Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil

Detalhes bibliográficos
Autor(a) principal: Santos, Izaias Souza dos
Data de Publicação: 2013
Outros Autores: Garcia, Carlos Alexandre Borges, Passos, Elisangela de Andrade, Alves, Jose do Patrocinio Hora
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UFS
Texto Completo: https://ri.ufs.br/handle/riufs/1824
Resumo: The distributions of Al, Cu, Co, Cr, Fe, Mn, Ni, Pb and Zn were measured in two sediment cores obtained from the Macela Reservoir in Northeast Brazil. Principal component analysis (PCA) clearly separated both the cores and the sections corresponding to different depths. The concentrations of Cu, Cr, Mn and Zn were highest in the upper sections (0-20 cm), and were significantly correlated with the total organic carbon (Corg) content. The concentrations of Co, Pb and Ni were highest in the lower sections (25-45 cm), and showed strong correlations with aluminum. Cu, Cr, Mn and Zn were derived from anthropogenic sources, while Co, Ni and Pb were of natural origin. Toxicity assessment based on the threshold effect level (TEL) and probable effect level (PEL) values listed in the Canadian Sediment Quality Guidelines (SQG) showed that Cu, Pb and Zn rarely cause any adverse effects, while Ni was likely to cause frequent effects in the biota of the reservoir. The toxicity of Cr was uncertain. _________________________________________________________________________________________ RESUMO: As distribuições de Al, Cu, Co, Cr, Fe, Mn, Ni, Pb e Zn foram investigadas em dois sítios de sedimentos do reservatório Macela, Nordeste do Brasil. A análise de componentes principais (PCA) separou nitidamente os sítios de sedimentos coletados e as suas diferentes seções. Cu, Cr, Mn e Zn apresentaram as maiores concentrações nas seções do topo (0-20 cm) e mostraram correlações significativas com o conteúdo de carbono orgânico total (Corg). As concentrações de Co, Pb e Ni foram maiores nas seções do fundo (25-45 cm) e mostraram fortes correlações com alumínio. Cu, Cr, Mn e Zn foram provenientes do aporte antropogênico, enquanto que Co, Ni e Pb foram de origem natural. As toxicidades avaliadas com base nos valores do nível limiar de efeitos (TEL) e nível provável de efeitos (PEL) listados no Sediment Quality Guidelines (SQG) canadense mostraram que Cu, Pb e Zn raramente exercem efeitos adversos aos organismos, enquanto que para o Ni, esses efeitos biológicos ocorrem frequentemente à biota do reservatório. A toxicidade do Cr foi incerta.
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spelling Santos, Izaias Souza dosGarcia, Carlos Alexandre BorgesPassos, Elisangela de AndradeAlves, Jose do Patrocinio Hora2016-07-28T20:50:36Z2016-07-28T20:50:36Z2013-02SANTOS, I. S. et al. Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil. Journal of the Brazilian Chemical Society, São Paulo, v. 24, n. 2, p. 246-255, fev. 2013. Disponível em: <http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000200011>. Acesso em: 13 jul. 2016.1678-4790https://ri.ufs.br/handle/riufs/1824Creative Commons Atribuição-NãoComercial 4.0 InternacionalThe distributions of Al, Cu, Co, Cr, Fe, Mn, Ni, Pb and Zn were measured in two sediment cores obtained from the Macela Reservoir in Northeast Brazil. Principal component analysis (PCA) clearly separated both the cores and the sections corresponding to different depths. The concentrations of Cu, Cr, Mn and Zn were highest in the upper sections (0-20 cm), and were significantly correlated with the total organic carbon (Corg) content. The concentrations of Co, Pb and Ni were highest in the lower sections (25-45 cm), and showed strong correlations with aluminum. Cu, Cr, Mn and Zn were derived from anthropogenic sources, while Co, Ni and Pb were of natural origin. Toxicity assessment based on