Study of the residual polymer-aluminum recycling process of carton packaging

Detalhes bibliográficos
Autor(a) principal: Pauletti, Hellen Cristina
Data de Publicação: 2021
Outros Autores: Vicari, Paulo, Klauck, Marília Gabriela, Patussi, Pahola, Cima, Letícia Bavaresco, Colpani, Gustavo Lopes, Silva, Luciano Luiz, Zanetti, Micheli, Mello, Josiane Maria Muneron de, Fiori, Márcio Antônio
Tipo de documento: Artigo
Idioma: por
Título da fonte: Research, Society and Development
Texto Completo: https://rsdjournal.org/index.php/rsd/article/view/20592
Resumo: The complexity of the structure of carton packs is one of the factors that hinder the development of processes for recycling after consumption. The few processes that are currently used do not manage to completely recycle all the materials used in these packages. The few economically viable processes are applied to the recycling of paper layers, leaving as a residue the combined layers of polyethylene and aluminum, known as polymer-aluminum residues (Poly-Al) from carton packs. In this context, a method for recycling polyethylene and aluminum present in Poly-Al residues from post-consumer carton packs was researched and developed using the alkaline aluminum digestion process. Solutions with different concentrations of NaOH were evaluated at an ambient temperature with a treatment time of 24 h. After the aluminum removal processes, the polyethylene films and the liquid and solid phases precipitated from the reaction medium were analyzed. Scanning electron microscopy (SEM/FEG), dispersive x-ray fluorescence energy spectroscopy (EDS), x-ray diffraction (XRD), inductively coupled plasma mass spectrometry (ICP) and calorimetry differential scanning (DSC) were used for the analyzes. The results indicated the removal of aluminum from polyethylene films from Poly-Al residues with good efficiency and without significantly compromising the thermal properties of the polymer.
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spelling Study of the residual polymer-aluminum recycling process of carton packagingEstudio del processo de reciclaje de residuos de polímero-aluminio de envases de cartonEstudo do processo de reciclagem de polímero-alumínio residual de embalagens cartonadasCarton packagingRecyclingPolymer-Aluminum.Envases de cartónReciclajePolímero-Aluminio.Embalagem cartonadaReciclagemPolímero-Alumínio.The complexity of the structure of carton packs is one of the factors that hinder the development of processes for recycling after consumption. The few processes that are currently used do not manage to completely recycle all the materials used in these packages. The few economically viable processes are applied to the recycling of paper layers, leaving as a residue the combined layers of polyethylene and aluminum, known as polymer-aluminum residues (Poly-Al) from carton packs. In this context, a method for recycling polyethylene and aluminum present in Poly-Al residues from post-consumer carton packs was researched and developed using the alkaline aluminum digestion process. Solutions with different concentrations of NaOH were evaluated at an ambient temperature with a treatment time of 24 h. After the aluminum removal processes, the polyethylene films and the liquid and solid phases precipitated from the reaction medium were analyzed. Scanning electron microscopy (SEM/FEG), dispersive x-ray fluorescence energy spectroscopy (EDS), x-ray diffraction (XRD), inductively coupled plasma mass spectrometry (ICP) and calorimetry differential scanning (DSC) were used for the analyzes. The results indicated the removal of aluminum from polyethylene films from Poly-Al residues with good efficiency and without significantly compromising the thermal properties of the polymer.La complejidad de la estructura de los envases de cartón es uno de los factores que impiden el desarrollo de los procesos de reciclaje después el consumo. Los procesos que se utilizan actualmente no pueden reciclar por completo todos los materiales utilizados en estos envases. Los pocos procesos económicamente viables se aplican para reciclar las capas de papel, dejando como residuo las capas combinadas de polietileno y aluminio, conocidas como residuos de polímero-aluminio (Poly-Al) de los envases de cartón. En este contexto, se investigó y desarrolló un método de