued.fl_str_mv 2012-03
dc.date.accessioned.fl_str_mv 2013-07-12T21:43:06Z
dc.date.available.fl_str_mv 2013-07-12T21:43:06Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.citation.fl_str_mv BULHOSA, M. C. S. et al. N'-[3-(Hydroxyimino)butan-2-ylidene]-4-methylbenzene-1-sulfonohydrazide. Acta Crystallographica Section E, Chester, v. 68, n. 3, p. o592-o592, mar. 2012. Disponível em: <http://journals.iucr.org/e/issues/2012/03/00/fy2042/index.html>. Acesso em: 12 jul. 2013.
dc.identifier.uri.fl_str_mv https://ri.ufs.br/handle/riufs/633
dc.identifier.issn.none.fl_str_mv 1600-5368
dc.identifier.license.pt_BR.fl_str_mv Copyright © International Union of Crystallography
identifier_str_mv BULHOSA, M. C. S. et al. N'-[3-(Hydroxyimino)butan-2-ylidene]-4-methylbenzene-1-sulfonohydrazide. Acta Crystallographica Section E, Chester, v. 68, n. 3, p. o592-o592, mar. 2012. Disponível em: <http://journals.iucr.org/e/issues/2012/03/00/fy2042/index.html>. Acesso em: 12 jul. 2013.
1600-5368
Copyright © International Union of Crystallography
url https://ri.ufs.br/handle/riufs/633
dc.language.iso.fl_str_mv eng
language eng
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.publisher.none.fl_str_mv International Union of Crystallography
publisher.none.fl_str_mv International Union of Crystallography
dc.source.none.fl_str_mv reponame:Repositório Institucional da UFS
instname:Universidade Federal de Sergipe (UFS)
instacron:UFS
instname_str Universidade Federal de Sergipe (UFS)
instacron_str UFS
institution UFS
reponame_str Repositório Institucional da UFS
collection Repositório Institucional da UFS
bitstream.url.fl_str_mv https://ri.ufs.br/jspui/bitstream/riufs/633/4/N%27-%5b3-%28Hydroxyimino%29.pdf.jpg
https://ri.ufs.br/jspui/bitstream/riufs/633/1/N%27-%5b3-%28Hydroxyimino%29.pdf
https://ri.ufs.br/jspui/bitstream/riufs/633/2/license.txt
https://ri.ufs.br/jspui/bitstream/riufs/633/3/N%27-%5b3-%28Hydroxyimino%29.pdf.txt
bitstream.checksum.fl_str_mv a4c9f39eafe35eccfa78e134bbb72bf8
f292b1868fd2da58e257be0525c28309
8a4605be74aa9ea9d79846c1fba20a33
5c71f109f845a36b8bd0796a6cb4cfb1
bitstream.checksumAlgorithm.fl_str_mv MD5
MD5
MD5
MD5
repository.name.fl_str_mv Repositório Institucional da UFS - Universidade Federal de Sergipe (UFS)
repository.mail.fl_str_mv repositorio@academico.ufs.br
_version_ 1793350943805276160

Similar Items