Equilibrium and mass transfer parameters estimation of the products of synthesis of piperonal by high performance liquid chromatography

Detalhes bibliográficos
Autor(a) principal: Ramos, Alex Martins
Data de Publicação: 2015
Outros Autores: Cremasco, Marco Aurélio
Tipo de documento: Artigo
Idioma: por
Título da fonte: Revista de Engenharia Química e Química
Texto Completo: https://periodicos.ufv.br/jcec/article/view/2446941601012015001
Resumo: The reaction sequences applied to essential oil of Piper hispidinervum D.C (long pepper) leads to formation of a multicomponent mixture composed, mainly, by piperonal, safrole, isosafrole and terpinolene. Due to importance of the piperonal for the pharmaceutical industry is that proposed separate it by high performance liquid chromatography. In this paper, it was studied the adsorption and mass transfer phenomena of these compounds using ethanol/water 70/30 (v/v) as mobile phase and C18 as stationary phase at 35 oC. Regarding to adsorption, the piperonal is the component that has the lowest affinity and terpinolene, the greatest with stationary phase. Regarding to mass transfer, effective diffusion and axial dispersion coefficients were around 10- (10 to 11) and 10- (7 to 8) m2.s-1, respectively. The internal resistance to mass transfer controls the overall mass transfer and parallel diffusion model describes the intra-particle transport mechanism.DOI: 10.18540/2446941601012015001
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spelling Equilibrium and mass transfer parameters estimation of the products of synthesis of piperonal by high performance liquid chromatographyEquilibrium thermodynamics and mass transfer parameters estimation of the products of synthesis of piperonal by high performance liquid chromatographySafroleLong pepperAdsorptionC18HPLCSafroleLong pepperAdsorptionC18HPLCThe reaction sequences applied to essential oil of Piper hispidinervum D.C (long pepper) leads to formation of a multicomponent mixture composed, mainly, by piperonal, safrole, isosafrole and terpinolene. Due to importance of the piperonal for the pharmaceutical industry is that proposed separate it by high performance liquid chromatography. In this paper, it was studied the adsorption and mass transfer phenomena of these compounds using ethanol/water 70/30 (v/v) as mobile phase and C18 as stationary phase at 35 oC. Regarding to adsorption, the piperonal is the component that has the lowest affinity and terpinolene, the greatest with stationary phase. Regarding to mass transfer, effective diffusion and axial dispersion coefficients were around 10- (10 to 11) and 10- (7 to 8) m2.s-1, respectively. The internal resistance to mass transfer controls the overall mass transfer and parallel diffusion model describes the intra-particle transport mechanism.DOI: 10.18540/2446941601012015001The reaction sequences applied to essential oil of Piper hispidinervum D.C (long pepper) leads to formation of a multicomponent mixture composed, mainly, by piperonal, safrole, isosafrole and terpinolene. Due to importance of the piperonal for the pharmaceutical industry is that proposed separate it by high performance liquid chromatography. In this paper, it was studied the adsorption and mass transfer phenomena of these compounds using ethanol/water 70/30 (v/v) as mobile phase and C18 as stationary phase at 35 oC. Regarding to adsorption, the piperonal is the component that has the lowest affinity and terpinolene, the greatest with stationary phase. Regarding to mass transfer, effective diffusion and axial dispersion coefficients were around 10- (10 to 11) and 10- (7 to 8) m2.s-1, respectively. The internal resistance to mass transfer controls the overall mass transfer and parallel diffusion model describes the intra-particle transport mechanism.Universidade Federal de Viçosa - UFV2015-06-25info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://periodicos.ufv.br/jcec/article/view/244694160101201500110.18540/jcecvl1iss1pp01-15The Journal of Engineering and Exact Sciences; Vol. 1 No. 1 (2015); 01-15The Journal of Engineering and Exact Sciences; Vol. 1 Núm. 1 (2015); 01-15The Journal of Engineering and Exact Sciences; v. 1 n. 1 (2015); 01-152527-1075reponame:Revista de Engenharia Química e Químicainstname:Universidade Federal de Viçosa (UFV)instacron:UFVporhttps://periodicos.ufv.br/jcec/article/view/2446941601012015001/pdfRamos, Alex MartinsCremasco, Marco Aurélioinfo:eu-repo/semantics/openAccess2019-12-23T15:35:27Zoai:ojs.periodicos.ufv.br:article/2118Revistahttp://www.seer.ufv.br/seer/rbeq2/index.php/req2/indexONGhttps://periodicos.ufv.br/jcec/oaijcec.journal@ufv.br||req2@ufv.br2446-94162446-9416opendoar:2019-12-23T15:35:27Revista de Engenharia Química e Química - Universidade Federal de Viçosa (UFV)false
