INFLUENCE OF INTERMEDIATE WASHING IN OXYGEN DELIGNIFICATION ON KRAFT PULP
Autor(a) principal: | |
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Data de Publicação: | 2015 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Ciência Florestal (Online) |
Texto Completo: | https://periodicos.ufsm.br/cienciaflorestal/article/view/20660 |
Resumo: | http://dx.doi.org/10.5902/1980509820660In the oxygen delignification lignin is removed from the pulp by applying high pressure oxygen, under alkaline conditions, resulting in a lower demand for chemicals in bleaching. The main objective of this study was to evaluate the influence of washing (conventional and acid) between two stages of O2 on the amount of residual lignin and transition metal present in samples of Pine Kraft pulp with 48.5 initial kappa. The reduction of kappa number and pulp degradation after two stages of O2 treatment with increase of final brightness on sheet produced were observed. The metal content of pulp during oxygen delignification was influenced by washing process, and the acid wash removed more percentage of metallic ions than conventional wash. The best results were obtained with the removal of the element manganese. The acid wash between two stages of delignification contributed to the control of transition metals, which optimize the use of bleaching reagents in the following steps. We concluded that the intermediate washing improves the performance of the oxygen delignification of high kappa number pulps performed in two stages. |
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INFLUENCE OF INTERMEDIATE WASHING IN OXYGEN DELIGNIFICATION ON KRAFT PULPINFLUÊNCIA DA LAVAGEM INTERMEDIÁRIA NA DESLIGNIFICAÇÃO COM OXIGÊNIO EM POLPA KRAFTpulp washingoxygen delignificationhigh kappatransition metals.lavagem da polpadeslignificação com oxigênionúmero kappa elevadometais de transição.http://dx.doi.org/10.5902/1980509820660In the oxygen delignification lignin is removed from the pulp by applying high pressure oxygen, under alkaline conditions, resulting in a lower demand for chemicals in bleaching. The main objective of this study was to evaluate the influence of washing (conventional and acid) between two stages of O2 on the amount of residual lignin and transition metal present in samples of Pine Kraft pulp with 48.5 initial kappa. The reduction of kappa number and pulp degradation after two stages of O2 treatment with increase of final brightness on sheet produced were observed. The metal content of pulp during oxygen delignification was influenced by washing process, and the acid wash removed more percentage of metallic ions than conventional wash. The best results were obtained with the removal of the element manganese. The acid wash between two stages of delignification contributed to the control of transition metals, which optimize the use of bleaching reagents in the following steps. We concluded that the intermediate washing improves the performance of the oxygen delignification of high kappa number pulps performed in two stages. http://dx.doi.org/10.5902/1980509820660Na deslignificação com oxigênio, a lignina é removida da polpa através da aplicação de elevada pressão de oxigênio, em condições alcalinas, resultando em uma menor demanda por produtos químicos na etapa de branqueamento. O objetivo principal deste trabalho foi avaliar a influência do tipo de lavagem (convencional e ácida) entre dois estágios de deslignificação com oxigênio sobre a quantidade de lignina residual e o teor de metais de transição presentes em amostras de polpa kraft de pinus com número kappa inicial de 48,5. Observou-se a redução do número kappa e da viscosidade da polpa após o tratamento com O2 em duplo estágio, além do aumento da alvura final das polpas produzidas. O teor de metais da polpa durante a deslignificação com oxigênio sofreu influência do processo de lavagem, sendo que a lavagem ácida retirou maior quantidade de íons metálicos do que a lavagem convencional. Os melhores resultados foram obtidos com a retirada do elemento manganês. A lavagem ácida entre dois estágios de deslignificação contribuiu para o controle de metais de transição, o que otimizou a utilização de reagentes químicos do branqueamento nas etapas seguintes. Conclui-se que a lavagem intermediária melhorou o desempenho do oxigênio na deslignificação de polpas de número kappa elevado realizada em dois estágios.Universidade Federal de Santa Maria2015-12-30info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://periodicos.ufsm.br/cienciaflorestal/article/view/2066010.5902/1980509820660Ciência Florestal; Vol. 25 No. 4 (2015); 991-999Ciência Florestal; v. 25 n. 4 (2015); 991-9991980-50980103-9954reponame:Ciência Florestal (Online)instname:Universidade Federal de Santa Maria (UFSM)instacron:UFSMporhttps://periodicos.ufsm.br/cienciaflorestal/article/view/20660/pdfVenson, IvanAndrade, Alan Sulato deKlock, UmbertoMuñiz, Graciela Inés Bolzón deNisgoski, SilvanaCardoso, Gilson da Silvainfo:eu-repo/semantics/openAccess2017-04-10T13:43:07Zoai:ojs.pkp.sfu.ca:article/20660Revistahttp://www.ufsm.br/cienciaflorestal/ONGhttps://old.scielo.br/oai/scielo-oai.php||cienciaflorestal@ufsm.br|| cienciaflorestal@gmail.com|| cf@smail.ufsm.br1980-50980103-9954opendoar:2017-04-10T13:43:07Ciência Florestal (Online) - Universidade Federal de Santa Maria (UFSM)false |
