Study of the residual polymer-aluminum recycling process of carton packaging
Autor(a) principal: | |
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Data de Publicação: | 2021 |
Outros Autores: | , , , , , , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Research, Society and Development |
Texto Completo: | https://rsdjournal.org/index.php/rsd/article/view/20592 |
Resumo: | The complexity of the structure of carton packs is one of the factors that hinder the development of processes for recycling after consumption. The few processes that are currently used do not manage to completely recycle all the materials used in these packages. The few economically viable processes are applied to the recycling of paper layers, leaving as a residue the combined layers of polyethylene and aluminum, known as polymer-aluminum residues (Poly-Al) from carton packs. In this context, a method for recycling polyethylene and aluminum present in Poly-Al residues from post-consumer carton packs was researched and developed using the alkaline aluminum digestion process. Solutions with different concentrations of NaOH were evaluated at an ambient temperature with a treatment time of 24 h. After the aluminum removal processes, the polyethylene films and the liquid and solid phases precipitated from the reaction medium were analyzed. Scanning electron microscopy (SEM/FEG), dispersive x-ray fluorescence energy spectroscopy (EDS), x-ray diffraction (XRD), inductively coupled plasma mass spectrometry (ICP) and calorimetry differential scanning (DSC) were used for the analyzes. The results indicated the removal of aluminum from polyethylene films from Poly-Al residues with good efficiency and without significantly compromising the thermal properties of the polymer. |
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Study of the residual polymer-aluminum recycling process of carton packagingEstudio del processo de reciclaje de residuos de polímero-aluminio de envases de cartonEstudo do processo de reciclagem de polímero-alumínio residual de embalagens cartonadasCarton packagingRecyclingPolymer-Aluminum.Envases de cartónReciclajePolímero-Aluminio.Embalagem cartonadaReciclagemPolímero-Alumínio.The complexity of the structure of carton packs is one of the factors that hinder the development of processes for recycling after consumption. The few processes that are currently used do not manage to completely recycle all the materials used in these packages. The few economically viable processes are applied to the recycling of paper layers, leaving as a residue the combined layers of polyethylene and aluminum, known as polymer-aluminum residues (Poly-Al) from carton packs. In this context, a method for recycling polyethylene and aluminum present in Poly-Al residues from post-consumer carton packs was researched and developed using the alkaline aluminum digestion process. Solutions with different concentrations of NaOH were evaluated at an ambient temperature with a treatment time of 24 h. After the aluminum removal processes, the polyethylene films and the liquid and solid phases precipitated from the reaction medium were analyzed. Scanning electron microscopy (SEM/FEG), dispersive x-ray fluorescence energy spectroscopy (EDS), x-ray diffraction (XRD), inductively coupled plasma mass spectrometry (ICP) and calorimetry differential scanning (DSC) were used for the analyzes. The results indicated the removal of aluminum from polyethylene films from Poly-Al residues with good efficiency and without significantly compromising the thermal properties of the polymer.La complejidad de la estructura de los envases de cartón es uno de los factores que impiden el desarrollo de los procesos de reciclaje después el consumo. Los procesos que se utilizan actualmente no pueden reciclar por completo todos los materiales utilizados en estos envases. Los pocos procesos económicamente viables se aplican para reciclar las capas de papel, dejando como residuo las capas combinadas de polietileno y aluminio, conocidas como residuos de polímero-aluminio (Poly-Al) de los envases de cartón. En este contexto, se investigó y desarrolló un método de reciclaje de polietileno y aluminio, presente en los residuos de Poly-Al de envases de cartón posconsumo, utilizando el proceso de digestión alcalina de aluminio. Se evaluaron soluciones con diferentes concentraciones de NaOH a