THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-X
Autor(a) principal: | |
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Data de Publicação: | 2017 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | The Journal of Engineering and Exact Sciences |
Texto Completo: | https://periodicos.ufv.br/jcec/article/view/2446941603022017254 |
Resumo: | Synthetic zeolites have found several industrial applications as components in heterogeneous catalysts due to its highly regular structure and micropores which have regular dimensions and high specific surface area. However, in many of the petrochemical applications, microporous structure imposes limitations on the diffusion of molecules of reactants and products and becomes a problem. Much research effort has been done in the synthesis of other zeolitic structures with wider micropores diameters or structures having mixed micro and mesoporous. In this study, an experimental design based on the Placket & Burman statistical method was done with the purpose of select variables that has the larger effects on the synthesis of zeolite of type faujasita (FAU-X) with low molar SiO2/Al2O3. After establish the best conditions the effect of the introduction of funcionalized nano-sized carbon particles in the generation of mesoporous structures was verified. |
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oai:ojs.periodicos.ufv.br:article/2318 |
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The Journal of Engineering and Exact Sciences |
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THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-XANÁLISE ESTATÍSTICA APLICADA AOS PARÂMETROS DE SÍNTESE DE FAUJASITA Na-XZeolite XPlackett & BurmanSynthesis parametersVariable selectionZeólita XPlackett&BurmanVariáveis de SínteseSeleção de variáveisSynthetic zeolites have found several industrial applications as components in heterogeneous catalysts due to its highly regular structure and micropores which have regular dimensions and high specific surface area. However, in many of the petrochemical applications, microporous structure imposes limitations on the diffusion of molecules of reactants and products and becomes a problem. Much research effort has been done in the synthesis of other zeolitic structures with wider micropores diameters or structures having mixed micro and mesoporous. In this study, an experimental design based on the Placket & Burman statistical method was done with the purpose of select variables that has the larger effects on the synthesis of zeolite of type faujasita (FAU-X) with low molar SiO2/Al2O3. After establish the best conditions the effect of the introduction of funcionalized nano-sized carbon particles in the generation of mesoporous structures was verified.Devido às sua estrutura altamente regular e características microporos com dimensões regulares e superfície específica, as zeólitas, especialmente as sintéticas tem encontrado várias aplicações industriais como componentes em catalisadores heterogêneos. Entretanto, em muitas das aplicações petroquímicas, a estrutura microporosa impõe limitações à difusão das moléculas de reagentes e produtos e se torna um problema. Muito esforço de pesquisa na síntese de outras estruturas zeolíticas com diâmetros de microporos mais largos ou estruturas mistas contendo micro e mesoporos tem sido feito. Neste estudo, foi realizado um delineamento experimental baseado na metodologia de Placket & Burman para selecionar as variáveis que tem maior efeito na síntese de zeólita do tipo faujasita (FAU-X) com baixa relação molar SiO2/Al2O3 para posteriormente fixar as melhores condições e verificar o efeito da introdução de partículas funcionalizadas de carbono nanométricas na geração de estruturas mesoporosas.Universidade Federal de Viçosa - UFV2017-03-19info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://periodicos.ufv.br/jcec/article/view/244694160302201725410.18540/jcecvl3iss2pp254-266The Journal of Engineering and Exact Sciences; Vol. 3 No. 2 (2017); 254-266The Journal of Engineering and Exact Sciences; Vol. 3 Núm. 2 (2017); 254-266The Journal of Engineering and Exact Sciences; v. 3 n. 2 (2017); 254-2662527-1075reponame:The Journal of Engineering and Exact Sciencesinstname:Universidade Federal de Viçosa (UFV)instacron:UFVporhttps://periodicos.ufv.br/jcec/article/view/2446941603022017254/pdfCastro, Mayara dos SantosFantim, Wellina MassassiCondotta, RodrigoGomes, Eliezer LadeiaPoço, João Guilherme da Rochainfo:eu-repo/semantics/openAccess2020-07-14T22:33:28Zoai:ojs.periodicos.ufv.br:article/2318Revistahttp://www.seer.ufv.br/seer/rbeq2/index.php/req2/oai2527-10752527-1075opendoar:2020-07-14T22:33:28The Journal of Engineering and Exact Sciences - Universidade Federal de Viçosa (UFV)false |
