Formation of copper oxide II in polymer solution-blow-spun fibers and the successful non-woven ceramic production
Autor(a) principal: | |
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Data de Publicação: | 2022 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1016/j.matchemphys.2021.125525 http://hdl.handle.net/11449/230105 |
Resumo: | Copper oxide II is a p-type semiconductor that can be used in several applications. Focusing on producing such material using an easy and low-cost technique, we followed an acetate one-pot-like route for producing a polymer precursor solution with different acetates:PVP (polyvinylpyrrolidone) weight ratios. Then, composite nanofibers were produced using the solution blow spinning (SBS) technique. The ceramic CuO samples were obtained after a calcination process at 600 °C for 2 h, applying a heating rate of 0.5 °C/min. Non-woven fabric-like ceramic samples with average diameters lower than 300 nm were successfully obtained. SEM images show relatively smooth fibers with a granular morphology. XRD shows the formation of randomly oriented grains of CuO. In addition, FTIR and XRD analyses show the CuO formation before the heat treatment. Thus, a chemical reaction sequence was proposed to explain the results. |
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Formation of copper oxide II in polymer solution-blow-spun fibers and the successful non-woven ceramic productionCopper oxideNanofibersNanowiresSolution blow spinningCopper oxide II is a p-type semiconductor that can be used in several applications. Focusing on producing such material using an easy and low-cost technique, we followed an acetate one-pot-like route for producing a polymer precursor solution with different acetates:PVP (polyvinylpyrrolidone) weight ratios. Then, composite nanofibers were produced using the solution blow spinning (SBS) technique. The ceramic CuO samples were obtained after a calcination process at 600 °C for 2 h, applying a heating rate of 0.5 °C/min. Non-woven fabric-like ceramic samples with average diameters lower than 300 nm were successfully obtained. SEM images show relatively smooth fibers with a granular morphology. XRD shows the formation of randomly oriented grains of CuO. In addition, FTIR and XRD analyses show the CuO formation before the heat treatment. Thus, a chemical reaction sequence was proposed to explain the results.Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Universidade Estadual Paulista (UNESP) Faculdade de Engenharia de Ilha Solteira Departamento de Física e QuímicaUniversidade Estadual Paulista (UNESP) Faculdade de Engenharia de Ilha Solteira Departamento de Física e QuímicaFAPESP: 2016/12390-6FAPESP: 2019/06170-1CNPq: 302564/2018-7CNPq: 312530/2018-8Universidade Estadual Paulista (UNESP)Bitencourt da Silva, Alex Nascimento [UNESP]de Moura, Marcia Regina [UNESP]Zadorosny, Rafael [UNESP]2022-04-29T08:37:58Z2022-04-29T08:37:58Z2022-02-15info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://dx.doi.org/10.1016/j.matchemphys.2021.125525Materials Chemistry and Physics, v. 278.0254-0584http://hdl.handle.net/11449/23010510.1016/j.matchemphys.2021.1255252-s2.0-85121624396Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengMaterials Chemistry and Physicsinfo:eu-repo/semantics/openAccess2022-04-29T08:37:58Zoai:repositorio.unesp.br:11449/230105Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462022-04-29T08:37:58Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Formation of copper oxide II in polymer solution-blow-spun fibers and the successful non-woven ceramic production |
title |
Formation of copper oxide II in polymer solution-blow-spun fibers and the successful non-woven ceramic production |
spellingShingle |
Formation of copper oxide II in polymer solution-blow-spun fibers and the successful non-woven ceramic production Bitencourt da Silva, Alex Nascimento [UNESP] Copper oxide Nanofibers Nanowires Solution blow spinning |
title_short |
Formation of copper oxide II in polymer solution-blow-spun fibers and the successful non-woven ceramic production |
title_full |
Formation of copper oxide II in polymer solution-blow-spun fibers and the successful non-woven ceramic production |
title_fullStr |
Formation of copper oxide II in polymer solution-blow-spun fibers and the successful non-woven ceramic production |
title_full_unstemmed |
Formation of copper oxide II in polymer solution-blow-spun fibers and the successful non-woven ceramic production |
title_sort |
Formation of copper oxide II in polymer solution-blow-spun fibers and the successful non-woven ceramic production |
author |
Bitencourt da Silva, Alex Nascimento [UNESP] |
author_facet |
Bitencourt da Silva, Alex Nascimento [UNESP] de Moura, Marcia Regina [UNESP] Zadorosny, Rafael [UNESP] |
author_role |
author |
author2 |
de Moura, Marcia Regina [UNESP] Zadorosny, Rafael [UNESP] |
author2_role |
author author |
dc.contributor.none.fl_str_mv |
Universidade Estadual Paulista (UNESP) |
dc.contributor.author.fl_str_mv |
Bitencourt da Silva, Alex Nascimento [UNESP] de Moura, Marcia Regina [UNESP] Zadorosny, Rafael [UNESP] |
dc.subject.por.fl_str_mv |
Copper oxide Nanofibers Nanowires Solution blow spinning |
topic |
Copper oxide Nanofibers Nanowires Solution blow spinning |
description |
Copper oxide II is a p-type semiconductor that can be used in several applications. Focusing on producing such material using an easy and low-cost technique, we followed an acetate one-pot-like route for producing a polymer precursor solution with different acetates:PVP (polyvinylpyrrolidone) weight ratios. Then, composite nanofibers were produced using the solution blow spinning (SBS) technique. The ceramic CuO samples were obtained after a calcination process at 600 °C for 2 h, applying a heating rate of 0.5 °C/min. Non-woven fabric-like ceramic samples with average diameters lower than 300 nm were successfully obtained. SEM images show relatively smooth fibers with a granular morphology. XRD shows the formation of randomly oriented grains of CuO. In addition, FTIR and XRD analyses show the CuO formation before the heat treatment. Thus, a chemical reaction sequence was proposed to explain the results. |
publishDate |
2022 |
dc.date.none.fl_str_mv |
2022-04-29T08:37:58Z 2022-04-29T08:37:58Z 2022-02-15 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1016/j.matchemphys.2021.125525 Materials Chemistry and Physics, v. 278. 0254-0584 http://hdl.handle.net/11449/230105 10.1016/j.matchemphys.2021.125525 2-s2.0-85121624396 |
url |
http://dx.doi.org/10.1016/j.matchemphys.2021.125525 http://hdl.handle.net/11449/230105 |
identifier_str_mv |
Materials Chemistry and Physics, v. 278. 0254-0584 10.1016/j.matchemphys.2021.125525 2-s2.0-85121624396 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Materials Chemistry and Physics |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1797789242520240128 |