STUDY OF THE REMOVAL OF FERMENTATION INHIBITORS AFTER ACID AND ENZYMATIC TREATMENT OF CANE STRAW

Detalhes bibliográficos
Autor(a) principal: Lucarini, Adriana Célia
Data de Publicação: 2017
Outros Autores: Ferreira, Newton Libânio, de Souza, Charles Douglas, Francisco, Felippe Pinheiro Lima, Fonseca, Isabela Reinaud, Rossi, Larissa Guedes, Ferreira, Vanuza Magalhães
Tipo de documento: Artigo
Idioma: por
Título da fonte: Revista de Engenharia Química e Química
Texto Completo: https://periodicos.ufv.br/jcec/article/view/2446941603022017095
Resumo: It was studied the removal of toxic inhibitors produced during dilute-acid pretreatment of lignocellulosic biomass. Different sulfuric acid concentrations (1%, 2.5% and 5%) and reaction times (15, 30 and 60 minutes) were analyzed for the pretreatment process, and, 1% w/w H2SO4 and 15-minute reaction time have proven to be the most proper condition. With the experimental data, purification and concentration operations were simulated. For C5 stream (xylose, furfural and water) three different unit operations have been explored: a flash drum, a distillation column and a distillation column followed by multiple-effect evaporators. The distillation column with five multiple-effect evaporator system achieved the best energy efficiency (0,85 kW/kg xylose) and removal of furfural. For C6 stream (glucose and water), a four multiple-effect evaporator system simulated showed that the energy requirements not change significantly within the range of sugar concentration used (14% to 20%).
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spelling STUDY OF THE REMOVAL OF FERMENTATION INHIBITORS AFTER ACID AND ENZYMATIC TREATMENT OF CANE STRAWESTUDO DA REMOÇÃO DE INIBIDORES DE FERMENTAÇÃO APÓS TRATAMENTO ÁCIDO E ENZIMÁTICO DE PALHA DE CANAEthanolFurfuralLignocellulosicsAcid pretreatmentBiomassEtanol. FurfuralLignocelulósicosPré-tratamento ácidoBiomassaIt was studied the removal of toxic inhibitors produced during dilute-acid pretreatment of lignocellulosic biomass. Different sulfuric acid concentrations (1%, 2.5% and 5%) and reaction times (15, 30 and 60 minutes) were analyzed for the pretreatment process, and, 1% w/w H2SO4 and 15-minute reaction time have proven to be the most proper condition. With the experimental data, purification and concentration operations were simulated. For C5 stream (xylose, furfural and water) three different unit operations have been explored: a flash drum, a distillation column and a distillation column followed by multiple-effect evaporators. The distillation column with five multiple-effect evaporator system achieved the best energy efficiency (0,85 kW/kg xylose) and removal of furfural. For C6 stream (glucose and water), a four multiple-effect evaporator system simulated showed that the energy requirements not change significantly within the range of sugar concentration used (14% to 20%).Neste trabalho estudou-se a remoção do furfural, inibidor tóxico à fermentação, formado no pré-tratamento ácido de lignocelulósicos. Experimentalmente estudaram-se no pré-tratamento diferentes concentrações de H2SO4 (1%, 2,5% e 5%) e tempos de reação (15, 30 e 60 minutos). Definiu-se como condição mais adequada 1 % m/m de ácido sulfúrico e 15 minutos como tempo de reação. Com os dados experimentais realizou-se a simulação da remoção do furfural e da concentração dos açúcares. As correntes contendo açúcares foram denominadas de C5 (hidrolisado ácido – xilose e furfural) e C6 (hidrolisado enzimático - glicose). A corrente C5 foi purificada e concentrada através de uma coluna de enchimento integrada a evaporadores múltiplos com cinco efeitos, com gasto energético de 0,85 kW/kg de xilose. Para concentrar a corrente C6 de 14 a 20% de açúcares utilizaram-se evaporadores múltiplos com quatro efeitos com gasto energético requerido de 0,34 kW/ kg de glicose.Universidade Federal de Viçosa - UFV2017-03-19info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://periodicos.ufv.br/jcec/article/view/244694160302201709510.18540/jcecvl3iss2pp095-111The Journal of Engineering and Exact Sciences; Vol. 3 No. 2 (2017); 095-111The Journal of Engineering and Exact Sciences; Vol. 3 Núm. 2 (2017); 095-111The Journal of Engineering and Exact Sciences; v. 3 n. 2 (2017); 095-1112527-1075reponame:Revista de Engenharia Química e Químicainstname:Universidade Federal de Viçosa (UFV)instacron:UFVporhttps://periodicos.ufv.br/jcec/article/view/2446941603022017095/pdfLucarini, Adriana CéliaFerreira, Newton Libâniode Souza, Charles DouglasFrancisco, Felippe Pinheiro LimaFonseca, Isabela ReinaudRossi, Larissa GuedesFerreira, Vanuza Magalhãesinfo:eu-repo/semantics/openAccess2020-07-14T22:30:57Zoai:ojs.periodicos.ufv.br:article/2306Revistahttp://www.seer.ufv.br/seer/rbeq2/index.php/req2/indexONGhttps://periodicos.ufv.br/jcec/oaijcec.journal@ufv.br||req2@ufv.br2446-94162446-9416opendoar:2020-07-14T22:30:57Revista de Engenharia Química e Química - Universidade Federal de Viçosa (UFV)false
