Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions
Autor(a) principal: | |
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Data de Publicação: | 2021 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Research, Society and Development |
Texto Completo: | https://rsdjournal.org/index.php/rsd/article/view/16974 |
Resumo: | In this research, the potential of sugarcane bagasse as a natural adsorbent of synthetic textile dye was evaluated. In the first stage of the research, the preparation and characterization of the adsorbent was carried out by determining the zero charge point - pHPCZ and Fourier transformation infrared spectroscopy (FTIR), it was found that adsorbent has a pHPCZ equal to 3.37 for dry material at 60 °C. In the second stage of the research, acidic and alkaline activations of adsorbent material were carried out and an experimental planning of the Box-Behnken type 25 for each adsorbent material, having the mass, concentration, pH, rotation and time as independent variables, evaluating adsorbed quantity responses (qt) and reduction in dye concentration (%red). The kinetic tests were performed at pH 3.0 and concentration of 150 mg.L-1, with samples collected every five minutes for up to 60 minutes, for fresh, acid and alkaline adsorbents. The kinetic data were adjusted to models of pseudo-first order, pseudo-second order and Elovich equation, with Elovich model being best adjusted to the tests. The isotherms were constructed varying concentration from 25 to 200 mg. L-1, with pH 3.0 and the Sips isotherm obtained a higher value of R2 and Test F. The sugarcane bagasse was attractive in the removal of the direct dye Tupy® burgundy 16, especially when the adsorbent treatment with HCl is carried out. |
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Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions Uso de bagazo de caña de azúcar en la adsorción de tintes textiles en soluciones acuosasUtilização do bagaço de cana-de-açúcar na adsorção de corantes têxteis em soluções aquosasAdsorciónEfluentes sintéticosBagazo de caña de azúcarAdsorçãoEfluentes sintéticosBagaço de cana-de-açúcarAdsorptionSynthetic effluentsSugarcane bagasseIn this research, the potential of sugarcane bagasse as a natural adsorbent of synthetic textile dye was evaluated. In the first stage of the research, the preparation and characterization of the adsorbent was carried out by determining the zero charge point - pHPCZ and Fourier transformation infrared spectroscopy (FTIR), it was found that adsorbent has a pHPCZ equal to 3.37 for dry material at 60 °C. In the second stage of the research, acidic and alkaline activations of adsorbent material were carried out and an experimental planning of the Box-Behnken type 25 for each adsorbent material, having the mass, concentration, pH, rotation and time as independent variables, evaluating adsorbed quantity responses (qt) and reduction in dye concentration (%red). The kinetic tests were performed at pH 3.0 and concentration of 150 mg.L-1, with samples collected every five minutes for up to 60 minutes, for fresh, acid and alkaline adsorbents. The kinetic data were adjusted to models of pseudo-first order, pseudo-second order and Elovich equation, with Elovich model being best adjusted to the tests. The isotherms were constructed varying concentration from 25 to 200 mg. L-1, with pH 3.0 and the Sips isotherm obtained a higher value of R2 and Test F. The sugarcane bagasse was attractive in the removal of the direct dye Tupy® burgundy 16, especially when the adsorbent treatment with HCl is carried out.En esta investigación, se evaluó el potencial del bagazo de caña de azúcar como adsorbente natural para tintes textiles sintéticos. En la primera etapa de la investigación se realizó la preparación y caracterización del adsorbente determinando el punto de carga cero - pHPCZ y Espectroscopía Infrarroja por Transformada de Fourier (FTIR), se encontró que el adsorbente tiene un pHPCZ igual a 3.37 para material secado a 60 ° C. En la segunda etapa de la investigación se realizó la activación ácida y alcalina del material adsorbente