APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSURE
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Outros Autores: | |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Revista de Engenharia Química e Química |
Texto Completo: | https://periodicos.ufv.br/jcec/article/view/2494 |
Resumo: | In the present study, experimental data of excess molar volumes ( ) of binary liquid mixtures of methyl tert butyl ether (MTBE) + methanol, or + ethanol, or + 1-propanol, or + 2-propanol, or + 1-butanol, or + 1-pentanol, or + 1-hexanol have been used to test the applicability of the Prigogine-Flory-Patterson theory (PFP) as a function of composition at different temperatures and atmospheric pressure. According to the model, interactional contribution is the most important one to explain the behavior. It may be observed that the PFP theory reproduces the main features of the experimental data by using only one fitted parameter adjusted. Good agreements between the experimental results and the theory were obtained for all the systems studied. |
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oai:ojs.periodicos.ufv.br:article/2494 |
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Revista de Engenharia Química e Química |
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APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSUREAPLICAÇÃO DA TEORIA PRIGOGINE-FLORY-PATTERSON AO VOLUME MOLAR EXCESSO DE SOLUÇÕES LÍQUIDAS BINÁRIAS DE {METIL TERC BUTIL ÉTER (MTBE) + ALCOÓIS} A DIFERENTES TEMPERATURAS E PRESSÃO ATMOSFÉRICAMethyl tert butyl etherAlcoholsExcess molar volumePrigogine-Flory-Patterson theoryMetil terc butil éterÁlcooisVolume molar excessoTeoria Prigogine-Flory-PattersonIn the present study, experimental data of excess molar volumes ( ) of binary liquid mixtures of methyl tert butyl ether (MTBE) + methanol, or + ethanol, or + 1-propanol, or + 2-propanol, or + 1-butanol, or + 1-pentanol, or + 1-hexanol have been used to test the applicability of the Prigogine-Flory-Patterson theory (PFP) as a function of composition at different temperatures and atmospheric pressure. According to the model, interactional contribution is the most important one to explain the behavior. It may be observed that the PFP theory reproduces the main features of the experimental data by using only one fitted parameter adjusted. Good agreements between the experimental results and the theory were obtained for all the systems studied.No presente estudo, dados experimentais de volume molar excesso ( ) de soluções líquidas binárias de metil terc butl éter (MTBE) + metanol, ou + etanol, ou + 1-propanol, ou + 2-propanol, ou + 1-butanol, ou + 1-pentanol, ou + 1-hexanol foram usados para testar a aplicabilidade da Teoria Prigogine-Flory-Patterson (PFP Theory), como função da composição a diferentes temperaturas e pressão atmosférica. De acordo com o modelo, a contribuição interacional é a mais importante para descrever o comportamento do . Foi observado que a Teoria PFP reproduz os dados experimentais usando apenas um parâmetro ajustável. Para todos os sistemas estudados foi obtida uma boa concordância entre os resultados experimentais e a Teoria.Universidade Federal de Viçosa - UFV2018-03-02info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://periodicos.ufv.br/jcec/article/view/249410.18540/jcecvl4iss1pp0085-0091The Journal of Engineering and Exact Sciences; Vol. 4 No. 1 (2018); 0085-0091The Journal of Engineering and Exact Sciences; Vol. 4 Núm. 1 (2018); 0085-0091The Journal of Engineering and Exact Sciences; v. 4 n. 1 (2018); 0085-00912527-1075reponame:Revista de Engenharia Química e Químicainstname:Universidade Federal de Viçosa (UFV)instacron:UFVporhttps://periodicos.ufv.br/jcec/article/view/2494/1045Hoga, Heloisa EmiTorres, Ricardo Belchiorinfo:eu-repo/semantics/openAccess2018-12-05T12:57:22Zoai:ojs.periodicos.ufv.br:article/2494Revistahttp://www.seer.ufv.br/seer/rbeq2/index.php/req2/indexONGhttps://periodicos.ufv.br/jcec/oaijcec.journal@ufv.br||req2@ufv.br2446-94162446-9416opendoar:2018-12-05T12:57:22Revista de Engenharia Química e Química - Universidade Federal de Viçosa (UFV)false |