reciclaje de polietileno y aluminio, presente en los residuos de Poly-Al de envases de cartón posconsumo, utilizando el proceso de digestión alcalina de aluminio. Se evaluaron soluciones con diferentes concentraciones de NaOH a temperatura ambiente con un tiempo de tratamiento de 24 h. Después de los procesos de eliminación de aluminio, se analizaron las películas de polietileno y las fases líquida y sólida precipitadas del medio de reacción. Para los análisis se utilizaron microscopía electrónica de barrido (MEB), espectroscopia de fluorescencia de rayos X de dispersión de energía (EDS), difracción de rayos X (DRX), espectrometría de masas de plasma acoplado inductivamente (ICP) y calorimetría diferencial de barrido (DSC). Los resultados indicaron la eliminación de aluminio de las películas de polietileno de los residuos de Poly-Al con buena eficiencia y sin comprometer significativamente las propiedades térmicas del polímero.A complexidade da estrutura das embalagens cartonadas é um dos fatores que impedem o desenvolvimento de processos de reciclagem após o consumo. Os processos utilizados atualmente não conseguem reciclar completamente todos os materiais utilizados nestas embalagens. Os poucos processos economicamente viáveis são aplicados para reciclagem das camadas de papel, deixando como resíduo as camadas combinadas de polietileno e alumínio, conhecidas como resíduos de polímero-alumínio (Poli-Al) das embalagens cartonadas. Nesse contexto, um método de reciclagem para polietileno e alumínio, presente nos resíduos de Poli-Al de embalagens cartonadas pós-consumo, foi pesquisado e desenvolvido utilizando o processo de digestão alcalina de alumínio. Soluções com diferentes concentrações de NaOH foram avaliadas em temperatura ambiente com tempo de tratamento de 24 h. Após os processos de remoção do alumínio, analisou-se os filmes de polietileno e as fases líquida e sólida precipitadas do meio reacional. Microscopia eletrônica de varredura (MEV/FEG), espectroscopia de energia de fluorescência de raios-X dispersiva (EDS), difração de raios-X (DRX), espectrometria de massa com plasma indutivamente acoplado (ICP) e varredura diferencial de calorimetria (DSC) foram usados para as análises. Os resultados indicaram a remoção do alumínio dos filmes de polietileno dos resíduos de Poli-Al com boa eficiência e sem comprometer significativamente as propriedades térmicas do polímero.Research, Society and Development2021-10-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://rsdjournal.org/index.php/rsd/article/view/2059210.33448/rsd-v10i13.20592Research, Society and Development; Vol. 10 No. 13; e240101320592Research, Society and Development; Vol. 10 Núm. 13; e240101320592Research, Society and Development; v. 10 n. 13; e2401013205922525-3409reponame:Research, Society and Developmentinstname:Universidade Federal de Itajubá (UNIFEI)instacron:UNIFEIporhttps://rsdjournal.org/index.php/rsd/article/view/20592/18865Copyright (c) 2021 Hellen Cristina Pauletti; Paulo Vicari; Marília Gabriela Klauck; Pahola Patussi; Letícia Bavaresco Cima; Gustavo Lopes Colpani; Luciano Luiz Silva; Micheli Zanetti; Josiane Maria Muneron de Mello; Márcio Antônio Fiorihttps://creativecommons.org/licenses/by/4.0info:eu-repo/semantics/openAccessPauletti, Hellen Cristina Vicari, PauloKlauck, Marília Gabriela Patussi, Pahola Cima, Letícia Bavaresco Colpani, Gustavo Lopes Silva, Luciano Luiz Zanetti, Micheli Mello, Josiane Maria Muneron de Fiori, Márcio Antônio 2021-11-21T18:26:28Zoai:ojs.pkp.sfu.ca:article/20592Revistahttps://rsdjournal.org/index.php/rsd/indexPUBhttps://rsdjournal.org/index.php/rsd/oairsd.articles@gmail.com2525-34092525-3409opendoar:2024-01-17T09:40:11.752305Research, Society and Development - Universidade Federal de Itajubá (UNIFEI)false
dc.title.none.fl_str_mv Study of the residual polymer-aluminum recycling process of carton packaging
Estudio del processo de reciclaje de residuos de polímero-aluminio de envases de carton
Estudo do processo de reciclagem de polímero-alumínio residual de embalagens cartonadas
title Study of the residual polymer-aluminum recycling process of carton packaging
spellingShingle Study of the residual polymer-aluminum recycling process of carton packaging
Pauletti, Hellen Cristina
Carton packaging
Recycling
Polymer-Aluminum.
Envases de cartón
Reciclaje
Polímero-Aluminio.