y un diseño experimental del tipo Box-Behnken 25 para cada material adsorbente, con masa, concentración, pH, rotación y tiempo como variables independientes, y se evaluaron las respuestas de la cantidad adsorbida (qt) y la reducción de la concentración de tinte (% rojo). Las pruebas cinéticas se realizaron a pH 3,0 y concentración de 150 mg. L-1, con toma de muestras cada cinco minutos hasta 60 minutos, para adsorbentes in natura, ácidos y alcalinos. Los datos cinéticos se ajustaron a modelos de ecuación de pseudo primer orden, pseudo segundo orden y ecuación de Elovich, siendo el modelo de Elovich el que mejor se ajustaba a las pruebas. Las isotermas se construyeron variando la concentración de 25 a 200 mg. L-1, con pH 3.0 y la isoterma Sips obtuvo el mayor valor R2 y Test F. El bagazo de caña de azúcar resultó atractivo en la remoción del colorante directo Tupy® color 16, especialmente cuando se realiza tratamiento del adsorbente con HCl.Nesta pesquisa avaliou-se o potencial do bagaço da cana-de-açúcar como adsorvente natural do corante têxtil sintético. Na primeira etapa da pesquisa foi realizado a preparação e caracterização do adsorvente através da determinação do ponto de carga zero – pHPCZ e da Espectroscopia de infravermelho com transformação de Fourier (FTIR), verificou-se que o adsorvente possui um pHPCZ igual a 3,37 para o material seco à 60 °C. Na segunda etapa da pesquisa foram realizadas ativações ácida e alcalina do material adsorvente e um planejamento experimental do tipo Box-Behnken 25 para cada material adsorvente tendo como variáveis independentes a massa, concentração, pH, rotação e tempo sendo avaliadas as respostas quantidade adsorvida (qt) e redução na concentração de corante (%red). Os ensaios cinéticos foram realizados em pH 3,0 e concentração de 150 mg. L-1, sendo coletadas amostras a cada cinco minutos até 60 minutos, para os adsorventes in natura, ácido e alcalino. Os dados cinéticos foram ajustados aos modelos de pseudo-primeira ordem, pseudo-segunda ordem e equação de Elovich, sendo o modelo de Elovich o que melhor se ajustou aos ensaios. As isotermas foram construídas variando a concentração de 25 a 200 mg. L-1, com pH 3,0 e a isoterma de Sips obteve maior valor de R2 e Teste F. O bagaço da cana-de-açúcar mostrou-se atraente na remoção do corante direto Tupy® cor bordô 16, principalmente quando é realizado o tratamento do adsorvente com HCl.Research, Society and Development2021-06-23info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://rsdjournal.org/index.php/rsd/article/view/1697410.33448/rsd-v10i7.16974Research, Society and Development; Vol. 10 No. 7; e59110716974Research, Society and Development; Vol. 10 Núm. 7; e59110716974Research, Society and Development; v. 10 n. 7; e591107169742525-3409reponame:Research, Society and Developmentinstname:Universidade Federal de Itajubá (UNIFEI)instacron:UNIFEIporhttps://rsdjournal.org/index.php/rsd/article/view/16974/14828Copyright (c) 2021 Cinthia Sany França Xavier; Fernando Fernandes Vieira; Marília Patrício Alves; Jóse Tavares de Sousa https://creativecommons.org/licenses/by/4.0info:eu-repo/semantics/openAccessXavier, Cinthia Sany FrançaVieira, Fernando Fernandes Alves, Marília Patrício Sousa , Jóse Tavares de2021-07-18T21:07:03Zoai:ojs.pkp.sfu.ca:article/16974Revistahttps://rsdjournal.org/index.php/rsd/indexPUBhttps://rsdjournal.org/index.php/rsd/oairsd.articles@gmail.com2525-34092525-3409opendoar:2024-01-17T09:37:23.240252Research, Society and Development - Universidade Federal de Itajubá (UNIFEI)false |
dc.title.none.fl_str_mv |
Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions Uso de bagazo de caña de azúcar en la adsorción de tintes textiles en soluciones acuosas Utilização do bagaço de cana-de-açúcar na adsorção de corantes têxteis em soluções aquosas |
title |
Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions |
spellingShingle |
Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions Xavier, Cinthia Sany França Adsorción Efluentes sintéticos Bagazo de caña de azúcar Adsorção Efluentes sintéticos Bagaço de cana-de-açúcar Adsorption Synthetic effluents Sugarcane bagasse |