the threshold effect level (TEL) and probable effect level (PEL) values listed in the Canadian Sediment Quality Guidelines (SQG) showed that Cu, Pb and Zn rarely cause any adverse effects, while Ni was likely to cause frequent effects in the biota of the reservoir. The toxicity of Cr was uncertain. _________________________________________________________________________________________ RESUMO: As distribuições de Al, Cu, Co, Cr, Fe, Mn, Ni, Pb e Zn foram investigadas em dois sítios de sedimentos do reservatório Macela, Nordeste do Brasil. A análise de componentes principais (PCA) separou nitidamente os sítios de sedimentos coletados e as suas diferentes seções. Cu, Cr, Mn e Zn apresentaram as maiores concentrações nas seções do topo (0-20 cm) e mostraram correlações significativas com o conteúdo de carbono orgânico total (Corg). As concentrações de Co, Pb e Ni foram maiores nas seções do fundo (25-45 cm) e mostraram fortes correlações com alumínio. Cu, Cr, Mn e Zn foram provenientes do aporte antropogênico, enquanto que Co, Ni e Pb foram de origem natural. As toxicidades avaliadas com base nos valores do nível limiar de efeitos (TEL) e nível provável de efeitos (PEL) listados no Sediment Quality Guidelines (SQG) canadense mostraram que Cu, Pb e Zn raramente exercem efeitos adversos aos organismos, enquanto que para o Ni, esses efeitos biológicos ocorrem frequentemente à biota do reservatório. A toxicidade do Cr foi incerta.Instituto de Química - UNICAMPSedimentosMetaisBiodisponibilidadeToxicidadeReservoir sedimentTrace metalsPCABioavailabilityToxicityDistributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazilinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleengreponame:Repositório Institucional da UFSinstname:Universidade Federal de Sergipe (UFS)instacron:UFSinfo:eu-repo/semantics/openAccessTHUMBNAILDistributionTraceMetals.pdf.jpgDistributionTraceMetals.pdf.jpgGenerated Thumbnailimage/jpeg1596https://ri.ufs.br/jspui/bitstream/riufs/1824/4/DistributionTraceMetals.pdf.jpga520f67881e9c5a39fa240a31f6d8591MD54LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://ri.ufs.br/jspui/bitstream/riufs/1824/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52TEXTDistributionTraceMetals.pdf.txtDistributionTraceMetals.pdf.txtExtracted texttext/plain39244https://ri.ufs.br/jspui/bitstream/riufs/1824/3/DistributionTraceMetals.pdf.txt65798ab559c70bba1a8bd17c79c22027MD53ORIGINALDistributionTraceMetals.pdfDistributionTraceMetals.pdfapplication/pdf426816https://ri.ufs.br/jspui/bitstream/riufs/1824/1/DistributionTraceMetals.pdf97a6e4675ceea7b20675e4ac266574eeMD51riufs/18242016-07-29 19:35:19.204oai:ufs.br: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Repositório InstitucionalPUBhttps://ri.ufs.br/oai/requestrepositorio@academico.ufs.bropendoar:2016-07-29T22:35:19Repositório Institucional da UFS - Universidade Federal de Sergipe (UFS)false
dc.title.pt_BR.fl_str_mv Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil
title Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil
spellingShingle Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil
Santos, Izaias Souza dos
Sedimentos
Metais
Biodisponibilidade
Toxicidade
Reservoir sediment
Trace metals
PCA
Bioavailability
Toxicity
title_short Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil
title_full Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil
title_fullStr Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil
title_full_unstemmed Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil
title_sort Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil
author Santos, Izaias Souza dos
author_facet Santos, Izaias Souza dos
Garcia, Carlos Alexandre Borges
Passos, Elisangela de Andrade
Alves, Jose do Patrocinio Hora
author_role author
author2 Garcia, Carlos Alexandre Borges
Passos, Elisangela de Andrade
