Model studies on the synthesis of the natural meroterpenoid cordiaquinone A

Bibliographic Details
Main Author: BATALINI,Claudemir
Publication Date: 2001
Other Authors: BIEBER,Lothar Wilhelm
Format: Article
Language: eng
Source: Eclética Química
Download full: http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702001000100005
Summary: Two main strategies for the synthesis of the natural meroterpenoid cordiaquinone A (1) - isolated of the roots of Cordia corymbosa G. Don (Boraginaceae) - were tested on model compounds. Whereas all attempts of alkylation of epsilon-caprolactone (10) were unsuccessful, the coupling of epoxycitronellol (17) with an appropriate organocuprate proceeded in the expected direction.
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spelling Model studies on the synthesis of the natural meroterpenoid cordiaquinone AMeroterpenoid naphthoquinoneCordia corymbosaBoraginaceaeepsilon-caprolactoneepoxycitronellolorganocuprateTwo main strategies for the synthesis of the natural meroterpenoid cordiaquinone A (1) - isolated of the roots of Cordia corymbosa G. Don (Boraginaceae) - were tested on model compounds. Whereas all attempts of alkylation of epsilon-caprolactone (10) were unsuccessful, the coupling of epoxycitronellol (17) with an appropriate organocuprate proceeded in the expected direction.Fundação Editora da Universidade Estadual Paulista Júlio de Mesquita Filho - UNESP2001-01-01info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersiontext/htmlhttp://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702001000100005Eclética Química v.26 2001reponame:Eclética Químicainstname:Universidade Estadual Paulista Júlio de Mesquita Filho (UNESP)instacron:UNESP10.1590/S0100-46702001000100005info:eu-repo/semantics/openAccessBATALINI,ClaudemirBIEBER,Lothar Wilhelmeng2002-11-26T00:00:00Zoai:scielo:S0100-46702001000100005Revistahttp://revista.iq.unesp.br/ojs/index.php/ecletica/PUBhttps://revista.iq.unesp.br/ojs/index.php/ecletica/oaiecletica@ctrlk.com.br||ecletica@iq.unesp.br1678-46181678-4618opendoar:2002-11-26T00:00Eclética Química - Universidade Estadual Paulista Júlio de Mesquita Filho (UNESP)false
dc.title.none.fl_str_mv Model studies on the synthesis of the natural meroterpenoid cordiaquinone A
title Model studies on the synthesis of the natural meroterpenoid cordiaquinone A
spellingShingle Model studies on the synthesis of the natural meroterpenoid cordiaquinone A
BATALINI,Claudemir
Meroterpenoid naphthoquinone
Cordia corymbosa
Boraginaceae
epsilon-caprolactone
epoxycitronellol
organocuprate
title_short Model studies on the synthesis of the natural meroterpenoid cordiaquinone A
title_full Model studies on the synthesis of the natural meroterpenoid cordiaquinone A
title_fullStr Model studies on the synthesis of the natural meroterpenoid cordiaquinone A
title_full_unstemmed Model studies on the synthesis of the natural meroterpenoid cordiaquinone A
title_sort Model studies on the synthesis of the natural meroterpenoid cordiaquinone A
author BATALINI,Claudemir
author_facet BATALINI,Claudemir
BIEBER,Lothar Wilhelm
author_role author
author2 BIEBER,Lothar Wilhelm
author2_role author
dc.contributor.author.fl_str_mv BATALINI,Claudemir
BIEBER,Lothar Wilhelm
dc.subject.por.fl_str_mv Meroterpenoid naphthoquinone
Cordia corymbosa
Boraginaceae
epsilon-caprolactone
epoxycitronellol
organocuprate
topic Meroterpenoid naphthoquinone
Cordia corymbosa
Boraginaceae
epsilon-caprolactone
epoxycitronellol
organocuprate
description Two main strategies for the synthesis of the natural meroterpenoid cordiaquinone A (1) - isolated of the roots of Cordia corymbosa G. Don (Boraginaceae) - were tested on model compounds. Whereas all attempts of alkylation of epsilon-caprolactone (10) were unsuccessful, the coupling of epoxycitronellol (17) with an appropriate organocuprate proceeded in the expected direction.
publishDate 2001
dc.date.none.fl_str_mv 2001-01-01
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702001000100005
url http://old.scielo.br/scielo.php?script=sci_arttext&pid=S0100-46702001000100005
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv 10.1590/S0100-46702001000100005
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv text/html
dc.publisher.none.fl_str_mv Fundação Editora da Universidade Estadual Paulista Júlio de Mesquita Filho - UNESP
publisher.none.fl_str_mv Fundação Editora da Universidade Estadual Paulista Júlio de Mesquita Filho - UNESP
dc.source.none.fl_str_mv Eclética Química v.26 2001
reponame:Eclética Química
instname:Universidade Estadual Paulista Júlio de Mesquita Filho (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista Júlio de Mesquita Filho (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Eclética Química
collection Eclética Química
repository.name.fl_str_mv Eclética Química - Universidade Estadual Paulista Júlio de Mesquita Filho (UNESP)
repository.mail.fl_str_mv ecletica@ctrlk.com.br||ecletica@iq.unesp.br
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