Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions

Detalhes bibliográficos
Autor(a) principal: Xavier, Cinthia Sany França
Data de Publicação: 2021
Outros Autores: Vieira, Fernando Fernandes, Alves, Marília Patrício, Sousa , Jóse Tavares de
Tipo de documento: Artigo
Idioma: por
Título da fonte: Research, Society and Development
Texto Completo: https://rsdjournal.org/index.php/rsd/article/view/16974
Resumo: In this research, the potential of sugarcane bagasse as a natural adsorbent of synthetic textile dye was evaluated. In the first stage of the research, the preparation and characterization of the adsorbent was carried out by determining the zero charge point - pHPCZ and Fourier transformation infrared spectroscopy (FTIR), it was found that adsorbent has a pHPCZ equal to 3.37 for dry material at 60 °C. In the second stage of the research, acidic and alkaline activations of adsorbent material were carried out and an experimental planning of the Box-Behnken type 25 for each adsorbent material, having the mass, concentration, pH, rotation and time as independent variables, evaluating adsorbed quantity responses (qt) and reduction in dye concentration (%red). The kinetic tests were performed at pH 3.0 and concentration of 150 mg.L-1, with samples collected every five minutes for up to 60 minutes, for fresh, acid and alkaline adsorbents. The kinetic data were adjusted to models of pseudo-first order, pseudo-second order and Elovich equation, with Elovich model being best adjusted to the tests. The isotherms were constructed varying concentration from 25 to 200 mg. L-1, with pH 3.0 and the Sips isotherm obtained a higher value of R2 and Test F. The sugarcane bagasse was attractive in the removal of the direct dye Tupy® burgundy 16, especially when the adsorbent treatment with HCl is carried out.
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spelling Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions Uso de bagazo de caña de azúcar en la adsorción de tintes textiles en soluciones acuosasUtilização do bagaço de cana-de-açúcar na adsorção de corantes têxteis em soluções aquosasAdsorciónEfluentes sintéticosBagazo de caña de azúcarAdsorçãoEfluentes sintéticosBagaço de cana-de-açúcarAdsorptionSynthetic effluentsSugarcane bagasseIn this research, the potential of sugarcane bagasse as a natural adsorbent of synthetic textile dye was evaluated. In the first stage of the research, the preparation and characterization of the adsorbent was carried out by determining the zero charge point - pHPCZ and Fourier transformation infrared spectroscopy (FTIR), it was found that adsorbent has a pHPCZ equal to 3.37 for dry material at 60 °C. In the second stage of the research, acidic and alkaline activations of adsorbent material were carried out and an experimental planning of the Box-Behnken type 25 for each adsorbent material, having the mass, concentration, pH, rotation and time as independent variables, evaluating adsorbed quantity responses (qt) and reduction in dye concentration (%red). The kinetic tests were performed at pH 3.0 and concentration of 150 mg.L-1, with samples collected every five minutes for up to 60 minutes, for fresh, acid and alkaline adsorbents. The kinetic data were adjusted to models of pseudo-first order, pseudo-second order and Elovich equation, with Elovich model being best adjusted to the tests. The isotherms were constructed varying concentration from 25 to 200 mg. L-1, with pH 3.0 and the Sips isotherm obtained a higher value of R2 and Test F. The sugarcane bagasse was attractive in the removal of the direct dye Tupy® burgundy 16, especially when the adsorbent treatment with HCl is carried out.En esta investigación, se evaluó el potencial del bagazo de caña de azúcar como adsorbente natural para tintes textiles sintéticos. En la primera etapa de la investigación se realizó la preparación y caracterización del adsorbente determinando el punto de carga cero - pHPCZ y Espectroscopía Infrarroja por Transformada de Fourier (FTIR), se encontró que el adsorbente tiene un pHPCZ igual a 3.37 para material secado a 60 ° C. En la segunda etapa de la investigación se realizó la activación ácida y alcalina del material adsorbente y un diseño experimental del tipo Box-Behnken 25 para cada material adsorbente, con masa, concentración, pH, rotación y tiempo como variables independientes, y se evaluaron las respuestas de la cantidad adsorbida (qt) y la reducción de la concentración de tinte (% rojo). Las pruebas cinéticas se realizaron a pH 3,0 y concentración de 150 mg. L-1, con toma de muestras cada cinco minutos hasta 60 minutos, para adsorbentes in natura, ácidos y alcalinos. Los datos cinéticos se ajustaron a modelos de ecuación de pseudo primer orden, pseudo segundo orden y ecuación de Elovich, siendo el modelo de Elovich el que mejor se ajustaba a las pruebas. Las isotermas se construyeron variando la concentración de 25 a 200 mg. L-1, con pH 3.0 y la isoterma Sips obtuvo el mayor valor R2 y Test F. El bagazo de caña de azúcar resultó atractivo en la remoción del colorante directo Tupy® color 16, especialmente cuando se realiza tratamiento del adsorbente con HCl.Nesta pesquisa avaliou-se o potencial do bagaço da cana-de-açúcar como adsorvente natural do corante têxtil sintético. Na primeira etapa da pesquisa foi realizado a preparação e caracterização do adsorvente através da determinação do ponto de carga zero – pHPCZ e da Espectroscopia de infravermelho com transformação de Fourier (FTIR), verificou-se que o adsorvente possui um pHPCZ igual a 3,37 para o material seco à 60 °C. Na segunda etapa da pesquisa foram realizadas ativações ácida e alcalina do material adsorvente e um planejamento experimental do tipo Box-Behnken 25 para cada material adsorvente tendo como variáveis independentes a massa, concentração, pH, rotação e tempo sendo avaliadas as respostas quantidade adsorvida (qt) e redução na concentração de corante (%red). Os ensaios cinéticos foram realizados em pH 3,0 e concentração de 150 mg. L-1, sendo coletadas amostras a cada cinco minutos até 60 minutos, para os adsorventes in natura, ácido e alcalino. Os dados cinéticos foram ajustados aos modelos de pseudo-primeira ordem, pseudo-segunda ordem e equação de Elovich, sendo o modelo de Elovich o que melhor se ajustou aos ensaios. As isotermas foram construídas variando a concentração de 25 a 200 mg. L-1, com pH 3,0 e a isoterma de Sips obteve maior valor de R2 e Teste F. O bagaço da cana-de-açúcar mostrou-se atraente na remoção do corante direto Tupy® cor bordô 16, principalmente quando é realizado o tratamento do adsorvente com HCl.Research, Society and Development2021-06-23info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://rsdjournal.org/index.php/rsd/article/view/1697410.33448/rsd-v10i7.16974Research, Society and Development; Vol. 10 No. 7; e59110716974Research, Society and Development; Vol. 10 Núm. 7; e59110716974Research, Society and Development; v. 10 n. 7; e591107169742525-3409reponame:Research, Society and Developmentinstname:Universidade Federal de Itajubá (UNIFEI)instacron:UNIFEIporhttps://rsdjournal.org/index.php/rsd/article/view/16974/14828Copyright (c) 2021 Cinthia Sany França Xavier; Fernando Fernandes Vieira; Marília Patrício Alves; Jóse Tavares de Sousa https://creativecommons.org/licenses/by/4.0info:eu-repo/semantics/openAccessXavier, Cinthia Sany FrançaVieira, Fernando Fernandes Alves, Marília Patrício Sousa , Jóse Tavares de2021-07-18T21:07:03Zoai:ojs.pkp.sfu.ca:article/16974Revistahttps://rsdjournal.org/index.php/rsd/indexPUBhttps://rsdjournal.org/index.php/rsd/oairsd.articles@gmail.com2525-34092525-3409opendoar:2024-01-17T09:37:23.240252Research, Society and Development - Universidade Federal de Itajubá (UNIFEI)false
dc.title.none.fl_str_mv Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions
Uso de bagazo de caña de azúcar en la adsorción de tintes textiles en soluciones acuosas
Utilização do bagaço de cana-de-açúcar na adsorção de corantes têxteis em soluções aquosas
title Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions
spellingShingle Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions
Xavier, Cinthia Sany França
Adsorción
Efluentes sintéticos