Alves, Jose do Patrocinio Hora
author2_role author
author
author
dc.contributor.author.fl_str_mv Santos, Izaias Souza dos
Garcia, Carlos Alexandre Borges
Passos, Elisangela de Andrade
Alves, Jose do Patrocinio Hora
dc.subject.por.fl_str_mv Sedimentos
Metais
Biodisponibilidade
Toxicidade
Reservoir sediment
Trace metals
PCA
Bioavailability
Toxicity
topic Sedimentos
Metais
Biodisponibilidade
Toxicidade
Reservoir sediment
Trace metals
PCA
Bioavailability
Toxicity
description The distributions of Al, Cu, Co, Cr, Fe, Mn, Ni, Pb and Zn were measured in two sediment cores obtained from the Macela Reservoir in Northeast Brazil. Principal component analysis (PCA) clearly separated both the cores and the sections corresponding to different depths. The concentrations of Cu, Cr, Mn and Zn were highest in the upper sections (0-20 cm), and were significantly correlated with the total organic carbon (Corg) content. The concentrations of Co, Pb and Ni were highest in the lower sections (25-45 cm), and showed strong correlations with aluminum. Cu, Cr, Mn and Zn were derived from anthropogenic sources, while Co, Ni and Pb were of natural origin. Toxicity assessment based on the threshold effect level (TEL) and probable effect level (PEL) values listed in the Canadian Sediment Quality Guidelines (SQG) showed that Cu, Pb and Zn rarely cause any adverse effects, while Ni was likely to cause frequent effects in the biota of the reservoir. The toxicity of Cr was uncertain. _________________________________________________________________________________________ RESUMO: As distribuições de Al, Cu, Co, Cr, Fe, Mn, Ni, Pb e Zn foram investigadas em dois sítios de sedimentos do reservatório Macela, Nordeste do Brasil. A análise de componentes principais (PCA) separou nitidamente os sítios de sedimentos coletados e as suas diferentes seções. Cu, Cr, Mn e Zn apresentaram as maiores concentrações nas seções do topo (0-20 cm) e mostraram correlações significativas com o conteúdo de carbono orgânico total (Corg). As concentrações de Co, Pb e Ni foram maiores nas seções do fundo (25-45 cm) e mostraram fortes correlações com alumínio. Cu, Cr, Mn e Zn foram provenientes do aporte antropogênico, enquanto que Co, Ni e Pb foram de origem natural. As toxicidades avaliadas com base nos valores do nível limiar de efeitos (TEL) e nível provável de efeitos (PEL) listados no Sediment Quality Guidelines (SQG) canadense mostraram que Cu, Pb e Zn raramente exercem efeitos adversos aos organismos, enquanto que para o Ni, esses efeitos biológicos ocorrem frequentemente à biota do reservatório. A toxicidade do Cr foi incerta.
publishDate 2013
dc.date.issued.fl_str_mv 2013-02
dc.date.accessioned.fl_str_mv 2016-07-28T20:50:36Z
dc.date.available.fl_str_mv 2016-07-28T20:50:36Z
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dc.identifier.citation.fl_str_mv SANTOS, I. S. et al. Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil. Journal of the Brazilian Chemical Society, São Paulo, v. 24, n. 2, p. 246-255, fev. 2013. Disponível em: <http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000200011>. Acesso em: 13 jul. 2016.
dc.identifier.uri.fl_str_mv https://ri.ufs.br/handle/riufs/1824
dc.identifier.issn.none.fl_str_mv 1678-4790
dc.identifier.license.pt_BR.fl_str_mv Creative Commons Atribuição-NãoComercial 4.0 Internacional
identifier_str_mv SANTOS, I. S. et al. Distributions of trace metals in sediment cores from a hypertrophic reservoir in northeast Brazil. Journal of the Brazilian Chemical Society, São Paulo, v. 24, n. 2, p. 246-255, fev. 2013. Disponível em: <http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0103-50532013000200011>. Acesso em: 13 jul. 2016.
1678-4790
Creative Commons Atribuição-NãoComercial 4.0 Internacional
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