Structural and compositional changes in eucalyptus wood chips subjected to dry torrefaction
Autor(a) principal: | |
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Data de Publicação: | 2017 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | LOCUS Repositório Institucional da UFV |
Texto Completo: | https://doi.org/10.1016/j.indcrop.2017.09.010 http://www.locus.ufv.br/handle/123456789/21879 |
Resumo: | The aim of this study was to evaluate the structural and compositional changes in eucalyptus wood chips subjected to dry torrefaction. The experiment was conducted in a semi-continuous screw reactor with indirect heating system. Wood chips samples of three initial moisture contents (0, 15 and 30% dry basis) were torrefied up to three final temperatures (220, 260 and 300 °C) and at three heating times (10, 15 and 20 min). The effect of these variables was evaluated through the analysis of chemical composition, thermogravimetry and mechanical durability of the torrefied wood chips. The increase at temperature and time of torrefaction, as well as the drop in the initial moisture content, promoted significant structural and compositional changes in the wood chips. The torrefied samples present a higher resistance to thermal degradation, more friable structure, higher lignin and lower polysaccharides contents than the untreated samples. These changes made it possible to increase the quality of the eucalyptus wood chips to be use as a solid fuel. |
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Silva, Carlos Miguel Simões daVital, Benedito RochaCarneiro, Angélica de Cássia O.Costa, Emylle V. S.Magalhães, Mateus A. deTrugilho, Paulo F.2018-09-19T16:15:35Z2018-09-19T16:15:35Z2017-12-1509266690https://doi.org/10.1016/j.indcrop.2017.09.010http://www.locus.ufv.br/handle/123456789/21879The aim of this study was to evaluate the structural and compositional changes in eucalyptus wood chips subjected to dry torrefaction. The experiment was conducted in a semi-continuous screw reactor with indirect heating system. Wood chips samples of three initial moisture contents (0, 15 and 30% dry basis) were torrefied up to three final temperatures (220, 260 and 300 °C) and at three heating times (10, 15 and 20 min). The effect of these variables was evaluated through the analysis of chemical composition, thermogravimetry and mechanical durability of the torrefied wood chips. The increase at temperature and time of torrefaction, as well as the drop in the initial moisture content, promoted significant structural and compositional changes in the wood chips. The torrefied samples present a higher resistance to thermal degradation, more friable structure, higher lignin and lower polysaccharides contents than the untreated samples. These changes made it possible to increase the quality of the eucalyptus wood chips to be use as a solid fuel.engIndustrial Crops and Productsv. 109, p. 598- 602, dez. 2017Elsevier B.V.info:eu-repo/semantics/openAccessLignocellulosic biomassMild pyrolysisScrew reactorChemical compositionThermogravimetryMechanical durabilityStructural and compositional changes in eucalyptus wood chips subjected to dry torrefactioninfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articleapplication/pdfreponame:LOCUS Repositório Institucional da UFVinstname:Universidade Federal de Viçosa (UFV)instacron:UFVORIGINALartigo.pdfartigo.pdftexto completoapplication/pdf595461https://locus.ufv.br//bitstream/123456789/21879/1/artigo.pdff7ae1b20d05199e7f2df58cf1a2159feMD51LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://locus.ufv.br//bitstream/123456789/21879/2/license.txt8a4605be74aa9ea9d79846c1fba20a33MD52THUMBNAILartigo.pdf.jpgartigo.pdf.jpgIM Thumbnailimage/jpeg6203https://locus.ufv.br//bitstream/123456789/21879/3/artigo.pdf.jpgbd84ddc33b92c25aa3bfaebc956619b9MD53123456789/218792018-09-19 23:00:42.931oai:locus.ufv.br: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Repositório InstitucionalPUBhttps://www.locus.ufv.br/oai/requestfabiojreis@ufv.bropendoar:21452018-09-20T02:00:42LOCUS Repositório Institucional da UFV - Universidade Federal de Viçosa (UFV)false |
dc.title.en.fl_str_mv |