dc.title.none.fl_str_mv |
APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSURE APLICAÇÃO DA TEORIA PRIGOGINE-FLORY-PATTERSON AO VOLUME MOLAR EXCESSO DE SOLUÇÕES LÍQUIDAS BINÁRIAS DE {METIL TERC BUTIL ÉTER (MTBE) + ALCOÓIS} A DIFERENTES TEMPERATURAS E PRESSÃO ATMOSFÉRICA |
title |
APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSURE |
spellingShingle |
APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSURE Hoga, Heloisa Emi Methyl tert butyl ether Alcohols Excess molar volume Prigogine-Flory-Patterson theory Metil terc butil éter Álcoois Volume molar excesso Teoria Prigogine-Flory-Patterson |
title_short |
APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSURE |
title_full |
APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSURE |
title_fullStr |
APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSURE |
title_full_unstemmed |
APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSURE |
title_sort |
APPLICATION OF PRIGOGINE-FLORY-PATTERSON THEORY TO EXCESS MOLAR VOLUMES OF BINARY LIQUID MIXTURES OF {METHYL TERT BUTYL ETHER (MTBE) + ALCOHOLS} AT DIFFERENT TEMPERATURES AND ATMOSPHERIC PRESSURE |
author |
Hoga, Heloisa Emi |
author_facet |
Hoga, Heloisa Emi Torres, Ricardo Belchior |
author_role |
author |
author2 |
Torres, Ricardo Belchior |
author2_role |
author |
dc.contributor.author.fl_str_mv |
Hoga, Heloisa Emi Torres, Ricardo Belchior |
dc.subject.por.fl_str_mv |
Methyl tert butyl ether Alcohols Excess molar volume Prigogine-Flory-Patterson theory Metil terc butil éter Álcoois Volume molar excesso Teoria Prigogine-Flory-Patterson |
topic |
Methyl tert butyl ether Alcohols Excess molar volume Prigogine-Flory-Patterson theory Metil terc butil éter Álcoois Volume molar excesso Teoria Prigogine-Flory-Patterson |
description |
In the present study, experimental data of excess molar volumes ( ) of binary liquid mixtures of methyl tert butyl ether (MTBE) + methanol, or + ethanol, or + 1-propanol, or + 2-propanol, or + 1-butanol, or + 1-pentanol, or + 1-hexanol have been used to test the applicability of the Prigogine-Flory-Patterson theory (PFP) as a function of composition at different temperatures and atmospheric pressure. According to the model, interactional contribution is the most important one to explain the behavior. It may be observed that the PFP theory reproduces the main features of the experimental data by using only one fitted parameter adjusted. Good agreements between the experimental results and the theory were obtained for all the systems studied. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-03-02 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://periodicos.ufv.br/jcec/article/view/2494 10.18540/jcecvl4iss1pp0085-0091 |
url |
https://periodicos.ufv.br/jcec/article/view/2494 |
identifier_str_mv |
10.18540/jcecvl4iss1pp0085-0091 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
https://periodicos.ufv.br/jcec/article/view/2494/1045 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Federal de Viçosa - UFV |
publisher.none.fl_str_mv |
Universidade Federal de Viçosa - UFV |
dc.source.none.fl_str_mv |
The Journal of Engineering and Exact Sciences; Vol. 4 No. 1 (2018); 0085-0091 The Journal of Engineering and Exact Sciences; Vol. 4 Núm. 1 (2018); 0085-0091 The Journal of Engineering and Exact Sciences; v. 4 n. 1 (2018); 0085-0091 2527-1075 reponame:Revista de Engenharia Química e Química instname:Universidade Federal de Viçosa (UFV) instacron:UFV |
instname_str |
Universidade Federal de Viçosa (UFV) |
instacron_str |
UFV |
institution |
UFV |
reponame_str |
Revista de Engenharia Química e Química |
collection |
Revista de Engenharia Química e Química |
repository.name.fl_str_mv |
Revista de Engenharia Química e Química - Universidade Federal de Viçosa (UFV) |
repository.mail.fl_str_mv |
jcec.journal@ufv.br||req2@ufv.br |
_version_ |
1800211188206796800 |