Mid-infrared spectroscopy and colorimetry of curupixá wood: artificial weathering along with finishing products

Detalhes bibliográficos
Autor(a) principal: Mesquita, Robert Rossi Silva de
Data de Publicação: 2020
Outros Autores: Paula, Marcella Hermida de, Gonçalez, Joaquim Carlos
Tipo de documento: Artigo
Idioma: por
Título da fonte: Ciência Florestal (Online)
Texto Completo: https://periodicos.ufsm.br/cienciaflorestal/article/view/31248
Resumo: This study investigates the changes in color and in the chemical structures of the surface of curupixá wood (Micropholis sp.), which was exposed to artificial weathering with two wood finishing products. We treated the sample surfaces with varnish and stain, and then we set them to artificial weathering for 700 hours, in accordance with ASTM G154 (2006). Our team used The Fourier Transform Mean Infrared (FT-MIR) and the CIELAB (1976) system in order to outline changes in the chemical and colorimetric structure of the wood surface, respectively. The color of curupixá wood got darker after applying finishing products. The color variation following the weathering process was appreciable in the control sample and very appreciable in the treated wood sample. The analysis of medium infrared spectroscopy demonstrated the depolymerization of lignin accompanied by the formation of carbonyls in all cases. In addition, mid-infrared displayed a concentration drop due to the heavy metal leaching. These ocurrences reveal degradation in the structural chemical components of the wood, and that the finishing products did not affect the weathering process at all.
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spelling Mid-infrared spectroscopy and colorimetry of curupixá wood: artificial weathering along with finishing productsColorimetria e espectroscopia no infravermelho médio em madeira de curupixá frente ao intemperismo artificial com produtos de acabamentoWood surfacePhotodegradationVarnishStainSuperfície da madeiraFotodegradaçãoVernizStainThis study investigates the changes in color and in the chemical structures of the surface of curupixá wood (Micropholis sp.), which was exposed to artificial weathering with two wood finishing products. We treated the sample surfaces with varnish and stain, and then we set them to artificial weathering for 700 hours, in accordance with ASTM G154 (2006). Our team used The Fourier Transform Mean Infrared (FT-MIR) and the CIELAB (1976) system in order to outline changes in the chemical and colorimetric structure of the wood surface, respectively. The color of curupixá wood got darker after applying finishing products. The color variation following the weathering process was appreciable in the control sample and very appreciable in the treated wood sample. The analysis of medium infrared spectroscopy demonstrated the depolymerization of lignin accompanied by the formation of carbonyls in all cases. In addition, mid-infrared displayed a concentration drop due to the heavy metal leaching. These ocurrences reveal degradation in the structural chemical components of the wood, and that the finishing products did not affect the weathering process at all.O objetivo do estudo foi investigar alterações de cor e de estruturas químicas da superfície da madeira de curupixá (Micropholis sp.), submetida ao intemperismo artificial, com dois produtos de acabamento. As superfícies das amostras foram tratadas com verniz e stain, e submetidas ao intemperismo artificial por 700 horas de acordo com a norma ASTM G154 (2006). O infravermelho médio com transformada de Fourier (FT-MIR) e o sistema CIELAB (1976) foram utilizados para caracterizar mudanças na estrutura química e colorimétricas da superfície da madeira, respectivamente. Em relação à cor, a madeira de curupixá escureceu com a aplicação dos produtos de acabamento. O intemperismo alterou de forma apreciável a cor da testemunha, e de forma muito apreciável a madeira tratada com os dois produtos de acabamento. A análise de espectroscopia no infravermelho médio mostrou que, em todos os casos, sucedeu a despolimerização da lignina acompanhada da formação de carbonilas, além de queda em suas concentrações devido à lixiviação dos metais pesados. Tudo isso indica que houve degradação dos componentes químicos estruturais da madeira e que não houve influência dos produtos de acabamento no processo de intemperismo.Universidade Federal de Santa Maria2020-09-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://periodicos.ufsm.br/cienciaflorestal/article/view/3124810.5902/1980509831248Ciência Florestal; Vol. 30 No. 3 (2020); 688-699Ciência Florestal; v. 30 n. 3 (2020); 688-6991980-50980103-9954reponame:Ciência Florestal (Online)instname:Universidade Federal de Santa Maria (UFSM)instacron:UFSMporhttps://periodicos.ufsm.br/cienciaflorestal/article/view/31248/33575Copyright (c) 2020 Ciência Florestalinfo:eu-repo/semantics/openAccessMesquita, Robert Rossi Silva dePaula, Marcella Hermida deGonçalez, Joaquim Carlos2020-09-02T20:52:05Zoai:ojs.pkp.sfu.ca:article/31248Revistahttp://www.ufsm.br/cienciaflorestal/ONGhttps://old.scielo.br/oai/scielo-oai.php||cienciaflorestal@ufsm.br|| cienciaflorestal@gmail.com|| cf@smail.ufsm.br1980-50980103-9954opendoar:2020-09-02T20:52:05Ciência Florestal (Online) - Universidade Federal de Santa Maria (UFSM)false
