In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions
Autor(a) principal: | |
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Data de Publicação: | 2024 |
Outros Autores: | , , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Revista de Engenharia Química e Química |
Texto Completo: | https://periodicos.ufv.br/jcec/article/view/18614 |
Resumo: | The ionic solids [C16MI]Cl and [C14MI]Cl were used as structure directors on MCM-48 mesoporous support with immobilized CALB lipase for the synthesis of esters from geraniol. Significant results were obtained in the synthesis of geranyl acetate and geranyl butyrate. Enzyme concentration, temperature and molar ratio of substrates were parameters that affect the synthesis yield. The highest temperature (60°C) and highest enzyme concentration (13%) conditions showed the best ester conversion results. For both esters, the ionic liquid [C16MI]Cl showed better conversion results and reached a value above 38% of conversion. Furthermore, the support tested in the present study for application in ester synthesis is cost-effective. In addition, the enzymatic route to obtain the esters presents mild reaction conditions and the results show potential for application in industrial applications. |
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Revista de Engenharia Química e Química |
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In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactionsImobilização in situ da enzima Cal B em materiais mesoporosos do tipo MCM-48 utilizando diferentes sólidos iônicos: síntese e aplicação em reações de esterificaçãoSynthesis of geranylIonic SolidsEnzymatic route catalystIndustrial applicationsSólidos Iônicos. Síntese de geranil. Catalisador de rota enzimática. Aplicações industriais.The ionic solids [C16MI]Cl and [C14MI]Cl were used as structure directors on MCM-48 mesoporous support with immobilized CALB lipase for the synthesis of esters from geraniol. Significant results were obtained in the synthesis of geranyl acetate and geranyl butyrate. Enzyme concentration, temperature and molar ratio of substrates were parameters that affect the synthesis yield. The highest temperature (60°C) and highest enzyme concentration (13%) conditions showed the best ester conversion results. For both esters, the ionic liquid [C16MI]Cl showed better conversion results and reached a value above 38% of conversion. Furthermore, the support tested in the present study for application in ester synthesis is cost-effective. In addition, the enzymatic route to obtain the esters presents mild reaction conditions and the results show potential for application in industrial applications.Os sólidos iônicos [C16MI]Cl e [C14MI]Cl foram utilizados como diretores de estrutura em suporte mesoporoso MCM-48 com lipase CALB imobilizada para a síntese de ésteres de geraniol. Resultados significativos foram obtidos na síntese de acetato de geranila e butirato de geranil. A concentração da enzima, a temperatura e a razão molar dos substratos foram parâmetros que afetaram o rendimento da síntese. As condições de maior temperatura (60°C) e maior concentração de enzima (13%) apresentaram os melhores resultados de conversão de ésteres. Para ambos os ésteres, o líquido iônico [C16MI]Cl apresentou melhores resultados de conversão e atingiu valor acima de 38% de conversão. Além disso, o suporte testado no presente estudo para aplicação na síntese de ésteres é custo-efetivo. Além disso, a rota enzimática para obtenção dos ésteres apresenta condições reacionais brandas e os resultados mostram potencial para aplicação em aplicações industriais.Universidade Federal de Viçosa - UFV2024-04-14info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://periodicos.ufv.br/jcec/article/view/1861410.18540/jcecvl10iss3pp18614The Journal of Engineering and Exact Sciences; Vol. 10 No. 3 (2024); 18614The Journal of Engineering and Exact Sciences; Vol. 10 Núm. 3 (2024); 18614The Journal of Engineering and Exact Sciences; v. 10 n. 3 (2024); 186142527-1075reponame:Revista de Engenharia Química e Químicainstname:Universidade Federal de Viçosa (UFV)instacron:UFVenghttps://periodicos.ufv.br/jcec/article/view/18614/9585Copyright (c) 2024 The Journal of Engineering and Exact Scienceshttps://creativecommons.org/licenses/by/4.0info:eu-repo/semantics/openAccessBattiston , Catia Santin ZanchettOro, Carolina Elisa DemamanFicanha , Aline M. MoreiraReato, Paloma TruccoloParoul, NataliaDallago, Rogério MarcosMignoni, Marcelo Luis2024-05-15T20:25:07Zoai:ojs.periodicos.ufv.br:article/18614Revistahttp://www.seer.ufv.br/seer/rbeq2/index.php/req2/indexONGhttps://periodicos.ufv.br/jcec/oaijcec.journal@ufv.br||req2@ufv.br2446-94162446-9416opendoar:2024-05-15T20:25:07Revista de Engenharia Química e Química - Universidade Federal de Viçosa (UFV)false |