dc.title.none.fl_str_mv Equilibrium and mass transfer parameters estimation of the products of synthesis of piperonal by high performance liquid chromatography
Equilibrium thermodynamics and mass transfer parameters estimation of the products of synthesis of piperonal by high performance liquid chromatography
title Equilibrium and mass transfer parameters estimation of the products of synthesis of piperonal by high performance liquid chromatography
spellingShingle Equilibrium and mass transfer parameters estimation of the products of synthesis of piperonal by high performance liquid chromatography
Ramos, Alex Martins
Safrole
Long pepper
Adsorption
C18
HPLC
Safrole
Long pepper
Adsorption
C18
HPLC
title_short Equilibrium and mass transfer parameters estimation of the products of synthesis of piperonal by high performance liquid chromatography
title_full Equilibrium and mass transfer parameters estimation of the products of synthesis of piperonal by high performance liquid chromatography
title_fullStr Equilibrium and mass transfer parameters estimation of the products of synthesis of piperonal by high performance liquid chromatography
title_full_unstemmed Equilibrium and mass transfer parameters estimation of the products of synthesis of piperonal by high performance liquid chromatography
title_sort Equilibrium and mass transfer parameters estimation of the products of synthesis of piperonal by high performance liquid chromatography
author Ramos, Alex Martins
author_facet Ramos, Alex Martins
Cremasco, Marco Aurélio
author_role author
author2 Cremasco, Marco Aurélio
author2_role author
dc.contributor.author.fl_str_mv Ramos, Alex Martins
Cremasco, Marco Aurélio
dc.subject.por.fl_str_mv Safrole
Long pepper
Adsorption
C18
HPLC
Safrole
Long pepper
Adsorption
C18
HPLC
topic Safrole
Long pepper
Adsorption
C18
HPLC
Safrole
Long pepper
Adsorption
C18
HPLC
description The reaction sequences applied to essential oil of Piper hispidinervum D.C (long pepper) leads to formation of a multicomponent mixture composed, mainly, by piperonal, safrole, isosafrole and terpinolene. Due to importance of the piperonal for the pharmaceutical industry is that proposed separate it by high performance liquid chromatography. In this paper, it was studied the adsorption and mass transfer phenomena of these compounds using ethanol/water 70/30 (v/v) as mobile phase and C18 as stationary phase at 35 oC. Regarding to adsorption, the piperonal is the component that has the lowest affinity and terpinolene, the greatest with stationary phase. Regarding to mass transfer, effective diffusion and axial dispersion coefficients were around 10- (10 to 11) and 10- (7 to 8) m2.s-1, respectively. The internal resistance to mass transfer controls the overall mass transfer and parallel diffusion model describes the intra-particle transport mechanism.DOI: 10.18540/2446941601012015001
publishDate 2015
dc.date.none.fl_str_mv 2015-06-25
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://periodicos.ufv.br/jcec/article/view/2446941601012015001
10.18540/jcecvl1iss1pp01-15
url https://periodicos.ufv.br/jcec/article/view/2446941601012015001
identifier_str_mv 10.18540/jcecvl1iss1pp01-15
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv https://periodicos.ufv.br/jcec/article/view/2446941601012015001/pdf
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Federal de Viçosa - UFV
publisher.none.fl_str_mv Universidade Federal de Viçosa - UFV
dc.source.none.fl_str_mv The Journal of Engineering and Exact Sciences; Vol. 1 No. 1 (2015); 01-15
The Journal of Engineering and Exact Sciences; Vol. 1 Núm. 1 (2015); 01-15
The Journal of Engineering and Exact Sciences; v. 1 n. 1 (2015); 01-15
2527-1075
reponame:Revista de Engenharia Química e Química
instname:Universidade Federal de Viçosa (UFV)
instacron:UFV
instname_str Universidade Federal de Viçosa (UFV)
instacron_str UFV
institution UFV
reponame_str Revista de Engenharia Química e Química
collection Revista de Engenharia Química e Química
repository.name.fl_str_mv Revista de Engenharia Química e Química - Universidade Federal de Viçosa (UFV)
repository.mail.fl_str_mv jcec.journal@ufv.br||req2@ufv.br
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