dc.title.none.fl_str_mv |
THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-X ANÁLISE ESTATÍSTICA APLICADA AOS PARÂMETROS DE SÍNTESE DE FAUJASITA Na-X |
title |
THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-X |
spellingShingle |
THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-X Castro, Mayara dos Santos Zeolite X Plackett & Burman Synthesis parameters Variable selection Zeólita X Plackett&Burman Variáveis de Síntese Seleção de variáveis |
title_short |
THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-X |
title_full |
THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-X |
title_fullStr |
THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-X |
title_full_unstemmed |
THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-X |
title_sort |
THE EFFECT OF SOME VARIABLES AND PARAMETERS USED IN THE SYNTHESIS OF FAUJASITE Na-X |
author |
Castro, Mayara dos Santos |
author_facet |
Castro, Mayara dos Santos Fantim, Wellina Massassi Condotta, Rodrigo Gomes, Eliezer Ladeia Poço, João Guilherme da Rocha |
author_role |
author |
author2 |
Fantim, Wellina Massassi Condotta, Rodrigo Gomes, Eliezer Ladeia Poço, João Guilherme da Rocha |
author2_role |
author author author author |
dc.contributor.author.fl_str_mv |
Castro, Mayara dos Santos Fantim, Wellina Massassi Condotta, Rodrigo Gomes, Eliezer Ladeia Poço, João Guilherme da Rocha |
dc.subject.por.fl_str_mv |
Zeolite X Plackett & Burman Synthesis parameters Variable selection Zeólita X Plackett&Burman Variáveis de Síntese Seleção de variáveis |
topic |
Zeolite X Plackett & Burman Synthesis parameters Variable selection Zeólita X Plackett&Burman Variáveis de Síntese Seleção de variáveis |
description |
Synthetic zeolites have found several industrial applications as components in heterogeneous catalysts due to its highly regular structure and micropores which have regular dimensions and high specific surface area. However, in many of the petrochemical applications, microporous structure imposes limitations on the diffusion of molecules of reactants and products and becomes a problem. Much research effort has been done in the synthesis of other zeolitic structures with wider micropores diameters or structures having mixed micro and mesoporous. In this study, an experimental design based on the Placket & Burman statistical method was done with the purpose of select variables that has the larger effects on the synthesis of zeolite of type faujasita (FAU-X) with low molar SiO2/Al2O3. After establish the best conditions the effect of the introduction of funcionalized nano-sized carbon particles in the generation of mesoporous structures was verified. |
publishDate |
2017 |
dc.date.none.fl_str_mv |
2017-03-19 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://periodicos.ufv.br/jcec/article/view/2446941603022017254 10.18540/jcecvl3iss2pp254-266 |
url |
https://periodicos.ufv.br/jcec/article/view/2446941603022017254 |
identifier_str_mv |
10.18540/jcecvl3iss2pp254-266 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
https://periodicos.ufv.br/jcec/article/view/2446941603022017254/pdf |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Federal de Viçosa - UFV |
publisher.none.fl_str_mv |
Universidade Federal de Viçosa - UFV |
dc.source.none.fl_str_mv |
The Journal of Engineering and Exact Sciences; Vol. 3 No. 2 (2017); 254-266 The Journal of Engineering and Exact Sciences; Vol. 3 Núm. 2 (2017); 254-266 The Journal of Engineering and Exact Sciences; v. 3 n. 2 (2017); 254-266 2527-1075 reponame:The Journal of Engineering and Exact Sciences instname:Universidade Federal de Viçosa (UFV) instacron:UFV |
instname_str |
Universidade Federal de Viçosa (UFV) |
instacron_str |
UFV |
institution |
UFV |
reponame_str |
The Journal of Engineering and Exact Sciences |
collection |
The Journal of Engineering and Exact Sciences |
repository.name.fl_str_mv |
The Journal of Engineering and Exact Sciences - Universidade Federal de Viçosa (UFV) |
repository.mail.fl_str_mv |
|
_version_ |
1808845243430207488 |