dc.title.none.fl_str_mv Mid-infrared spectroscopy and colorimetry of curupixá wood: artificial weathering along with finishing products
Colorimetria e espectroscopia no infravermelho médio em madeira de curupixá frente ao intemperismo artificial com produtos de acabamento
title Mid-infrared spectroscopy and colorimetry of curupixá wood: artificial weathering along with finishing products
spellingShingle Mid-infrared spectroscopy and colorimetry of curupixá wood: artificial weathering along with finishing products
Mesquita, Robert Rossi Silva de
Wood surface
Photodegradation
Varnish
Stain
Superfície da madeira
Fotodegradação
Verniz
Stain
title_short Mid-infrared spectroscopy and colorimetry of curupixá wood: artificial weathering along with finishing products
title_full Mid-infrared spectroscopy and colorimetry of curupixá wood: artificial weathering along with finishing products
title_fullStr Mid-infrared spectroscopy and colorimetry of curupixá wood: artificial weathering along with finishing products
title_full_unstemmed Mid-infrared spectroscopy and colorimetry of curupixá wood: artificial weathering along with finishing products
title_sort Mid-infrared spectroscopy and colorimetry of curupixá wood: artificial weathering along with finishing products
author Mesquita, Robert Rossi Silva de
author_facet Mesquita, Robert Rossi Silva de
Paula, Marcella Hermida de
Gonçalez, Joaquim Carlos
author_role author
author2 Paula, Marcella Hermida de
Gonçalez, Joaquim Carlos
author2_role author
author
dc.contributor.author.fl_str_mv Mesquita, Robert Rossi Silva de
Paula, Marcella Hermida de
Gonçalez, Joaquim Carlos
dc.subject.por.fl_str_mv Wood surface
Photodegradation
Varnish
Stain
Superfície da madeira
Fotodegradação
Verniz
Stain
topic Wood surface
Photodegradation
Varnish
Stain
Superfície da madeira
Fotodegradação
Verniz
Stain
description This study investigates the changes in color and in the chemical structures of the surface of curupixá wood (Micropholis sp.), which was exposed to artificial weathering with two wood finishing products. We treated the sample surfaces with varnish and stain, and then we set them to artificial weathering for 700 hours, in accordance with ASTM G154 (2006). Our team used The Fourier Transform Mean Infrared (FT-MIR) and the CIELAB (1976) system in order to outline changes in the chemical and colorimetric structure of the wood surface, respectively. The color of curupixá wood got darker after applying finishing products. The color variation following the weathering process was appreciable in the control sample and very appreciable in the treated wood sample. The analysis of medium infrared spectroscopy demonstrated the depolymerization of lignin accompanied by the formation of carbonyls in all cases. In addition, mid-infrared displayed a concentration drop due to the heavy metal leaching. These ocurrences reveal degradation in the structural chemical components of the wood, and that the finishing products did not affect the weathering process at all.
publishDate 2020
dc.date.none.fl_str_mv 2020-09-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://periodicos.ufsm.br/cienciaflorestal/article/view/31248
10.5902/1980509831248
url https://periodicos.ufsm.br/cienciaflorestal/article/view/31248
identifier_str_mv 10.5902/1980509831248
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv https://periodicos.ufsm.br/cienciaflorestal/article/view/31248/33575
dc.rights.driver.fl_str_mv Copyright (c) 2020 Ciência Florestal
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Copyright (c) 2020 Ciência Florestal
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Federal de Santa Maria
publisher.none.fl_str_mv Universidade Federal de Santa Maria
dc.source.none.fl_str_mv Ciência Florestal; Vol. 30 No. 3 (2020); 688-699
Ciência Florestal; v. 30 n. 3 (2020); 688-699
1980-5098
0103-9954
reponame:Ciência Florestal (Online)
instname:Universidade Federal de Santa Maria (UFSM)
instacron:UFSM
instname_str Universidade Federal de Santa Maria (UFSM)
instacron_str UFSM
institution UFSM
reponame_str Ciência Florestal (Online)
collection Ciência Florestal (Online)
repository.name.fl_str_mv Ciência Florestal (Online) - Universidade Federal de Santa Maria (UFSM)
repository.mail.fl_str_mv ||cienciaflorestal@ufsm.br|| cienciaflorestal@gmail.com|| cf@smail.ufsm.br
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