title_short |
Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions |
title_full |
Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions |
title_fullStr |
Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions |
title_full_unstemmed |
Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions |
title_sort |
Use of sugarcane bagasse in the adsorption of textile dyes in aqueous solutions |
author |
Xavier, Cinthia Sany França |
author_facet |
Xavier, Cinthia Sany França Vieira, Fernando Fernandes Alves, Marília Patrício Sousa , Jóse Tavares de |
author_role |
author |
author2 |
Vieira, Fernando Fernandes Alves, Marília Patrício Sousa , Jóse Tavares de |
author2_role |
author author author |
dc.contributor.author.fl_str_mv |
Xavier, Cinthia Sany França Vieira, Fernando Fernandes Alves, Marília Patrício Sousa , Jóse Tavares de |
dc.subject.por.fl_str_mv |
Adsorción Efluentes sintéticos Bagazo de caña de azúcar Adsorção Efluentes sintéticos Bagaço de cana-de-açúcar Adsorption Synthetic effluents Sugarcane bagasse |
topic |
Adsorción Efluentes sintéticos Bagazo de caña de azúcar Adsorção Efluentes sintéticos Bagaço de cana-de-açúcar Adsorption Synthetic effluents Sugarcane bagasse |
description |
In this research, the potential of sugarcane bagasse as a natural adsorbent of synthetic textile dye was evaluated. In the first stage of the research, the preparation and characterization of the adsorbent was carried out by determining the zero charge point - pHPCZ and Fourier transformation infrared spectroscopy (FTIR), it was found that adsorbent has a pHPCZ equal to 3.37 for dry material at 60 °C. In the second stage of the research, acidic and alkaline activations of adsorbent material were carried out and an experimental planning of the Box-Behnken type 25 for each adsorbent material, having the mass, concentration, pH, rotation and time as independent variables, evaluating adsorbed quantity responses (qt) and reduction in dye concentration (%red). The kinetic tests were performed at pH 3.0 and concentration of 150 mg.L-1, with samples collected every five minutes for up to 60 minutes, for fresh, acid and alkaline adsorbents. The kinetic data were adjusted to models of pseudo-first order, pseudo-second order and Elovich equation, with Elovich model being best adjusted to the tests. The isotherms were constructed varying concentration from 25 to 200 mg. L-1, with pH 3.0 and the Sips isotherm obtained a higher value of R2 and Test F. The sugarcane bagasse was attractive in the removal of the direct dye Tupy® burgundy 16, especially when the adsorbent treatment with HCl is carried out. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-06-23 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://rsdjournal.org/index.php/rsd/article/view/16974 10.33448/rsd-v10i7.16974 |
url |
https://rsdjournal.org/index.php/rsd/article/view/16974 |
identifier_str_mv |
10.33448/rsd-v10i7.16974 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
https://rsdjournal.org/index.php/rsd/article/view/16974/14828 |
dc.rights.driver.fl_str_mv |
https://creativecommons.org/licenses/by/4.0 info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by/4.0 |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Research, Society and Development |
publisher.none.fl_str_mv |
Research, Society and Development |
dc.source.none.fl_str_mv |
Research, Society and Development; Vol. 10 No. 7; e59110716974 Research, Society and Development; Vol. 10 Núm. 7; e59110716974 Research, Society and Development; v. 10 n. 7; e59110716974 2525-3409 reponame:Research, Society and Development instname:Universidade Federal de Itajubá (UNIFEI) instacron:UNIFEI |
instname_str |
Universidade Federal de Itajubá (UNIFEI) |
instacron_str |
UNIFEI |
institution |
UNIFEI |
reponame_str |
Research, Society and Development |
collection |
Research, Society and Development |
repository.name.fl_str_mv |
Research, Society and Development - Universidade Federal de Itajubá (UNIFEI) |
repository.mail.fl_str_mv |
rsd.articles@gmail.com |
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1797052681170190336 |