Electrical, Thermal and Mechanical Properties of Epoxy/CNT/Calcium Carbonate Nanocomposites
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNIFESP |
Texto Completo: | http://dx.doi.org/10.1590/1980-5373-MR-2017-0801 https://repositorio.unifesp.br/handle/11600/54303 |
Resumo: | Epoxy/CNT and epoxy/CNT/calcium carbonate nanocomposites were produced via in situ polymerization assisted by ultrasonication without solvent and electrical, mechanical, thermal and thermomechanical properties of nanocomposites were evaluated. Epoxy/CNT presented very low percolation threshold, near 0.05 wt % and nanocomposites with higher contents of CNT presented further increase m electrical conductivity. The addition of calcium carbonate in epoxy/CNT nanocomposites increased the electrical conductivity, due to volume exclusion phenomena. Regarding thermal properties, due to the low content of the CNT and calcium carbonate no changes in glass transition (Tg) were observed. DMA results showed no significant changes in thermomechanical properties, once the contents of CNT and calcium carbonate are below stiffness threshold, however an increase of flexural modulus by adding CNT and calcium carbonate was observed. |
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Repositório Institucional da UNIFESP |
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Electrical, Thermal and Mechanical Properties of Epoxy/CNT/Calcium Carbonate NanocompositesEpoxy nanocompositesMWCNTdielectrical propertiesEpoxy/CNT and epoxy/CNT/calcium carbonate nanocomposites were produced via in situ polymerization assisted by ultrasonication without solvent and electrical, mechanical, thermal and thermomechanical properties of nanocomposites were evaluated. Epoxy/CNT presented very low percolation threshold, near 0.05 wt % and nanocomposites with higher contents of CNT presented further increase m electrical conductivity. The addition of calcium carbonate in epoxy/CNT nanocomposites increased the electrical conductivity, due to volume exclusion phenomena. Regarding thermal properties, due to the low content of the CNT and calcium carbonate no changes in glass transition (Tg) were observed. DMA results showed no significant changes in thermomechanical properties, once the contents of CNT and calcium carbonate are below stiffness threshold, however an increase of flexural modulus by adding CNT and calcium carbonate was observed.Univ Fed Sao Carlos, Dept Engn Mat, Via Washington Luiz,Km 235, BR-13565905 Sao Carlos, SP, BrazilUniv Fed Sao Paulo, Inst Ciencia & Tecnol, Rua Talim 330, BR-12231280 Sao Jose Dos Campos, SP, BrazilUniv Fed Sao Paulo, Inst Ciencia & Tecnol, Rua Talim 330, BR-12231280 Sao Jose Dos Campos, SP, BrazilWeb of ScienceSao Paulo Research Foundation (FAPESP)National Council for Scientific and Technological Development (CNPq)FAPESP: 2014/16299-8CNPq: 309 978/2014-0Univ Fed Sao Carlos, Dept Engenharia Materials2020-07-08T13:09:56Z2020-07-08T13:09:56Z2018info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersion-http://dx.doi.org/10.1590/1980-5373-MR-2017-0801Materials Research-Ibero-American Journal Of Materials. Sao Carlos, v. 21, n. 1, p. -, 2018.10.1590/1980-5373-MR-2017-0801S1516-14392018000100119.pdf1516-1439S1516-14392018000100119https://repositorio.unifesp.br/handle/11600/54303WOS:000432383900041engMaterials Research-Ibero-American Journal Of MaterialsSao Carlosinfo:eu-repo/semantics/openAccessBackes, Eduardo HenriqueSene, Tarcisio SansonPassador, Fabio Roberto [UNIFESP]Pessan, Luiz Antonioreponame:Repositório Institucional da UNIFESPinstname:Universidade Federal de São Paulo (UNIFESP)instacron:UNIFESP2021-09-29T09:31:01Zoai:repositorio.unifesp.br/:11600/54303Repositório InstitucionalPUBhttp://www.repositorio.unifesp.br/oai/requestbiblioteca.csp@unifesp.bropendoar:34652021-09-29T09:31:01Repositório Institucional da UNIFESP - Universidade Federal de São Paulo (UNIFESP)false |
dc.title.none.fl_str_mv |
Electrical, Thermal and Mechanical Properties of Epoxy/CNT/Calcium Carbonate Nanocomposites |