Structural and compositional changes in eucalyptus wood chips subjected to dry torrefaction |
title |
Structural and compositional changes in eucalyptus wood chips subjected to dry torrefaction |
spellingShingle |
Structural and compositional changes in eucalyptus wood chips subjected to dry torrefaction Silva, Carlos Miguel Simões da Lignocellulosic biomass Mild pyrolysis Screw reactor Chemical composition Thermogravimetry Mechanical durability |
title_short |
Structural and compositional changes in eucalyptus wood chips subjected to dry torrefaction |
title_full |
Structural and compositional changes in eucalyptus wood chips subjected to dry torrefaction |
title_fullStr |
Structural and compositional changes in eucalyptus wood chips subjected to dry torrefaction |
title_full_unstemmed |
Structural and compositional changes in eucalyptus wood chips subjected to dry torrefaction |
title_sort |
Structural and compositional changes in eucalyptus wood chips subjected to dry torrefaction |
author |
Silva, Carlos Miguel Simões da |
author_facet |
Silva, Carlos Miguel Simões da Vital, Benedito Rocha Carneiro, Angélica de Cássia O. Costa, Emylle V. S. Magalhães, Mateus A. de Trugilho, Paulo F. |
author_role |
author |
author2 |
Vital, Benedito Rocha Carneiro, Angélica de Cássia O. Costa, Emylle V. S. Magalhães, Mateus A. de Trugilho, Paulo F. |
author2_role |
author author author author author |
dc.contributor.author.fl_str_mv |
Silva, Carlos Miguel Simões da Vital, Benedito Rocha Carneiro, Angélica de Cássia O. Costa, Emylle V. S. Magalhães, Mateus A. de Trugilho, Paulo F. |
dc.subject.pt-BR.fl_str_mv |
Lignocellulosic biomass Mild pyrolysis Screw reactor Chemical composition Thermogravimetry Mechanical durability |
topic |
Lignocellulosic biomass Mild pyrolysis Screw reactor Chemical composition Thermogravimetry Mechanical durability |
description |
The aim of this study was to evaluate the structural and compositional changes in eucalyptus wood chips subjected to dry torrefaction. The experiment was conducted in a semi-continuous screw reactor with indirect heating system. Wood chips samples of three initial moisture contents (0, 15 and 30% dry basis) were torrefied up to three final temperatures (220, 260 and 300 °C) and at three heating times (10, 15 and 20 min). The effect of these variables was evaluated through the analysis of chemical composition, thermogravimetry and mechanical durability of the torrefied wood chips. The increase at temperature and time of torrefaction, as well as the drop in the initial moisture content, promoted significant structural and compositional changes in the wood chips. The torrefied samples present a higher resistance to thermal degradation, more friable structure, higher lignin and lower polysaccharides contents than the untreated samples. These changes made it possible to increase the quality of the eucalyptus wood chips to be use as a solid fuel. |
publishDate |
2017 |
dc.date.issued.fl_str_mv |
2017-12-15 |
dc.date.accessioned.fl_str_mv |
2018-09-19T16:15:35Z |
dc.date.available.fl_str_mv |
2018-09-19T16:15:35Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
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publishedVersion |
dc.identifier.uri.fl_str_mv |
https://doi.org/10.1016/j.indcrop.2017.09.010 http://www.locus.ufv.br/handle/123456789/21879 |
dc.identifier.issn.none.fl_str_mv |
09266690 |
identifier_str_mv |
09266690 |
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https://doi.org/10.1016/j.indcrop.2017.09.010 http://www.locus.ufv.br/handle/123456789/21879 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.ispartofseries.pt-BR.fl_str_mv |
v. 109, p. 598- 602, dez. 2017 |
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Elsevier B.V. info:eu-repo/semantics/openAccess |
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Elsevier B.V. |
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openAccess |
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Industrial Crops and Products |
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Industrial Crops and Products |
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