Uso da Pistia stratiotes como fitorremediadora de recursos hídricos contaminados por clomazone
Autor(a) principal: | |
---|---|
Data de Publicação: | 2017 |
Tipo de documento: | Dissertação |
Idioma: | por |
Título da fonte: | Repositório Institucional da UNIPAMPA |
Texto Completo: | http://dspace.unipampa.edu.br:8080/jspui/handle/riu/1552 |
Resumo: | With the growth of world population and the advent of industrialization, the demand for abundant and profitable food production worldwide is increasing. There is then a need for strategies that minimize loss and changes in food products, especially those that are grown for long periods of time like grains and vegetables. In this bias arise the pesticides, marketed since the nineteenth century, increasingly specialized and chemically modified to achieve greater efficiency in pest elimination and a shorter period of time. When pesticides are used correctly, they minimize grain losses by over 40%, but when used improperly or above the recommended dosage, they can lead to environmental and public health impacts. In this context, Clomazone (2 - (2-chlorobenzyl) -4,4-dimethyl-1,2-oxazolidin-3-one), active principle of the commercial herbicide Gamit®, of the Isoxazolidinone family and belonging to toxicological class III is Of broad spectrum used for the control of annual grasses and broadleaf weeds in cotton, peas, squash, soybeans, sweet potatoes, tobacco, wheat and rice. However, this herbicide has a series of physico-chemical characteristics and distinct behavior depending on the environment where it is inserted which can cause the increase of its permanence in the environment and contamination of organisms that are not its origin targets. An alternative to reduce the environmental impact caused by herbicides is phytoremediation. Phytoremediation consists of a technique of removal and / or pollutants from environments using plants as environmental remediation agents. This study aimed to evaluate the ability of the Pistia Stratiotes plant species in phytoremediation of the herbicide clomazone in its commercial form of water resources. The assay lasted 24 days and counted on two herbicidal concentrations that were determined from the one hundred fold multiplication of the dose recommended for use in crops, setting up an acute exposure to the herbicide. The clomazone degradation kinetics analyzes were performed by analytical methods by high performance liquid chromatography coupled to a detector with CLAE-DAD diode array. After 24 days of experiment, it was possible to identify that the plant species was able to reduce the presence of the herbicide clomazone in water by 90% and also that despite the water exposure to P. stratiotes does not undergo morphological changes due to sensitivity to the compound. Thus, the results indicate that Pistia Straiotes is capable of phytoremediation of the herbicide clomazone of water resources. |
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Denardin, Elton Luis GasparottoRoehrs, RafaelEscoto, Dandara Fidélis2017-06-05T13:54:50Z2017-06-05T13:54:50Z2017-03-20With the growth of world population and the advent of industrialization, the demand for abundant and profitable food production worldwide is increasing. There is then a need for strategies that minimize loss and changes in food products, especially those that are grown for long periods of time like grains and vegetables. In this bias arise the pesticides, marketed since the nineteenth century, increasingly specialized and chemically modified to achieve greater efficiency in pest elimination and a shorter period of time. When pesticides are used correctly, they minimize grain losses by over 40%, but when used improperly or above the recommended dosage, they can lead to environmental and public health impacts. In this context, Clomazone (2 - (2-chlorobenzyl) -4,4-dimethyl-1,2-oxazolidin-3-one), active principle of the commercial herbicide Gamit®, of the Isoxazolidinone family and belonging to toxicological class III is Of broad spectrum used for the control of annual grasses and broadleaf weeds in cotton, peas, squash, soybeans, sweet potatoes, tobacco, wheat and rice. However, this herbicide has a series of physico-chemical characteristics and distinct behavior depending on the environment where it is inserted which can cause the increase of its permanence in the environment and contamination of organisms that are not its origin targets. An alternative to reduce the environmental impact caused by herbicides is phytoremediation. Phytoremediation consists of a technique of removal and / or pollutants from environments using plants as environmental remediation agents. This study aimed to evaluate the ability of the Pistia Stratiotes plant species in phytoremediation of the herbicide clomazone in its commercial form of water resources. The assay lasted 24 days and counted on two herbicidal concentrations that were determined from the one hundred fold multiplication of the dose recommended for use in crops, setting up an acute exposure to the herbicide. The clomazone degradation kinetics analyzes were performed by analytical methods by high performance liquid chromatography coupled to a detector with CLAE-DAD diode array. After 24 days of experiment, it was possible to identify