title |
Electrical, Thermal and Mechanical Properties of Epoxy/CNT/Calcium Carbonate Nanocomposites |
spellingShingle |
Electrical, Thermal and Mechanical Properties of Epoxy/CNT/Calcium Carbonate Nanocomposites Backes, Eduardo Henrique Epoxy nanocomposites MWCNT dielectrical properties |
title_short |
Electrical, Thermal and Mechanical Properties of Epoxy/CNT/Calcium Carbonate Nanocomposites |
title_full |
Electrical, Thermal and Mechanical Properties of Epoxy/CNT/Calcium Carbonate Nanocomposites |
title_fullStr |
Electrical, Thermal and Mechanical Properties of Epoxy/CNT/Calcium Carbonate Nanocomposites |
title_full_unstemmed |
Electrical, Thermal and Mechanical Properties of Epoxy/CNT/Calcium Carbonate Nanocomposites |
title_sort |
Electrical, Thermal and Mechanical Properties of Epoxy/CNT/Calcium Carbonate Nanocomposites |
author |
Backes, Eduardo Henrique |
author_facet |
Backes, Eduardo Henrique Sene, Tarcisio Sanson Passador, Fabio Roberto [UNIFESP] Pessan, Luiz Antonio |
author_role |
author |
author2 |
Sene, Tarcisio Sanson Passador, Fabio Roberto [UNIFESP] Pessan, Luiz Antonio |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Backes, Eduardo Henrique Sene, Tarcisio Sanson Passador, Fabio Roberto [UNIFESP] Pessan, Luiz Antonio |
dc.subject.por.fl_str_mv |
Epoxy nanocomposites MWCNT dielectrical properties |
topic |
Epoxy nanocomposites MWCNT dielectrical properties |
description |
Epoxy/CNT and epoxy/CNT/calcium carbonate nanocomposites were produced via in situ polymerization assisted by ultrasonication without solvent and electrical, mechanical, thermal and thermomechanical properties of nanocomposites were evaluated. Epoxy/CNT presented very low percolation threshold, near 0.05 wt % and nanocomposites with higher contents of CNT presented further increase m electrical conductivity. The addition of calcium carbonate in epoxy/CNT nanocomposites increased the electrical conductivity, due to volume exclusion phenomena. Regarding thermal properties, due to the low content of the CNT and calcium carbonate no changes in glass transition (Tg) were observed. DMA results showed no significant changes in thermomechanical properties, once the contents of CNT and calcium carbonate are below stiffness threshold, however an increase of flexural modulus by adding CNT and calcium carbonate was observed. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018 2020-07-08T13:09:56Z 2020-07-08T13:09:56Z |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1590/1980-5373-MR-2017-0801 Materials Research-Ibero-American Journal Of Materials. Sao Carlos, v. 21, n. 1, p. -, 2018. 10.1590/1980-5373-MR-2017-0801 S1516-14392018000100119.pdf 1516-1439 S1516-14392018000100119 https://repositorio.unifesp.br/handle/11600/54303 WOS:000432383900041 |
url |
http://dx.doi.org/10.1590/1980-5373-MR-2017-0801 https://repositorio.unifesp.br/handle/11600/54303 |
identifier_str_mv |
Materials Research-Ibero-American Journal Of Materials. Sao Carlos, v. 21, n. 1, p. -, 2018. 10.1590/1980-5373-MR-2017-0801 S1516-14392018000100119.pdf 1516-1439 S1516-14392018000100119 WOS:000432383900041 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Materials Research-Ibero-American Journal Of Materials |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
- |
dc.coverage.none.fl_str_mv |
Sao Carlos |
dc.publisher.none.fl_str_mv |
Univ Fed Sao Carlos, Dept Engenharia Materials |
publisher.none.fl_str_mv |
Univ Fed Sao Carlos, Dept Engenharia Materials |
dc.source.none.fl_str_mv |
reponame:Repositório Institucional da UNIFESP instname:Universidade Federal de São Paulo (UNIFESP) instacron:UNIFESP |
instname_str |
Universidade Federal de São Paulo (UNIFESP) |
instacron_str |
UNIFESP |
institution |
UNIFESP |
reponame_str |
Repositório Institucional da UNIFESP |
collection |
Repositório Institucional da UNIFESP |
repository.name.fl_str_mv |
Repositório Institucional da UNIFESP - Universidade Federal de São Paulo (UNIFESP) |
repository.mail.fl_str_mv |
biblioteca.csp@unifesp.br |
_version_ |
1814268370813452288 |