Correlating pH and Swelling Degree Parameters to Understand the Sorption and Desorption Process of Diquat Herbicide from Nanocomposites Based on Polysaccharide and Clinoptilolite
Autor(a) principal: | |
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Data de Publicação: | 2021 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1007/s10924-021-02126-1 http://hdl.handle.net/11449/207521 |
Resumo: | Zeolite-based nanocomposites have become an efficient option for application in herbicide removal and controlled release systems. Our group previously described the degree of swelling in water and salt solutions, spectroscopic and structural properties, and fertilizer desorption from carboxymethylcellulose-poly(methacrylic acid-co-acrylamide)-zeolite nanocomposites. Here, morphological and thermal properties, and swelling degree studies at different pH was investigated in these same nanocomposites. Their water-uptake in these various swelling media was correlated with sorption and desorption profiles of diquat. SEM-EDX technique indicated the presence of zeolite in the nanocomposites, as well as the increase in the quantity of water hydration molecules trapped in the zeolite cavities was confirmed by DSC. Improved diquat sorption from 8.3 to 9.4 mg/g was recorded when 1.5% zeolite was added into nanocomposites, indicating a significant increase in herbicide–matrix interaction. This increase also led to a small decrease in the desorption process, but in a more controlled manner. Variation of pH of the swelling media might have changed the elasticity of nanocomposite chains, which in turn adjusted release rate. A better understanding of nanocomposite–herbicide interaction can help design novel matrices with enhanced pesticide sorption, contributing to reduce contaminations caused by the indiscriminate use of agrochemicals. |
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Correlating pH and Swelling Degree Parameters to Understand the Sorption and Desorption Process of Diquat Herbicide from Nanocomposites Based on Polysaccharide and ClinoptiloliteHydrogelsNanocompositesPolysaccharidesUV–Vis spectroscopyZeolitesZeolite-based nanocomposites have become an efficient option for application in herbicide removal and controlled release systems. Our group previously described the degree of swelling in water and salt solutions, spectroscopic and structural properties, and fertilizer desorption from carboxymethylcellulose-poly(methacrylic acid-co-acrylamide)-zeolite nanocomposites. Here, morphological and thermal properties, and swelling degree studies at different pH was investigated in these same nanocomposites. Their water-uptake in these various swelling media was correlated with sorption and desorption profiles of diquat. SEM-EDX technique indicated the presence of zeolite in the nanocomposites, as well as the increase in the quantity of water hydration molecules trapped in the zeolite cavities was confirmed by DSC. Improved diquat sorption from 8.3 to 9.4 mg/g was recorded when 1.5% zeolite was added into nanocomposites, indicating a significant increase in herbicide–matrix interaction. This increase also led to a small decrease in the desorption process, but in a more controlled manner. Variation of pH of the swelling media might have changed the elasticity of nanocomposite chains, which in turn adjusted release rate. A better understanding of nanocomposite–herbicide interaction can help design novel matrices with enhanced pesticide sorption, contributing to reduce contaminations caused by the indiscriminate use of agrochemicals.Grupo de Compósitos e Nanocompósitos Híbridos (GCNH) Department of Physics and Chemistry Ilha Solteira School of Engineering São Paulo State University (UNESP)Grupo de Compósitos e Nanocompósitos Híbridos (GCNH) Department of Physics and Chemistry Ilha Solteira School of Engineering São Paulo State University (UNESP)Universidade Estadual Paulista (Unesp)Tanaka, Fabrício C. [UNESP]Junior, Carlos. R. F. [UNESP]Fernandes, Renan. S. [UNESP]de Moura, Marcia R. [UNESP]Aouada, Fauze A. [UNESP]2021-06-25T10:56:36Z2021-06-25T10:56:36Z2021-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://dx.doi.org/10.1007/s10924-021-02126-1Journal of Polymers and the Environment.1572-89191566-2543http://hdl.handle.net/11449/20752110.1007/s10924-021-02126-12-s2.0-85103175202Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of Polymers and the Environmentinfo:eu-repo/semantics/openAccess2024-07-10T14:07:13Zoai:repositorio.unesp.br:11449/207521Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T14:27:39.423475Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Correlating pH and Swelling Degree Parameters to Understand the Sorption and Desorption Process of Diquat Herbicide from Nanocomposites Based on Polysaccharide and Clinoptilolite |