dc.title.none.fl_str_mv |
In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions Imobilização in situ da enzima Cal B em materiais mesoporosos do tipo MCM-48 utilizando diferentes sólidos iônicos: síntese e aplicação em reações de esterificação |
title |
In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions |
spellingShingle |
In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions Battiston , Catia Santin Zanchett Synthesis of geranyl Ionic Solids Enzymatic route catalyst Industrial applications Sólidos Iônicos. Síntese de geranil. Catalisador de rota enzimática. Aplicações industriais. |
title_short |
In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions |
title_full |
In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions |
title_fullStr |
In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions |
title_full_unstemmed |
In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions |
title_sort |
In situ immobilization of Cal B enzyme in mesoporous materials of the MCM-48 type using different ionic solids: synthesis and application in esterification reactions |
author |
Battiston , Catia Santin Zanchett |
author_facet |
Battiston , Catia Santin Zanchett Oro, Carolina Elisa Demaman Ficanha , Aline M. Moreira Reato, Paloma Truccolo Paroul, Natalia Dallago, Rogério Marcos Mignoni, Marcelo Luis |
author_role |
author |
author2 |
Oro, Carolina Elisa Demaman Ficanha , Aline M. Moreira Reato, Paloma Truccolo Paroul, Natalia Dallago, Rogério Marcos Mignoni, Marcelo Luis |
author2_role |
author author author author author author |
dc.contributor.author.fl_str_mv |
Battiston , Catia Santin Zanchett Oro, Carolina Elisa Demaman Ficanha , Aline M. Moreira Reato, Paloma Truccolo Paroul, Natalia Dallago, Rogério Marcos Mignoni, Marcelo Luis |
dc.subject.por.fl_str_mv |
Synthesis of geranyl Ionic Solids Enzymatic route catalyst Industrial applications Sólidos Iônicos. Síntese de geranil. Catalisador de rota enzimática. Aplicações industriais. |
topic |
Synthesis of geranyl Ionic Solids Enzymatic route catalyst Industrial applications Sólidos Iônicos. Síntese de geranil. Catalisador de rota enzimática. Aplicações industriais. |
description |
The ionic solids [C16MI]Cl and [C14MI]Cl were used as structure directors on MCM-48 mesoporous support with immobilized CALB lipase for the synthesis of esters from geraniol. Significant results were obtained in the synthesis of geranyl acetate and geranyl butyrate. Enzyme concentration, temperature and molar ratio of substrates were parameters that affect the synthesis yield. The highest temperature (60°C) and highest enzyme concentration (13%) conditions showed the best ester conversion results. For both esters, the ionic liquid [C16MI]Cl showed better conversion results and reached a value above 38% of conversion. Furthermore, the support tested in the present study for application in ester synthesis is cost-effective. In addition, the enzymatic route to obtain the esters presents mild reaction conditions and the results show potential for application in industrial applications. |
publishDate |
2024 |
dc.date.none.fl_str_mv |
2024-04-14 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://periodicos.ufv.br/jcec/article/view/18614 10.18540/jcecvl10iss3pp18614 |
url |
https://periodicos.ufv.br/jcec/article/view/18614 |
identifier_str_mv |
10.18540/jcecvl10iss3pp18614 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
https://periodicos.ufv.br/jcec/article/view/18614/9585 |
dc.rights.driver.fl_str_mv |
Copyright (c) 2024 The Journal of Engineering and Exact Sciences https://creativecommons.org/licenses/by/4.0 info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
Copyright (c) 2024 The Journal of Engineering and Exact Sciences https://creativecommons.org/licenses/by/4.0 |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Federal de Viçosa - UFV |
publisher.none.fl_str_mv |
Universidade Federal de Viçosa - UFV |
dc.source.none.fl_str_mv |
The Journal of Engineering and Exact Sciences; Vol. 10 No. 3 (2024); 18614 The Journal of Engineering and Exact Sciences; Vol. 10 Núm. 3 (2024); 18614 The Journal of Engineering and Exact Sciences; v. 10 n. 3 (2024); 18614 2527-1075 reponame:Revista de Engenharia Química e Química instname:Universidade Federal de Viçosa (UFV) instacron:UFV |
instname_str |
Universidade Federal de Viçosa (UFV) |
instacron_str |
UFV |
institution |
UFV |
reponame_str |
Revista de Engenharia Química e Química |
collection |
Revista de Engenharia Química e Química |
repository.name.fl_str_mv |
Revista de Engenharia Química e Química - Universidade Federal de Viçosa (UFV) |
repository.mail.fl_str_mv |
jcec.journal@ufv.br||req2@ufv.br |
_version_ |
1800211186173607936 |