THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-X

Detalhes bibliográficos
Autor(a) principal: Castro, Mayara dos Santos
Data de Publicação: 2017
Outros Autores: Fantim, Wellina Massassi, Condotta, Rodrigo, Gomes, Eliezer Ladeia, Poço, João Guilherme da Rocha
Tipo de documento: Artigo
Idioma: por
Título da fonte: Revista de Engenharia Química e Química
Texto Completo: https://periodicos.ufv.br/jcec/article/view/2446941603022017254
Resumo: Synthetic zeolites have found several industrial applications as components in heterogeneous catalysts due to its highly regular structure and micropores which have regular dimensions and high specific surface area. However, in many of the petrochemical applications, microporous structure imposes limitations on the diffusion of molecules of reactants and products and becomes a problem. Much research effort has been done in the synthesis of other zeolitic structures with wider micropores diameters or structures having mixed micro and mesoporous. In this study, an experimental design based on the Placket & Burman statistical method was done with the purpose of select variables that has the larger effects on the synthesis of zeolite of type faujasita (FAU-X) with low molar SiO2/Al2O3. After establish the best conditions the effect of the introduction of funcionalized nano-sized carbon particles in the generation of mesoporous structures was verified.
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spelling THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-XANÁLISE ESTATÍSTICA APLICADA AOS PARÂMETROS DE SÍNTESE DE FAUJASITA Na-XZeolite XPlackett & BurmanSynthesis parametersVariable selectionZeólita XPlackett&BurmanVariáveis de SínteseSeleção de variáveisSynthetic zeolites have found several industrial applications as components in heterogeneous catalysts due to its highly regular structure and micropores which have regular dimensions and high specific surface area. However, in many of the petrochemical applications, microporous structure imposes limitations on the diffusion of molecules of reactants and products and becomes a problem. Much research effort has been done in the synthesis of other zeolitic structures with wider micropores diameters or structures having mixed micro and mesoporous. In this study, an experimental design based on the Placket & Burman statistical method was done with the purpose of select variables that has the larger effects on the synthesis of zeolite of type faujasita (FAU-X) with low molar SiO2/Al2O3. After establish the best conditions the effect of the introduction of funcionalized nano-sized carbon particles in the generation of mesoporous structures was verified.Devido às sua estrutura altamente regular e características microporos com dimensões regulares e superfície específica, as zeólitas, especialmente as sintéticas tem encontrado várias aplicações industriais como componentes em catalisadores heterogêneos. Entretanto, em muitas das aplicações petroquímicas, a estrutura microporosa impõe limitações à difusão das moléculas de reagentes e produtos e se torna um problema. Muito esforço de pesquisa na síntese de outras estruturas zeolíticas com diâmetros de microporos mais largos ou estruturas mistas contendo micro e mesoporos tem sido feito. Neste estudo, foi realizado um delineamento experimental baseado na metodologia de Placket & Burman para selecionar as variáveis que tem maior efeito na síntese de zeólita do tipo faujasita (FAU-X) com baixa relação molar SiO2/Al2O3 para posteriormente fixar as melhores condições e verificar o efeito da introdução de partículas funcionalizadas de carbono nanométricas na geração de estruturas mesoporosas.Universidade Federal de Viçosa - UFV2017-03-19info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://periodicos.ufv.br/jcec/article/view/244694160302201725410.18540/jcecvl3iss2pp254-266The Journal of Engineering and Exact Sciences; Vol. 3 No. 2 (2017); 254-266The Journal of Engineering and Exact Sciences; Vol. 3 Núm. 2 (2017); 254-266The Journal of Engineering and Exact Sciences; v. 3 n. 2 (2017); 254-2662527-1075reponame:Revista de Engenharia Química e Químicainstname:Universidade Federal de Viçosa (UFV)instacron:UFVporhttps://periodicos.ufv.br/jcec/article/view/2446941603022017254/pdfCastro, Mayara dos SantosFantim, Wellina MassassiCondotta, RodrigoGomes, Eliezer LadeiaPoço, João Guilherme da Rochainfo:eu-repo/semantics/openAccess2020-07-14T22:33:28Zoai:ojs.periodicos.ufv.br:article/2318Revistahttp://www.seer.ufv.br/seer/rbeq2/index.php/req2/indexONGhttps://periodicos.ufv.br/jcec/oaijcec.journal@ufv.br||req2@ufv.br2446-94162446-9416opendoar:2020-07-14T22:33:28Revista de Engenharia Química e Química - Universidade Federal de Viçosa (UFV)false