title |
Correlating pH and Swelling Degree Parameters to Understand the Sorption and Desorption Process of Diquat Herbicide from Nanocomposites Based on Polysaccharide and Clinoptilolite |
spellingShingle |
Correlating pH and Swelling Degree Parameters to Understand the Sorption and Desorption Process of Diquat Herbicide from Nanocomposites Based on Polysaccharide and Clinoptilolite Tanaka, Fabrício C. [UNESP] Hydrogels Nanocomposites Polysaccharides UV–Vis spectroscopy Zeolites |
title_short |
Correlating pH and Swelling Degree Parameters to Understand the Sorption and Desorption Process of Diquat Herbicide from Nanocomposites Based on Polysaccharide and Clinoptilolite |
title_full |
Correlating pH and Swelling Degree Parameters to Understand the Sorption and Desorption Process of Diquat Herbicide from Nanocomposites Based on Polysaccharide and Clinoptilolite |
title_fullStr |
Correlating pH and Swelling Degree Parameters to Understand the Sorption and Desorption Process of Diquat Herbicide from Nanocomposites Based on Polysaccharide and Clinoptilolite |
title_full_unstemmed |
Correlating pH and Swelling Degree Parameters to Understand the Sorption and Desorption Process of Diquat Herbicide from Nanocomposites Based on Polysaccharide and Clinoptilolite |
title_sort |
Correlating pH and Swelling Degree Parameters to Understand the Sorption and Desorption Process of Diquat Herbicide from Nanocomposites Based on Polysaccharide and Clinoptilolite |
author |
Tanaka, Fabrício C. [UNESP] |
author_facet |
Tanaka, Fabrício C. [UNESP] Junior, Carlos. R. F. [UNESP] Fernandes, Renan. S. [UNESP] de Moura, Marcia R. [UNESP] Aouada, Fauze A. [UNESP] |
author_role |
author |
author2 |
Junior, Carlos. R. F. [UNESP] Fernandes, Renan. S. [UNESP] de Moura, Marcia R. [UNESP] Aouada, Fauze A. [UNESP] |
author2_role |
author author author author |
dc.contributor.none.fl_str_mv |
Universidade Estadual Paulista (Unesp) |
dc.contributor.author.fl_str_mv |
Tanaka, Fabrício C. [UNESP] Junior, Carlos. R. F. [UNESP] Fernandes, Renan. S. [UNESP] de Moura, Marcia R. [UNESP] Aouada, Fauze A. [UNESP] |
dc.subject.por.fl_str_mv |
Hydrogels Nanocomposites Polysaccharides UV–Vis spectroscopy Zeolites |
topic |
Hydrogels Nanocomposites Polysaccharides UV–Vis spectroscopy Zeolites |
description |
Zeolite-based nanocomposites have become an efficient option for application in herbicide removal and controlled release systems. Our group previously described the degree of swelling in water and salt solutions, spectroscopic and structural properties, and fertilizer desorption from carboxymethylcellulose-poly(methacrylic acid-co-acrylamide)-zeolite nanocomposites. Here, morphological and thermal properties, and swelling degree studies at different pH was investigated in these same nanocomposites. Their water-uptake in these various swelling media was correlated with sorption and desorption profiles of diquat. SEM-EDX technique indicated the presence of zeolite in the nanocomposites, as well as the increase in the quantity of water hydration molecules trapped in the zeolite cavities was confirmed by DSC. Improved diquat sorption from 8.3 to 9.4 mg/g was recorded when 1.5% zeolite was added into nanocomposites, indicating a significant increase in herbicide–matrix interaction. This increase also led to a small decrease in the desorption process, but in a more controlled manner. Variation of pH of the swelling media might have changed the elasticity of nanocomposite chains, which in turn adjusted release rate. A better understanding of nanocomposite–herbicide interaction can help design novel matrices with enhanced pesticide sorption, contributing to reduce contaminations caused by the indiscriminate use of agrochemicals. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-06-25T10:56:36Z 2021-06-25T10:56:36Z 2021-01-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1007/s10924-021-02126-1 Journal of Polymers and the Environment. 1572-8919 1566-2543 http://hdl.handle.net/11449/207521 10.1007/s10924-021-02126-1 2-s2.0-85103175202 |
url |
http://dx.doi.org/10.1007/s10924-021-02126-1 http://hdl.handle.net/11449/207521 |
identifier_str_mv |
Journal of Polymers and the Environment. 1572-8919 1566-2543 10.1007/s10924-021-02126-1 2-s2.0-85103175202 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Journal of Polymers and the Environment |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
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1808128363482578944 |