Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil
Autor(a) principal: | |
---|---|
Data de Publicação: | 2013 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UFS |
Texto Completo: | https://ri.ufs.br/handle/riufs/1824 |
Resumo: | The distributions of Al, Cu, Co, Cr, Fe, Mn, Ni, Pb and Zn were measured in two sediment cores obtained from the Macela Reservoir in Northeast Brazil. Principal component analysis (PCA) clearly separated both the cores and the sections corresponding to different depths. The concentrations of Cu, Cr, Mn and Zn were highest in the upper sections (0-20 cm), and were significantly correlated with the total organic carbon (Corg) content. The concentrations of Co, Pb and Ni were highest in the lower sections (25-45 cm), and showed strong correlations with aluminum. Cu, Cr, Mn and Zn were derived from anthropogenic sources, while Co, Ni and Pb were of natural origin. Toxicity assessment based on the threshold effect level (TEL) and probable effect level (PEL) values listed in the Canadian Sediment Quality Guidelines (SQG) showed that Cu, Pb and Zn rarely cause any adverse effects, while Ni was likely to cause frequent effects in the biota of the reservoir. The toxicity of Cr was uncertain. _________________________________________________________________________________________ RESUMO: As distribuições de Al, Cu, Co, Cr, Fe, Mn, Ni, Pb e Zn foram investigadas em dois sítios de sedimentos do reservatório Macela, Nordeste do Brasil. A análise de componentes principais (PCA) separou nitidamente os sítios de sedimentos coletados e as suas diferentes seções. Cu, Cr, Mn e Zn apresentaram as maiores concentrações nas seções do topo (0-20 cm) e mostraram correlações significativas com o conteúdo de carbono orgânico total (Corg). As concentrações de Co, Pb e Ni foram maiores nas seções do fundo (25-45 cm) e mostraram fortes correlações com alumínio. Cu, Cr, Mn e Zn foram provenientes do aporte antropogênico, enquanto que Co, Ni e Pb foram de origem natural. As toxicidades avaliadas com base nos valores do nível limiar de efeitos (TEL) e nível provável de efeitos (PEL) listados no Sediment Quality Guidelines (SQG) canadense mostraram que Cu, Pb e Zn raramente exercem efeitos adversos aos organismos, enquanto que para o Ni, esses efeitos biológicos ocorrem frequentemente à biota do reservatório. A toxicidade do Cr foi incerta. |
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Santos, Izaias Souza dosGarcia, Carlos Alexandre BorgesPassos, Elisangela de AndradeAlves, Jose do Patrocinio Hora2016-07-28T20:50:36Z2016-07-28T20:50:36Z2013-02SANTOS, I. S. et al. Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil. Journal of the Brazilian Chemical Society, São Paulo, v. 24, n. 2, p. 246-255, fev. 2013. Disponível em: <http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000200011>. Acesso em: 13 jul. 2016.1678-4790https://ri.ufs.br/handle/riufs/1824Creative Commons Atribuição-NãoComercial 4.0 InternacionalThe distributions of Al, Cu, Co, Cr, Fe, Mn, Ni, Pb and Zn were measured in two sediment cores obtained from the Macela Reservoir in Northeast Brazil. Principal component analysis (PCA) clearly separated both the cores and the sections corresponding to different depths. The concentrations of Cu, Cr, Mn and Zn were highest in the upper sections (0-20 cm), and were significantly correlated with the total organic carbon (Corg) content. The concentrations of Co, Pb and Ni were highest in the lower sections (25-45 cm), and showed strong correlations with aluminum. Cu, Cr, Mn and Zn were derived from anthropogenic sources, while Co, Ni and Pb were of natural origin. Toxicity assessment based on the threshold effect level (TEL) and probable effect level (PEL) values listed in the Canadian Sediment Quality Guidelines (SQG) showed that Cu, Pb and Zn rarely cause any adverse effects, while Ni was likely to cause frequent effects in