dc.title.none.fl_str_mv STUDY OF THE REMOVAL OF FERMENTATION INHIBITORS AFTER ACID AND ENZYMATIC TREATMENT OF CANE STRAW
ESTUDO DA REMOÇÃO DE INIBIDORES DE FERMENTAÇÃO APÓS TRATAMENTO ÁCIDO E ENZIMÁTICO DE PALHA DE CANA
title STUDY OF THE REMOVAL OF FERMENTATION INHIBITORS AFTER ACID AND ENZYMATIC TREATMENT OF CANE STRAW
spellingShingle STUDY OF THE REMOVAL OF FERMENTATION INHIBITORS AFTER ACID AND ENZYMATIC TREATMENT OF CANE STRAW
Lucarini, Adriana Célia
Ethanol
Furfural
Lignocellulosics
Acid pretreatment
Biomass
Etanol. Furfural
Lignocelulósicos
Pré-tratamento ácido
Biomassa
title_short STUDY OF THE REMOVAL OF FERMENTATION INHIBITORS AFTER ACID AND ENZYMATIC TREATMENT OF CANE STRAW
title_full STUDY OF THE REMOVAL OF FERMENTATION INHIBITORS AFTER ACID AND ENZYMATIC TREATMENT OF CANE STRAW
title_fullStr STUDY OF THE REMOVAL OF FERMENTATION INHIBITORS AFTER ACID AND ENZYMATIC TREATMENT OF CANE STRAW
title_full_unstemmed STUDY OF THE REMOVAL OF FERMENTATION INHIBITORS AFTER ACID AND ENZYMATIC TREATMENT OF CANE STRAW
title_sort STUDY OF THE REMOVAL OF FERMENTATION INHIBITORS AFTER ACID AND ENZYMATIC TREATMENT OF CANE STRAW
author Lucarini, Adriana Célia
author_facet Lucarini, Adriana Célia
Ferreira, Newton Libânio
de Souza, Charles Douglas
Francisco, Felippe Pinheiro Lima
Fonseca, Isabela Reinaud
Rossi, Larissa Guedes
Ferreira, Vanuza Magalhães
author_role author
author2 Ferreira, Newton Libânio
de Souza, Charles Douglas
Francisco, Felippe Pinheiro Lima
Fonseca, Isabela Reinaud
Rossi, Larissa Guedes
Ferreira, Vanuza Magalhães
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Lucarini, Adriana Célia
Ferreira, Newton Libânio
de Souza, Charles Douglas
Francisco, Felippe Pinheiro Lima
Fonseca, Isabela Reinaud
Rossi, Larissa Guedes
Ferreira, Vanuza Magalhães
dc.subject.por.fl_str_mv Ethanol
Furfural
Lignocellulosics
Acid pretreatment
Biomass
Etanol. Furfural
Lignocelulósicos
Pré-tratamento ácido
Biomassa
topic Ethanol
Furfural
Lignocellulosics
Acid pretreatment
Biomass
Etanol. Furfural
Lignocelulósicos
Pré-tratamento ácido
Biomassa
description It was studied the removal of toxic inhibitors produced during dilute-acid pretreatment of lignocellulosic biomass. Different sulfuric acid concentrations (1%, 2.5% and 5%) and reaction times (15, 30 and 60 minutes) were analyzed for the pretreatment process, and, 1% w/w H2SO4 and 15-minute reaction time have proven to be the most proper condition. With the experimental data, purification and concentration operations were simulated. For C5 stream (xylose, furfural and water) three different unit operations have been explored: a flash drum, a distillation column and a distillation column followed by multiple-effect evaporators. The distillation column with five multiple-effect evaporator system achieved the best energy efficiency (0,85 kW/kg xylose) and removal of furfural. For C6 stream (glucose and water), a four multiple-effect evaporator system simulated showed that the energy requirements not change significantly within the range of sugar concentration used (14% to 20%).
publishDate 2017
dc.date.none.fl_str_mv 2017-03-19
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://periodicos.ufv.br/jcec/article/view/2446941603022017095
10.18540/jcecvl3iss2pp095-111
url https://periodicos.ufv.br/jcec/article/view/2446941603022017095
identifier_str_mv 10.18540/jcecvl3iss2pp095-111
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv https://periodicos.ufv.br/jcec/article/view/2446941603022017095/pdf
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Federal de Viçosa - UFV
publisher.none.fl_str_mv Universidade Federal de Viçosa - UFV
dc.source.none.fl_str_mv The Journal of Engineering and Exact Sciences; Vol. 3 No. 2 (2017); 095-111
The Journal of Engineering and Exact Sciences; Vol. 3 Núm. 2 (2017); 095-111
The Journal of Engineering and Exact Sciences; v. 3 n. 2 (2017); 095-111
2527-1075
reponame:Revista de Engenharia Química e Química
instname:Universidade Federal de Viçosa (UFV)
instacron:UFV
instname_str Universidade Federal de Viçosa (UFV)
instacron_str UFV
institution UFV
reponame_str Revista de Engenharia Química e Química
collection Revista de Engenharia Química e Química
repository.name.fl_str_mv Revista de Engenharia Química e Química - Universidade Federal de Viçosa (UFV)
repository.mail.fl_str_mv jcec.journal@ufv.br||req2@ufv.br
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