In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions

Detalhes bibliográficos
Autor(a) principal: Battiston , Catia Santin Zanchett
Data de Publicação: 2024
Outros Autores: Oro, Carolina Elisa Demaman, Ficanha , Aline M. Moreira, Reato, Paloma Truccolo, Paroul, Natalia, Dallago, Rogério Marcos, Mignoni, Marcelo Luis
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Revista de Engenharia Química e Química
Texto Completo: https://periodicos.ufv.br/jcec/article/view/18614
Resumo: The ionic solids [C16MI]Cl and [C14MI]Cl were used as structure directors on MCM-48 mesoporous support with immobilized CALB lipase for the synthesis of esters from geraniol. Significant results were obtained in the synthesis of geranyl acetate and geranyl butyrate. Enzyme concentration, temperature and molar ratio of substrates were parameters that affect the synthesis yield. The highest temperature (60°C) and highest enzyme concentration (13%) conditions showed the best ester conversion results. For both esters, the ionic liquid [C16MI]Cl showed better conversion results and reached a value above 38% of conversion.   Furthermore, the support tested in the present study for application in ester synthesis is cost-effective. In addition, the enzymatic route to obtain the esters presents mild reaction conditions and the results show potential for application in industrial applications.
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spelling In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactionsImobilização in situ da enzima Cal B em materiais mesoporosos do tipo MCM-48 utilizando diferentes sólidos iônicos: síntese e aplicação em reações de esterificaçãoSynthesis of geranylIonic SolidsEnzymatic route catalystIndustrial applicationsSólidos Iônicos. Síntese de geranil. Catalisador de rota enzimática. Aplicações industriais.The ionic solids [C16MI]Cl and [C14MI]Cl were used as structure directors on MCM-48 mesoporous support with immobilized CALB lipase for the synthesis of esters from geraniol. Significant results were obtained in the synthesis of geranyl acetate and geranyl butyrate. Enzyme concentration, temperature and molar ratio of substrates were parameters that affect the synthesis yield. The highest temperature (60°C) and highest enzyme concentration (13%) conditions showed the best ester conversion results. For both esters, the ionic liquid [C16MI]Cl showed better conversion results and reached a value above 38% of conversion.   Furthermore, the support tested in the present study for application in ester synthesis is cost-effective. In addition, the enzymatic route to obtain the esters presents mild reaction conditions and the results show potential for application in industrial applications.Os sólidos iônicos [C16MI]Cl e [C14MI]Cl foram utilizados como diretores de estrutura em suporte mesoporoso MCM-48 com lipase CALB imobilizada para a síntese de ésteres de geraniol. Resultados significativos foram obtidos na síntese de acetato de geranila e butirato de geranil. A concentração da enzima, a temperatura e a razão molar dos substratos foram parâmetros que afetaram o rendimento da síntese. As condições de maior temperatura (60°C) e maior concentração de enzima (13%) apresentaram os melhores resultados de conversão de ésteres. Para ambos os ésteres, o líquido iônico [C16MI]Cl apresentou melhores resultados de conversão e atingiu valor acima de 38% de conversão. Além disso, o suporte testado no presente estudo para aplicação na síntese de ésteres é custo-efetivo. Além disso, a rota enzimática para obtenção dos ésteres apresenta condições reacionais brandas e os resultados mostram potencial para aplicação em aplicações industriais.Universidade Federal de Viçosa - UFV2024-04-14info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://periodicos.ufv.br/jcec/article/view/1861410.18540/jcecvl10iss3pp18614The Journal of Engineering and Exact Sciences; Vol. 10 No. 3 (2024); 18614The Journal of Engineering and Exact Sciences; Vol. 10 Núm. 3 (2024); 18614The Journal of Engineering and Exact Sciences; v. 10 n. 3 (2024); 186142527-1075reponame:Revista de Engenharia Química e Químicainstname:Universidade Federal de Viçosa (UFV)instacron:UFVenghttps://periodicos.ufv.br/jcec/article/view/18614/9585Copyright (c) 2024 The Journal of Engineering and Exact Scienceshttps://creativecommons.org/licenses/by/4.0info:eu-repo/semantics/openAccessBattiston , Catia Santin ZanchettOro, Carolina Elisa DemamanFicanha , Aline M. MoreiraReato, Paloma TruccoloParoul, NataliaDallago, Rogério MarcosMignoni, Marcelo Luis2024-05-15T20:25:07Zoai:ojs.periodicos.ufv.br:article/18614Revistahttp://www.seer.ufv.br/seer/rbeq2/index.php/req2/indexONGhttps://periodicos.ufv.br/jcec/oaijcec.journal@ufv.br||req2@ufv.br2446-94162446-9416opendoar:2024-05-15T20:25:07Revista de Engenharia Química e Química - Universidade Federal de Viçosa (UFV)false
dc.title.none.fl_str_mv In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions
Imobilização in situ da enzima Cal B em materiais mesoporosos do tipo MCM-48 utilizando diferentes sólidos iônicos: síntese e aplicação em reações de esterificação
title In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions
spellingShingle In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions
Battiston , Catia Santin Zanchett
Synthesis of geranyl
Ionic Solids
Enzymatic route catalyst
Industrial applications
Sólidos Iônicos. Síntese de geranil. Catalisador de rota enzimática. Aplicações industriais.