the biota of the reservoir. The toxicity of Cr was uncertain. _________________________________________________________________________________________ RESUMO: As distribuições de Al, Cu, Co, Cr, Fe, Mn, Ni, Pb e Zn foram investigadas em dois sítios de sedimentos do reservatório Macela, Nordeste do Brasil. A análise de componentes principais (PCA) separou nitidamente os sítios de sedimentos coletados e as suas diferentes seções. Cu, Cr, Mn e Zn apresentaram as maiores concentrações nas seções do topo (0-20 cm) e mostraram correlações significativas com o conteúdo de carbono orgânico total (Corg). As concentrações de Co, Pb e Ni foram maiores nas seções do fundo (25-45 cm) e mostraram fortes correlações com alumínio. Cu, Cr, Mn e Zn foram provenientes do aporte antropogênico, enquanto que Co, Ni e Pb foram de origem natural. As toxicidades avaliadas com base nos valores do nível limiar de efeitos (TEL) e nível provável de efeitos (PEL) listados no Sediment Quality Guidelines (SQG) canadense mostraram que Cu, Pb e Zn raramente exercem efeitos adversos aos organismos, enquanto que para o Ni, esses efeitos biológicos ocorrem frequentemente à biota do reservatório. A toxicidade do Cr foi incerta.Instituto de Química - UNICAMPSedimentosMetaisBiodisponibilidadeToxicidadeReservoir sedimentTrace metalsPCABioavailabilityToxicityDistributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazilinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleengreponame:Repositório Institucional da UFSinstname:Universidade Federal de Sergipe (UFS)instacron:UFSinfo:eu-repo/semantics/openAccessTHUMBNAILDistributionTraceMetals.pdf.jpgDistributionTraceMetals.pdf.jpgGenerated Thumbnailimage/jpeg1596https://ri.ufs.br/jspui/bitstream/riufs/1824/4/DistributionTraceMetals.pdf.jpga520f67881e9c5a39fa240a31f6d8591MD54LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://ri.ufs.br/jspui/bitstream/riufs/1824/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52TEXTDistributionTraceMetals.pdf.txtDistributionTraceMetals.pdf.txtExtracted texttext/plain39244https://ri.ufs.br/jspui/bitstream/riufs/1824/3/DistributionTraceMetals.pdf.txt65798ab559c70bba1a8bd17c79c22027MD53ORIGINALDistributionTraceMetals.pdfDistributionTraceMetals.pdfapplication/pdf426816https://ri.ufs.br/jspui/bitstream/riufs/1824/1/DistributionTraceMetals.pdf97a6e4675ceea7b20675e4ac266574eeMD51riufs/18242016-07-29 19:35:19.204oai:ufs.br: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Repositório InstitucionalPUBhttps://ri.ufs.br/oai/requestrepositorio@academico.ufs.bropendoar:2016-07-29T22:35:19Repositório Institucional da UFS - Universidade Federal de Sergipe (UFS)false |
dc.title.pt_BR.fl_str_mv |
Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil |
title |
Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil |
spellingShingle |
Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil Santos, Izaias Souza dos Sedimentos Metais Biodisponibilidade Toxicidade Reservoir sediment Trace metals PCA Bioavailability Toxicity |
title_short |
Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil |
title_full |
Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil |
title_fullStr |
Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil |
title_full_unstemmed |
Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil |
title_sort |
Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil |
author |
Santos, Izaias Souza dos |
author_facet |
Santos, Izaias Souza dos Garcia, Carlos Alexandre Borges Passos, Elisangela de Andrade Alves, Jose do Patrocinio Hora |
author_role |
author |
author2 |
Garcia, Carlos Alexandre Borges Passos, Elisangela de Andrade Alves, Jose do Patrocinio Hora |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Santos, Izaias Souza dos Garcia, Carlos Alexandre Borges Passos, Elisangela de Andrade Alves, Jose do Patrocinio Hora |
dc.subject.por.fl_str_mv |