Bagazo de caña de azúcar
Adsorção
Efluentes sintéticos
Bagaço de cana-de-açúcar
Adsorption
Synthetic effluents
Sugarcane bagasse
title_short Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions
title_full Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions
title_fullStr Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions
title_full_unstemmed Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions
title_sort Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions
author Xavier, Cinthia Sany França
author_facet Xavier, Cinthia Sany França
Vieira, Fernando Fernandes
Alves, Marília Patrício
Sousa , Jóse Tavares de
author_role author
author2 Vieira, Fernando Fernandes
Alves, Marília Patrício
Sousa , Jóse Tavares de
author2_role author
author
author
dc.contributor.author.fl_str_mv Xavier, Cinthia Sany França
Vieira, Fernando Fernandes
Alves, Marília Patrício
Sousa , Jóse Tavares de
dc.subject.por.fl_str_mv Adsorción
Efluentes sintéticos
Bagazo de caña de azúcar
Adsorção
Efluentes sintéticos
Bagaço de cana-de-açúcar
Adsorption
Synthetic effluents
Sugarcane bagasse
topic Adsorción
Efluentes sintéticos
Bagazo de caña de azúcar
Adsorção
Efluentes sintéticos
Bagaço de cana-de-açúcar
Adsorption
Synthetic effluents
Sugarcane bagasse
description In this research, the potential of sugarcane bagasse as a natural adsorbent of synthetic textile dye was evaluated. In the first stage of the research, the preparation and characterization of the adsorbent was carried out by determining the zero charge point - pHPCZ and Fourier transformation infrared spectroscopy (FTIR), it was found that adsorbent has a pHPCZ equal to 3.37 for dry material at 60 °C. In the second stage of the research, acidic and alkaline activations of adsorbent material were carried out and an experimental planning of the Box-Behnken type 25 for each adsorbent material, having the mass, concentration, pH, rotation and time as independent variables, evaluating adsorbed quantity responses (qt) and reduction in dye concentration (%red). The kinetic tests were performed at pH 3.0 and concentration of 150 mg.L-1, with samples collected every five minutes for up to 60 minutes, for fresh, acid and alkaline adsorbents. The kinetic data were adjusted to models of pseudo-first order, pseudo-second order and Elovich equation, with Elovich model being best adjusted to the tests. The isotherms were constructed varying concentration from 25 to 200 mg. L-1, with pH 3.0 and the Sips isotherm obtained a higher value of R2 and Test F. The sugarcane bagasse was attractive in the removal of the direct dye Tupy® burgundy 16, especially when the adsorbent treatment with HCl is carried out.
publishDate 2021
dc.date.none.fl_str_mv 2021-06-23
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://rsdjournal.org/index.php/rsd/article/view/16974
10.33448/rsd-v10i7.16974
url https://rsdjournal.org/index.php/rsd/article/view/16974
identifier_str_mv 10.33448/rsd-v10i7.16974
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv https://rsdjournal.org/index.php/rsd/article/view/16974/14828
dc.rights.driver.fl_str_mv https://creativecommons.org/licenses/by/4.0
info:eu-repo/semantics/openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/4.0
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Research, Society and Development
publisher.none.fl_str_mv Research, Society and Development
dc.source.none.fl_str_mv Research, Society and Development; Vol. 10 No. 7; e59110716974
Research, Society and Development; Vol. 10 Núm. 7; e59110716974
Research, Society and Development; v. 10 n. 7; e59110716974
2525-3409
reponame:Research, Society and Development
instname:Universidade Federal de Itajubá (UNIFEI)
instacron:UNIFEI
instname_str Universidade Federal de Itajubá (UNIFEI)
instacron_str UNIFEI
institution UNIFEI
reponame_str Research, Society and Development
collection Research, Society and Development
repository.name.fl_str_mv Research, Society and Development - Universidade Federal de Itajubá (UNIFEI)
repository.mail.fl_str_mv rsd.articles@gmail.com
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