Embalagem cartonada
Reciclagem
Polímero-Alumínio.
title_short Study of the residual polymer-aluminum recycling process of carton packaging
title_full Study of the residual polymer-aluminum recycling process of carton packaging
title_fullStr Study of the residual polymer-aluminum recycling process of carton packaging
title_full_unstemmed Study of the residual polymer-aluminum recycling process of carton packaging
title_sort Study of the residual polymer-aluminum recycling process of carton packaging
author Pauletti, Hellen Cristina
author_facet Pauletti, Hellen Cristina
Vicari, Paulo
Klauck, Marília Gabriela
Patussi, Pahola
Cima, Letícia Bavaresco
Colpani, Gustavo Lopes
Silva, Luciano Luiz
Zanetti, Micheli
Mello, Josiane Maria Muneron de
Fiori, Márcio Antônio
author_role author
author2 Vicari, Paulo
Klauck, Marília Gabriela
Patussi, Pahola
Cima, Letícia Bavaresco
Colpani, Gustavo Lopes
Silva, Luciano Luiz
Zanetti, Micheli
Mello, Josiane Maria Muneron de
Fiori, Márcio Antônio
author2_role author
author
author
author
author
author
author
author
author
dc.contributor.author.fl_str_mv Pauletti, Hellen Cristina
Vicari, Paulo
Klauck, Marília Gabriela
Patussi, Pahola
Cima, Letícia Bavaresco
Colpani, Gustavo Lopes
Silva, Luciano Luiz
Zanetti, Micheli
Mello, Josiane Maria Muneron de
Fiori, Márcio Antônio
dc.subject.por.fl_str_mv Carton packaging
Recycling
Polymer-Aluminum.
Envases de cartón
Reciclaje
Polímero-Aluminio.
Embalagem cartonada
Reciclagem
Polímero-Alumínio.
topic Carton packaging
Recycling
Polymer-Aluminum.
Envases de cartón
Reciclaje
Polímero-Aluminio.
Embalagem cartonada
Reciclagem
Polímero-Alumínio.
description The complexity of the structure of carton packs is one of the factors that hinder the development of processes for recycling after consumption. The few processes that are currently used do not manage to completely recycle all the materials used in these packages. The few economically viable processes are applied to the recycling of paper layers, leaving as a residue the combined layers of polyethylene and aluminum, known as polymer-aluminum residues (Poly-Al) from carton packs. In this context, a method for recycling polyethylene and aluminum present in Poly-Al residues from post-consumer carton packs was researched and developed using the alkaline aluminum digestion process. Solutions with different concentrations of NaOH were evaluated at an ambient temperature with a treatment time of 24 h. After the aluminum removal processes, the polyethylene films and the liquid and solid phases precipitated from the reaction medium were analyzed. Scanning electron microscopy (SEM/FEG), dispersive x-ray fluorescence energy spectroscopy (EDS), x-ray diffraction (XRD), inductively coupled plasma mass spectrometry (ICP) and calorimetry differential scanning (DSC) were used for the analyzes. The results indicated the removal of aluminum from polyethylene films from Poly-Al residues with good efficiency and without significantly compromising the thermal properties of the polymer.
publishDate 2021
dc.date.none.fl_str_mv 2021-10-10
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
info:eu-repo/semantics/publishedVersion
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv https://rsdjournal.org/index.php/rsd/article/view/20592
10.33448/rsd-v10i13.20592
url https://rsdjournal.org/index.php/rsd/article/view/20592
identifier_str_mv 10.33448/rsd-v10i13.20592
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv https://rsdjournal.org/index.php/rsd/article/view/20592/18865
dc.rights.driver.fl_str_mv https://creativecommons.org/licenses/by/4.0
info:eu-repo/semantics/openAccess
rights_invalid_str_mv https://creativecommons.org/licenses/by/4.0
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Research, Society and Development
publisher.none.fl_str_mv Research, Society and Development
dc.source.none.fl_str_mv Research, Society and Development; Vol. 10 No. 13; e240101320592
Research, Society and Development; Vol. 10 Núm. 13; e240101320592
Research, Society and Development; v. 10 n. 13; e240101320592
2525-3409
reponame:Research, Society and Development
instname:Universidade Federal de Itajubá (UNIFEI)
instacron:UNIFEI
instname_str Universidade Federal de Itajubá (UNIFEI)
instacron_str UNIFEI
institution UNIFEI
reponame_str Research, Society and Development
collection Research, Society and Development
repository.name.fl_str_mv Research, Society and Development - Universidade Federal de Itajubá (UNIFEI)
repository.mail.fl_str_mv rsd.articles@gmail.com
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