temperatura ambiente con un tiempo de tratamiento de 24 h. Después de los procesos de eliminación de aluminio, se analizaron las películas de polietileno y las fases líquida y sólida precipitadas del medio de reacción. Para los análisis se utilizaron microscopía electrónica de barrido (MEB), espectroscopia de fluorescencia de rayos X de dispersión de energía (EDS), difracción de rayos X (DRX), espectrometría de masas de plasma acoplado inductivamente (ICP) y calorimetría diferencial de barrido (DSC). Los resultados indicaron la eliminación de aluminio de las películas de polietileno de los residuos de Poly-Al con buena eficiencia y sin comprometer significativamente las propiedades térmicas del polímero.A complexidade da estrutura das embalagens cartonadas é um dos fatores que impedem o desenvolvimento de processos de reciclagem após o consumo. Os processos utilizados atualmente não conseguem reciclar completamente todos os materiais utilizados nestas embalagens. Os poucos processos economicamente viáveis são aplicados para reciclagem das camadas de papel, deixando como resíduo as camadas combinadas de polietileno e alumínio, conhecidas como resíduos de polímero-alumínio (Poli-Al) das embalagens cartonadas. Nesse contexto, um método de reciclagem para polietileno e alumínio, presente nos resíduos de Poli-Al de embalagens cartonadas pós-consumo, foi pesquisado e desenvolvido utilizando o processo de digestão alcalina de alumínio. Soluções com diferentes concentrações de NaOH foram avaliadas em temperatura ambiente com tempo de tratamento de 24 h. Após os processos de remoção do alumínio, analisou-se os filmes de polietileno e as fases líquida e sólida precipitadas do meio reacional. Microscopia eletrônica de varredura (MEV/FEG), espectroscopia de energia de fluorescência de raios-X dispersiva (EDS), difração de raios-X (DRX), espectrometria de massa com plasma indutivamente acoplado (ICP) e varredura diferencial de calorimetria (DSC) foram usados para as análises. Os resultados indicaram a remoção do alumínio dos filmes de polietileno dos resíduos de Poli-Al com boa eficiência e sem comprometer significativamente as propriedades térmicas do polímero.Research, Society and Development2021-10-10info:eu-repo/semantics/articleinfo:eu-repo/semantics/publishedVersionapplication/pdfhttps://rsdjournal.org/index.php/rsd/article/view/2059210.33448/rsd-v10i13.20592Research, Society and Development; Vol. 10 No. 13; e240101320592Research, Society and Development; Vol. 10 Núm. 13; e240101320592Research, Society and Development; v. 10 n. 13; e2401013205922525-3409reponame:Research, Society and Developmentinstname:Universidade Federal de Itajubá (UNIFEI)instacron:UNIFEIporhttps://rsdjournal.org/index.php/rsd/article/view/20592/18865Copyright (c) 2021 Hellen Cristina Pauletti; Paulo Vicari; Marília Gabriela Klauck; Pahola Patussi; Letícia Bavaresco Cima; Gustavo Lopes Colpani; Luciano Luiz Silva; Micheli Zanetti; Josiane Maria Muneron de Mello; Márcio Antônio Fiorihttps://creativecommons.org/licenses/by/4.0info:eu-repo/semantics/openAccessPauletti, Hellen Cristina Vicari, PauloKlauck, Marília Gabriela Patussi, Pahola Cima, Letícia Bavaresco Colpani, Gustavo Lopes Silva, Luciano Luiz Zanetti, Micheli Mello, Josiane Maria Muneron de Fiori, Márcio Antônio 2021-11-21T18:26:28Zoai:ojs.pkp.sfu.ca:article/20592Revistahttps://rsdjournal.org/index.php/rsd/indexPUBhttps://rsdjournal.org/index.php/rsd/oairsd.articles@gmail.com2525-34092525-3409opendoar:2024-01-17T09:40:11.752305Research, Society and Development - Universidade Federal de Itajubá (UNIFEI)false |
dc.title.none.fl_str_mv |
Study of the residual polymer-aluminum recycling process of carton packaging Estudio del processo de reciclaje de residuos de polímero-aluminio de envases de carton Estudo do processo de reciclagem de polímero-alumínio residual de embalagens cartonadas |
title |
Study of the residual polymer-aluminum recycling process of carton packaging |
spellingShingle |
Study of the residual polymer-aluminum recycling process of carton packaging Pauletti, Hellen Cristina Carton packaging Recycling Polymer-Aluminum. Envases de cartón Reciclaje Polímero-Aluminio. Embalagem cartonada Reciclagem Polímero-Alumínio. |
title_short |
Study of the residual polymer-aluminum recycling process of carton packaging |
title_full |
Study of the residual polymer-aluminum recycling process of carton packaging |