Sedimentos Metais Biodisponibilidade Toxicidade Reservoir sediment Trace metals PCA Bioavailability Toxicity |
topic |
Sedimentos Metais Biodisponibilidade Toxicidade Reservoir sediment Trace metals PCA Bioavailability Toxicity |
description |
The distributions of Al, Cu, Co, Cr, Fe, Mn, Ni, Pb and Zn were measured in two sediment cores obtained from the Macela Reservoir in Northeast Brazil. Principal component analysis (PCA) clearly separated both the cores and the sections corresponding to different depths. The concentrations of Cu, Cr, Mn and Zn were highest in the upper sections (0-20 cm), and were significantly correlated with the total organic carbon (Corg) content. The concentrations of Co, Pb and Ni were highest in the lower sections (25-45 cm), and showed strong correlations with aluminum. Cu, Cr, Mn and Zn were derived from anthropogenic sources, while Co, Ni and Pb were of natural origin. Toxicity assessment based on the threshold effect level (TEL) and probable effect level (PEL) values listed in the Canadian Sediment Quality Guidelines (SQG) showed that Cu, Pb and Zn rarely cause any adverse effects, while Ni was likely to cause frequent effects in the biota of the reservoir. The toxicity of Cr was uncertain. _________________________________________________________________________________________ RESUMO: As distribuições de Al, Cu, Co, Cr, Fe, Mn, Ni, Pb e Zn foram investigadas em dois sítios de sedimentos do reservatório Macela, Nordeste do Brasil. A análise de componentes principais (PCA) separou nitidamente os sítios de sedimentos coletados e as suas diferentes seções. Cu, Cr, Mn e Zn apresentaram as maiores concentrações nas seções do topo (0-20 cm) e mostraram correlações significativas com o conteúdo de carbono orgânico total (Corg). As concentrações de Co, Pb e Ni foram maiores nas seções do fundo (25-45 cm) e mostraram fortes correlações com alumínio. Cu, Cr, Mn e Zn foram provenientes do aporte antropogênico, enquanto que Co, Ni e Pb foram de origem natural. As toxicidades avaliadas com base nos valores do nível limiar de efeitos (TEL) e nível provável de efeitos (PEL) listados no Sediment Quality Guidelines (SQG) canadense mostraram que Cu, Pb e Zn raramente exercem efeitos adversos aos organismos, enquanto que para o Ni, esses efeitos biológicos ocorrem frequentemente à biota do reservatório. A toxicidade do Cr foi incerta. |
publishDate |
2013 |
dc.date.issued.fl_str_mv |
2013-02 |
dc.date.accessioned.fl_str_mv |
2016-07-28T20:50:36Z |
dc.date.available.fl_str_mv |
2016-07-28T20:50:36Z |
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info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
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article |
status_str |
publishedVersion |
dc.identifier.citation.fl_str_mv |
SANTOS, I. S. et al. Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil. Journal of the Brazilian Chemical Society, São Paulo, v. 24, n. 2, p. 246-255, fev. 2013. Disponível em: <http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000200011>. Acesso em: 13 jul. 2016. |
dc.identifier.uri.fl_str_mv |
https://ri.ufs.br/handle/riufs/1824 |
dc.identifier.issn.none.fl_str_mv |
1678-4790 |
dc.identifier.license.pt_BR.fl_str_mv |
Creative Commons Atribuição-NãoComercial 4.0 Internacional |
identifier_str_mv |
SANTOS, I. S. et al. Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil. Journal of the Brazilian Chemical Society, São Paulo, v. 24, n. 2, p. 246-255, fev. 2013. Disponível em: <http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000200011>. Acesso em: 13 jul. 2016. 1678-4790 Creative Commons Atribuição-NãoComercial 4.0 Internacional |
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eng |
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Instituto de Química - UNICAMP |
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Instituto de Química - UNICAMP |
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