dc.title.none.fl_str_mv |
INFLUENCE OF INTERMEDIATE WASHING IN OXYGEN DELIGNIFICATION ON KRAFT PULP INFLUÊNCIA DA LAVAGEM INTERMEDIÁRIA NA DESLIGNIFICAÇÃO COM OXIGÊNIO EM POLPA KRAFT |
title |
INFLUENCE OF INTERMEDIATE WASHING IN OXYGEN DELIGNIFICATION ON KRAFT PULP |
spellingShingle |
INFLUENCE OF INTERMEDIATE WASHING IN OXYGEN DELIGNIFICATION ON KRAFT PULP Venson, Ivan pulp washing oxygen delignification high kappa transition metals. lavagem da polpa deslignificação com oxigênio número kappa elevado metais de transição. |
title_short |
INFLUENCE OF INTERMEDIATE WASHING IN OXYGEN DELIGNIFICATION ON KRAFT PULP |
title_full |
INFLUENCE OF INTERMEDIATE WASHING IN OXYGEN DELIGNIFICATION ON KRAFT PULP |
title_fullStr |
INFLUENCE OF INTERMEDIATE WASHING IN OXYGEN DELIGNIFICATION ON KRAFT PULP |
title_full_unstemmed |
INFLUENCE OF INTERMEDIATE WASHING IN OXYGEN DELIGNIFICATION ON KRAFT PULP |
title_sort |
INFLUENCE OF INTERMEDIATE WASHING IN OXYGEN DELIGNIFICATION ON KRAFT PULP |
author |
Venson, Ivan |
author_facet |
Venson, Ivan Andrade, Alan Sulato de Klock, Umberto Muñiz, Graciela Inés Bolzón de Nisgoski, Silvana Cardoso, Gilson da Silva |
author_role |
author |
author2 |
Andrade, Alan Sulato de Klock, Umberto Muñiz, Graciela Inés Bolzón de Nisgoski, Silvana Cardoso, Gilson da Silva |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Venson, Ivan Andrade, Alan Sulato de Klock, Umberto Muñiz, Graciela Inés Bolzón de Nisgoski, Silvana Cardoso, Gilson da Silva |
dc.subject.por.fl_str_mv |
pulp washing oxygen delignification high kappa transition metals. lavagem da polpa deslignificação com oxigênio número kappa elevado metais de transição. |
topic |
pulp washing oxygen delignification high kappa transition metals. lavagem da polpa deslignificação com oxigênio número kappa elevado metais de transição. |
description |
http://dx.doi.org/10.5902/1980509820660In the oxygen delignification lignin is removed from the pulp by applying high pressure oxygen, under alkaline conditions, resulting in a lower demand for chemicals in bleaching. The main objective of this study was to evaluate the influence of washing (conventional and acid) between two stages of O2 on the amount of residual lignin and transition metal present in samples of Pine Kraft pulp with 48.5 initial kappa. The reduction of kappa number and pulp degradation after two stages of O2 treatment with increase of final brightness on sheet produced were observed. The metal content of pulp during oxygen delignification was influenced by washing process, and the acid wash removed more percentage of metallic ions than conventional wash. The best results were obtained with the removal of the element manganese. The acid wash between two stages of delignification contributed to the control of transition metals, which optimize the use of bleaching reagents in the following steps. We concluded that the intermediate washing improves the performance of the oxygen delignification of high kappa number pulps performed in two stages. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-12-30 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://periodicos.ufsm.br/cienciaflorestal/article/view/20660 10.5902/1980509820660 |
url |
https://periodicos.ufsm.br/cienciaflorestal/article/view/20660 |
identifier_str_mv |
10.5902/1980509820660 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
https://periodicos.ufsm.br/cienciaflorestal/article/view/20660/pdf |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Federal de Santa Maria |
publisher.none.fl_str_mv |
Universidade Federal de Santa Maria |
dc.source.none.fl_str_mv |
Ciência Florestal; Vol. 25 No. 4 (2015); 991-999 Ciência Florestal; v. 25 n. 4 (2015); 991-999 1980-5098 0103-9954 reponame:Ciência Florestal (Online) instname:Universidade Federal de Santa Maria (UFSM) instacron:UFSM |
instname_str |
Universidade Federal de Santa Maria (UFSM) |
instacron_str |
UFSM |
institution |
UFSM |
reponame_str |
Ciência Florestal (Online) |
collection |
Ciência Florestal (Online) |
repository.name.fl_str_mv |
Ciência Florestal (Online) - Universidade Federal de Santa Maria (UFSM) |
repository.mail.fl_str_mv |
||cienciaflorestal@ufsm.br|| cienciaflorestal@gmail.com|| cf@smail.ufsm.br |
_version_ |
1799944130485288960 |