title_fullStr |
Study of the residual polymer-aluminum recycling process of carton packaging |
title_full_unstemmed |
Study of the residual polymer-aluminum recycling process of carton packaging |
title_sort |
Study of the residual polymer-aluminum recycling process of carton packaging |
author |
Pauletti, Hellen Cristina |
author_facet |
Pauletti, Hellen Cristina Vicari, Paulo Klauck, Marília Gabriela Patussi, Pahola Cima, Letícia Bavaresco Colpani, Gustavo Lopes Silva, Luciano Luiz Zanetti, Micheli Mello, Josiane Maria Muneron de Fiori, Márcio Antônio |
author_role |
author |
author2 |
Vicari, Paulo Klauck, Marília Gabriela Patussi, Pahola Cima, Letícia Bavaresco Colpani, Gustavo Lopes Silva, Luciano Luiz Zanetti, Micheli Mello, Josiane Maria Muneron de Fiori, Márcio Antônio |
author2_role |
author author author author author author author author author |
dc.contributor.author.fl_str_mv |
Pauletti, Hellen Cristina Vicari, Paulo Klauck, Marília Gabriela Patussi, Pahola Cima, Letícia Bavaresco Colpani, Gustavo Lopes Silva, Luciano Luiz Zanetti, Micheli Mello, Josiane Maria Muneron de Fiori, Márcio Antônio |
dc.subject.por.fl_str_mv |
Carton packaging Recycling Polymer-Aluminum. Envases de cartón Reciclaje Polímero-Aluminio. Embalagem cartonada Reciclagem Polímero-Alumínio. |
topic |
Carton packaging Recycling Polymer-Aluminum. Envases de cartón Reciclaje Polímero-Aluminio. Embalagem cartonada Reciclagem Polímero-Alumínio. |
description |
The complexity of the structure of carton packs is one of the factors that hinder the development of processes for recycling after consumption. The few processes that are currently used do not manage to completely recycle all the materials used in these packages. The few economically viable processes are applied to the recycling of paper layers, leaving as a residue the combined layers of polyethylene and aluminum, known as polymer-aluminum residues (Poly-Al) from carton packs. In this context, a method for recycling polyethylene and aluminum present in Poly-Al residues from post-consumer carton packs was researched and developed using the alkaline aluminum digestion process. Solutions with different concentrations of NaOH were evaluated at an ambient temperature with a treatment time of 24 h. After the aluminum removal processes, the polyethylene films and the liquid and solid phases precipitated from the reaction medium were analyzed. Scanning electron microscopy (SEM/FEG), dispersive x-ray fluorescence energy spectroscopy (EDS), x-ray diffraction (XRD), inductively coupled plasma mass spectrometry (ICP) and calorimetry differential scanning (DSC) were used for the analyzes. The results indicated the removal of aluminum from polyethylene films from Poly-Al residues with good efficiency and without significantly compromising the thermal properties of the polymer. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-10-10 |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
https://rsdjournal.org/index.php/rsd/article/view/20592 10.33448/rsd-v10i13.20592 |
url |
https://rsdjournal.org/index.php/rsd/article/view/20592 |
identifier_str_mv |
10.33448/rsd-v10i13.20592 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
https://rsdjournal.org/index.php/rsd/article/view/20592/18865 |
dc.rights.driver.fl_str_mv |
https://creativecommons.org/licenses/by/4.0 info:eu-repo/semantics/openAccess |
rights_invalid_str_mv |
https://creativecommons.org/licenses/by/4.0 |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
application/pdf |
dc.publisher.none.fl_str_mv |
Research, Society and Development |
publisher.none.fl_str_mv |
Research, Society and Development |
dc.source.none.fl_str_mv |
Research, Society and Development; Vol. 10 No. 13; e240101320592 Research, Society and Development; Vol. 10 Núm. 13; e240101320592 Research, Society and Development; v. 10 n. 13; e240101320592 2525-3409 reponame:Research, Society and Development instname:Universidade Federal de Itajubá (UNIFEI) instacron:UNIFEI |
instname_str |
Universidade Federal de Itajubá (UNIFEI) |
instacron_str |
UNIFEI |
institution |
UNIFEI |
reponame_str |
Research, Society and Development |
collection |
Research, Society and Development |
repository.name.fl_str_mv |
Research, Society and Development - Universidade Federal de Itajubá (UNIFEI) |
repository.mail.fl_str_mv |
rsd.articles@gmail.com |
_version_ |
1797052755949387776 |