title_short In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions
title_full In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions
title_fullStr In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions
title_full_unstemmed In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions
title_sort In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions
author Battiston , Catia Santin Zanchett
author_facet Battiston , Catia Santin Zanchett
Oro, Carolina Elisa Demaman
Ficanha , Aline M. Moreira
Reato, Paloma Truccolo
Paroul, Natalia
Dallago, Rogério Marcos
Mignoni, Marcelo Luis
author_role author
author2 Oro, Carolina Elisa Demaman
Ficanha , Aline M. Moreira
Reato, Paloma Truccolo
Paroul, Natalia
Dallago, Rogério Marcos
Mignoni, Marcelo Luis
author2_role author
author
author
author
author
author
dc.contributor.author.fl_str_mv Battiston , Catia Santin Zanchett
Oro, Carolina Elisa Demaman
Ficanha , Aline M. Moreira
Reato, Paloma Truccolo
Paroul, Natalia
Dallago, Rogério Marcos
Mignoni, Marcelo Luis
dc.subject.por.fl_str_mv Synthesis of geranyl
Ionic Solids
Enzymatic route catalyst
Industrial applications
Sólidos Iônicos. Síntese de geranil. Catalisador de rota enzimática. Aplicações industriais.
topic Synthesis of geranyl
Ionic Solids
Enzymatic route catalyst
Industrial applications
Sólidos Iônicos. Síntese de geranil. Catalisador de rota enzimática. Aplicações industriais.
description The ionic solids [C16MI]Cl and [C14MI]Cl were used as structure directors on MCM-48 mesoporous support with immobilized CALB lipase for the synthesis of esters from geraniol. Significant results were obtained in the synthesis of geranyl acetate and geranyl butyrate. Enzyme concentration, temperature and molar ratio of substrates were parameters that affect the synthesis yield. The highest temperature (60°C) and highest enzyme concentration (13%) conditions showed the best ester conversion results. For both esters, the ionic liquid [C16MI]Cl showed better conversion results and reached a value above 38% of conversion.   Furthermore, the support tested in the present study for application in ester synthesis is cost-effective. In addition, the enzymatic route to obtain the esters presents mild reaction conditions and the results show potential for application in industrial applications.
publishDate 2024
dc.date.none.fl_str_mv 2024-04-14
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://periodicos.ufv.br/jcec/article/view/18614
10.18540/jcecvl10iss3pp18614
url https://periodicos.ufv.br/jcec/article/view/18614
identifier_str_mv 10.18540/jcecvl10iss3pp18614
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv https://periodicos.ufv.br/jcec/article/view/18614/9585
dc.rights.driver.fl_str_mv Copyright (c) 2024 The Journal of Engineering and Exact Sciences
https://creativecommons.org/licenses/by/4.0
info:eu-repo/semantics/openAccess
rights_invalid_str_mv Copyright (c) 2024 The Journal of Engineering and Exact Sciences
https://creativecommons.org/licenses/by/4.0
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Federal de Viçosa - UFV
publisher.none.fl_str_mv Universidade Federal de Viçosa - UFV
dc.source.none.fl_str_mv The Journal of Engineering and Exact Sciences; Vol. 10 No. 3 (2024); 18614
The Journal of Engineering and Exact Sciences; Vol. 10 Núm. 3 (2024); 18614
The Journal of Engineering and Exact Sciences; v. 10 n. 3 (2024); 18614
2527-1075
reponame:Revista de Engenharia Química e Química
instname:Universidade Federal de Viçosa (UFV)
instacron:UFV
instname_str Universidade Federal de Viçosa (UFV)
instacron_str UFV
institution UFV
reponame_str Revista de Engenharia Química e Química
collection Revista de Engenharia Química e Química
repository.name.fl_str_mv Revista de Engenharia Química e Química - Universidade Federal de Viçosa (UFV)
repository.mail.fl_str_mv jcec.journal@ufv.br||req2@ufv.br
_version_ 1800211186173607936

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