that the plant species was able to reduce the presence of the herbicide clomazone in water by 90% and also that despite the water exposure to P. stratiotes does not undergo morphological changes due to sensitivity to the compound. Thus, the results indicate that Pistia Straiotes is capable of phytoremediation of the herbicide clomazone of water resources.Com o crescimento da população mundial e o advento da industrialização cada vez mais aumenta a demanda pela produção abundante e rentável de alimentos pelo mundo todo. Existe então a necessidade de estratégias que minimizem a perda e as alterações nos produtos alimentares, sobretudo os que são cultivados por longos períodos de tempo como grãos e hortaliças. Neste viés surgem os pesticidas, comercializados desde o século XIX, cada vez mais especializados e modificados quimicamente para atingir uma maior eficiência na eliminação de pragas e um menor período de tempo. Quando os pesticidas são usados corretamente, eles minimizam acima de 40% as perdas de grãos, mas quando usados de maneira incorreta ou acima da dosagem recomendada, podem conduzir a impactos no ambiente e na saúde pública. Neste contexto, o Clomazone (2 - (2-clorobenzil) -4,4-dimetil-1,2-oxazolidin-3-ona), princípio ativo do herbicida comercial Gamit®, da família das Isoxazolidinona e pertencente a classe toxicológica III é de amplo espectro usado para o controle de gramíneas anuais e plantas daninhas de folha larga em algodão, ervilhas, abóbora, soja, batata-doce, tabaco, trigo e arroz. Porém, este herbicida possui uma série de características físico-químicas e comportamento distinto dependentemente do ambiente onde for inserido o que pode causar o aumento de sua permanência no ambiente e contaminação de organismos que não são os seus alvos de origem. Uma alternativa para reduzir o impacto ambiental causado pelos herbicidas é a fitorremediação. A fitorremediação consiste em uma técnica de remoção e/ou de poluentes dos ambientes utilizando plantas como agentes de remediação ambiental. Este estudo teve como objetivo avaliar a capacidade a espécie vegetal Pistia stratiotes em fitorremediar o herbicida clomazone em sua forma comercial de recursos hídricos. O ensaio teve a duração de 24 dias e contou com duas concentrações o herbicida que foram determinadas a partir da multiplicação em cem vezes da dose recomendada para uso em lavouras, configurando uma exposição aguda ao herbicida. As análises da cinética de degradação do clomazone foram realizadas através de métodos analíticos por cromatográfica líquida de alta eficiência acoplada a detector com arranjo de diodos CLAE-DAD. Após os 24 dias de experimento foi possível identificar que a espécie vegetal foi capaz de reduzir em 90% a presença do herbicida clomazone na água e também que apesar da exposição agua a P. Stratiotes não sofre alterações morfológicas em decorrência de sensibilidade ao composto. Dessa maneira, os resultados indicam que a Pistia Straiotes é capaz de fitorremediar o herbicida clomazone de recursos hídricos.porUniversidade Federal do PampaCampus UruguaianaAttribution-NonCommercial-NoDerivs 3.0 Brazilhttp://creativecommons.org/licenses/by-nc-nd/3.0/br/info:eu-repo/semantics/openAccessCNPQ::CIENCIAS BIOLOGICASBioquímicaFitorremediaçãoClomazonePistia SaiotesGAMITPhytoremediationClomazonePistia SaiotesUso da Pistia stratiotes como fitorremediadora de recursos hídricos contaminados por clomazoneinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesisapplication/pdfreponame:Repositório Institucional da UNIPAMPAinstname:Universidade Federal do Pampa (UNIPAMPA)instacron:UNIPAMPAhttp://dspace.unipampa.edu.br:8080/jspui/handle/riu/1552Use of Pistia stratiotes as a phytoremediate of water resources contaminated by clomazoneORIGINALDANDARA FIDÉLIS ESCOTO.pdfDANDARA FIDÉLIS ESCOTO.pdfapplication/pdf2090171https://repositorio.unipampa.edu.br/jspui/bitstream/riu/1552/1/DANDARA%20FID%c3%89LIS%20ESCOTO.pdf1c4b35661ab0654fc646af3838138cf9MD51CC-LICENSElicense_rdflicense_rdfapplication/rdf+xml; charset=utf-81232https://repositorio.unipampa.edu.br/jspui/bitstream/riu/1552/2/license_rdf66e71c371cc565284e70f40736c94386MD52LICENSElicense.txtlicense.txttext/plain; charset=utf-81748https://repositorio.unipampa.edu.br/jspui/bitstream/riu/1552/3/license.txt8a4605be74aa9ea9d79846c1fba20a33MD53TEXTDANDARA FIDÉLIS ESCOTO.pdf.txtDANDARA FIDÉLIS ESCOTO.pdf.txtExtracted texttext/plain96922https://repositorio.unipampa.edu.br/jspui/bitstream/riu/1552/4/DANDARA%20FID%c3%89LIS%20ESCOTO.pdf.txt56f2a133067a170d32aacd25637baaaeMD54riu/15522018-11-29 14:34:00.835oai:repositorio.unipampa.edu.br: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Repositório InstitucionalPUBhttp://dspace.unipampa.edu.br:8080/oai/requestsisbi@unipampa.edu.bropendoar:2018-11-29T16:34Repositório Institucional da UNIPAMPA - Universidade Federal do Pampa (UNIPAMPA)false |
dc.title.pt_BR.fl_str_mv |
Uso da Pistia stratiotes como fitorremediadora de recursos hídricos contaminados por clomazone |
title |
Uso da Pistia stratiotes como fitorremediadora de recursos hídricos contaminados por clomazone |
spellingShingle |
Uso da Pistia stratiotes como fitorremediadora de recursos hídricos contaminados por clomazone Escoto, Dandara Fidélis CNPQ::CIENCIAS BIOLOGICAS GAMIT Phytoremediation Clomazone Pistia Saiotes Bioquímica Fitorremediação Clomazone Pistia Saiotes |