dc.title.none.fl_str_mv THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-X
ANÁLISE ESTATÍSTICA APLICADA AOS PARÂMETROS DE SÍNTESE DE FAUJASITA Na-X
title THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-X
spellingShingle THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-X
Castro, Mayara dos Santos
Zeolite X
Plackett & Burman
Synthesis parameters
Variable selection
Zeólita X
Plackett&Burman
Variáveis de Síntese
Seleção de variáveis
title_short THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-X
title_full THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-X
title_fullStr THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-X
title_full_unstemmed THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-X
title_sort THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-X
author Castro, Mayara dos Santos
author_facet Castro, Mayara dos Santos
Fantim, Wellina Massassi
Condotta, Rodrigo
Gomes, Eliezer Ladeia
Poço, João Guilherme da Rocha
author_role author
author2 Fantim, Wellina Massassi
Condotta, Rodrigo
Gomes, Eliezer Ladeia
Poço, João Guilherme da Rocha
author2_role author
author
author
author
dc.contributor.author.fl_str_mv Castro, Mayara dos Santos
Fantim, Wellina Massassi
Condotta, Rodrigo
Gomes, Eliezer Ladeia
Poço, João Guilherme da Rocha
dc.subject.por.fl_str_mv Zeolite X
Plackett & Burman
Synthesis parameters
Variable selection
Zeólita X
Plackett&Burman
Variáveis de Síntese
Seleção de variáveis
topic Zeolite X
Plackett & Burman
Synthesis parameters
Variable selection
Zeólita X
Plackett&Burman
Variáveis de Síntese
Seleção de variáveis
description Synthetic zeolites have found several industrial applications as components in heterogeneous catalysts due to its highly regular structure and micropores which have regular dimensions and high specific surface area. However, in many of the petrochemical applications, microporous structure imposes limitations on the diffusion of molecules of reactants and products and becomes a problem. Much research effort has been done in the synthesis of other zeolitic structures with wider micropores diameters or structures having mixed micro and mesoporous. In this study, an experimental design based on the Placket & Burman statistical method was done with the purpose of select variables that has the larger effects on the synthesis of zeolite of type faujasita (FAU-X) with low molar SiO2/Al2O3. After establish the best conditions the effect of the introduction of funcionalized nano-sized carbon particles in the generation of mesoporous structures was verified.
publishDate 2017
dc.date.none.fl_str_mv 2017-03-19
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://periodicos.ufv.br/jcec/article/view/2446941603022017254
10.18540/jcecvl3iss2pp254-266
url https://periodicos.ufv.br/jcec/article/view/2446941603022017254
identifier_str_mv 10.18540/jcecvl3iss2pp254-266
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv https://periodicos.ufv.br/jcec/article/view/2446941603022017254/pdf
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Federal de Viçosa - UFV
publisher.none.fl_str_mv Universidade Federal de Viçosa - UFV
dc.source.none.fl_str_mv The Journal of Engineering and Exact Sciences; Vol. 3 No. 2 (2017); 254-266
The Journal of Engineering and Exact Sciences; Vol. 3 Núm. 2 (2017); 254-266
The Journal of Engineering and Exact Sciences; v. 3 n. 2 (2017); 254-266
2527-1075
reponame:Revista de Engenharia Química e Química
instname:Universidade Federal de Viçosa (UFV)
instacron:UFV
instname_str Universidade Federal de Viçosa (UFV)
instacron_str UFV
institution UFV
reponame_str Revista de Engenharia Química e Química
collection Revista de Engenharia Química e Química
repository.name.fl_str_mv Revista de Engenharia Química e Química - Universidade Federal de Viçosa (UFV)
repository.mail.fl_str_mv jcec.journal@ufv.br||req2@ufv.br
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