title_short |
Uso da Pistia stratiotes como fitorremediadora de recursos hídricos contaminados por clomazone |
title_full |
Uso da Pistia stratiotes como fitorremediadora de recursos hídricos contaminados por clomazone |
title_fullStr |
Uso da Pistia stratiotes como fitorremediadora de recursos hídricos contaminados por clomazone |
title_full_unstemmed |
Uso da Pistia stratiotes como fitorremediadora de recursos hídricos contaminados por clomazone |
title_sort |
Uso da Pistia stratiotes como fitorremediadora de recursos hídricos contaminados por clomazone |
author |
Escoto, Dandara Fidélis |
author_facet |
Escoto, Dandara Fidélis |
author_role |
author |
dc.contributor.co-advisor.none.fl_str_mv |
Roehrs, Rafael |
dc.contributor.advisor1.fl_str_mv |
Denardin, Elton Luis Gasparotto |
dc.contributor.author.fl_str_mv |
Escoto, Dandara Fidélis |
contributor_str_mv |
Denardin, Elton Luis Gasparotto |
dc.subject.cnpq.fl_str_mv |
CNPQ::CIENCIAS BIOLOGICAS |
topic |
CNPQ::CIENCIAS BIOLOGICAS GAMIT Phytoremediation Clomazone Pistia Saiotes Bioquímica Fitorremediação Clomazone Pistia Saiotes |
dc.subject.por.fl_str_mv |
GAMIT |
dc.subject.eng.fl_str_mv |
Phytoremediation Clomazone Pistia Saiotes |
dc.subject.keyword.pt_BR.fl_str_mv |
Bioquímica Fitorremediação Clomazone Pistia Saiotes |
description |
With the growth of world population and the advent of industrialization, the demand for abundant and profitable food production worldwide is increasing. There is then a need for strategies that minimize loss and changes in food products, especially those that are grown for long periods of time like grains and vegetables. In this bias arise the pesticides, marketed since the nineteenth century, increasingly specialized and chemically modified to achieve greater efficiency in pest elimination and a shorter period of time. When pesticides are used correctly, they minimize grain losses by over 40%, but when used improperly or above the recommended dosage, they can lead to environmental and public health impacts. In this context, Clomazone (2 - (2-chlorobenzyl) -4,4-dimethyl-1,2-oxazolidin-3-one), active principle of the commercial herbicide Gamit®, of the Isoxazolidinone family and belonging to toxicological class III is Of broad spectrum used for the control of annual grasses and broadleaf weeds in cotton, peas, squash, soybeans, sweet potatoes, tobacco, wheat and rice. However, this herbicide has a series of physico-chemical characteristics and distinct behavior depending on the environment where it is inserted which can cause the increase of its permanence in the environment and contamination of organisms that are not its origin targets. An alternative to reduce the environmental impact caused by herbicides is phytoremediation. Phytoremediation consists of a technique of removal and / or pollutants from environments using plants as environmental remediation agents. This study aimed to evaluate the ability of the Pistia Stratiotes plant species in phytoremediation of the herbicide clomazone in its commercial form of water resources. The assay lasted 24 days and counted on two herbicidal concentrations that were determined from the one hundred fold multiplication of the dose recommended for use in crops, setting up an acute exposure to the herbicide. The clomazone degradation kinetics analyzes were performed by analytical methods by high performance liquid chromatography coupled to a detector with CLAE-DAD diode array. After 24 days of experiment, it was possible to identify that the plant species was able to reduce the presence of the herbicide clomazone in water by 90% and also that despite the water exposure to P. stratiotes does not undergo morphological changes due to sensitivity to the compound. Thus, the results indicate that Pistia Straiotes is capable of phytoremediation of the herbicide clomazone of water resources. |
publishDate |
2017 |
dc.date.accessioned.fl_str_mv |
2017-06-05T13:54:50Z |
dc.date.available.fl_str_mv |
2017-06-05T13:54:50Z |
dc.date.issued.fl_str_mv |
2017-03-20 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/masterThesis |
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masterThesis |
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publishedVersion |
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http://dspace.unipampa.edu.br:8080/jspui/handle/riu/1552 |
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http://dspace.unipampa.edu.br:8080/jspui/handle/riu/1552 |
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por |
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Attribution-NonCommercial-NoDerivs 3.0 Brazil http://creativecommons.org/licenses/by-nc-nd/3.0/br/ info:eu-repo/semantics/openAccess |
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Attribution-NonCommercial-NoDerivs 3.0 Brazil http://creativecommons.org/licenses/by-nc-nd/3.0/br/ |
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openAccess |
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Universidade Federal do Pampa |
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Campus Uruguaiana |
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Universidade Federal do Pampa |
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