Effect of a Polymeric Protective Coating on Optical and Electrical Properties of Poly(p-phenylene vinylene) Derivatives
Autor(a) principal: | |
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Data de Publicação: | 2013 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1155/2013/160464 http://hdl.handle.net/11449/111533 |
Resumo: | The resistance to photodegradation of poly[(2-methoxy-5-n-hexyloxy)-p-phenylene vinylene] (OC1OC6-PPV) films was significantly enhanced by the use of poly(vinyl alcohol) 99% hydrolyzed as protective coating. The deposition of poly(vinyl alcohol) onto OC1OC6-PPV films did not affect the absorption and the emission spectra of the luminescent polymer. The protected film showed 5% drop on the absorbance at 500 nm after 270 hours of light exposure while the unprotected film completely degraded in the same conditions. The conductivity of the protected film remained stable (around 7 x 10(-10) S/m) while the value for the unprotected one dropped around two orders of magnitude after 100 hours of light exposure. |
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Repositório Institucional da UNESP |
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spelling |
Effect of a Polymeric Protective Coating on Optical and Electrical Properties of Poly(p-phenylene vinylene) DerivativesThe resistance to photodegradation of poly[(2-methoxy-5-n-hexyloxy)-p-phenylene vinylene] (OC1OC6-PPV) films was significantly enhanced by the use of poly(vinyl alcohol) 99% hydrolyzed as protective coating. The deposition of poly(vinyl alcohol) onto OC1OC6-PPV films did not affect the absorption and the emission spectra of the luminescent polymer. The protected film showed 5% drop on the absorbance at 500 nm after 270 hours of light exposure while the unprotected film completely degraded in the same conditions. The conductivity of the protected film remained stable (around 7 x 10(-10) S/m) while the value for the unprotected one dropped around two orders of magnitude after 100 hours of light exposure.Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)Instituto Nacional de Eletronica Organica, BrazilUniv Sao Paulo, IFSC, BR-13566590 Sao Carlos, SP, BrazilUnesp Presidente Prudente, FCT, BR-19060900 Presidente Prudente, SP, BrazilUniv Sao Paulo, EESC, Dept Engn Mat, BR-13566590 Sao Carlos, SP, BrazilUnesp Presidente Prudente, FCT, BR-19060900 Presidente Prudente, SP, BrazilHindawi Publishing CorporationUniversidade de São Paulo (USP)Universidade Estadual Paulista (Unesp)Goncalves, V. C.Olivati, C. A. [UNESP]Carvalho, A. J. F.Balogh, D. T.2014-12-03T13:08:44Z2014-12-03T13:08:44Z2013-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article5application/pdfhttp://dx.doi.org/10.1155/2013/160464Journal Of Nanomaterials. New York: Hindawi Publishing Corporation, 5 p., 2013.1687-4110http://hdl.handle.net/11449/11153310.1155/2013/160464WOS:000327306600001WOS000327306600001.pdf98222128086514150000-0002-0114-6795Web of Sciencereponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of Nanomaterials2.2070,360info:eu-repo/semantics/openAccess2024-06-19T12:44:41Zoai:repositorio.unesp.br:11449/111533Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T20:58:28.689368Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Effect of a Polymeric Protective Coating on Optical and Electrical Properties of Poly(p-phenylene vinylene) Derivatives |
title |
Effect of a Polymeric Protective Coating on Optical and Electrical Properties of Poly(p-phenylene vinylene) Derivatives |
spellingShingle |
Effect of a Polymeric Protective Coating on Optical and Electrical Properties of Poly(p-phenylene vinylene) Derivatives Goncalves, V. C. |
title_short |
Effect of a Polymeric Protective Coating on Optical and Electrical Properties of Poly(p-phenylene vinylene) Derivatives |
title_full |
Effect of a Polymeric Protective Coating on Optical and Electrical Properties of Poly(p-phenylene vinylene) Derivatives |
title_fullStr |
Effect of a Polymeric Protective Coating on Optical and Electrical Properties of Poly(p-phenylene vinylene) Derivatives |
title_full_unstemmed |
Effect of a Polymeric Protective Coating on Optical and Electrical Properties of Poly(p-phenylene vinylene) Derivatives |
title_sort |
Effect of a Polymeric Protective Coating on Optical and Electrical Properties of Poly(p-phenylene vinylene) Derivatives |
author |
Goncalves, V. C. |
author_facet |
Goncalves, V. C. Olivati, C. A. [UNESP] Carvalho, A. J. F. Balogh, D. T. |
author_role |
author |
author2 |
Olivati, C. A. [UNESP] Carvalho, A. J. F. Balogh, D. T. |
author2_role |
author author author |
dc.contributor.none.fl_str_mv |
Universidade de São Paulo (USP) Universidade Estadual Paulista (Unesp) |
dc.contributor.author.fl_str_mv |
Goncalves, V. C. Olivati, C. A. [UNESP] Carvalho, A. J. F. Balogh, D. T. |
description |
The resistance to photodegradation of poly[(2-methoxy-5-n-hexyloxy)-p-phenylene vinylene] (OC1OC6-PPV) films was significantly enhanced by the use of poly(vinyl alcohol) 99% hydrolyzed as protective coating. The deposition of poly(vinyl alcohol) onto OC1OC6-PPV films did not affect the absorption and the emission spectra of the luminescent polymer. The protected film showed 5% drop on the absorbance at 500 nm after 270 hours of light exposure while the unprotected film completely degraded in the same conditions. The conductivity of the protected film remained stable (around 7 x 10(-10) S/m) while the value for the unprotected one dropped around two orders of magnitude after 100 hours of light exposure. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013-01-01 2014-12-03T13:08:44Z 2014-12-03T13:08:44Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1155/2013/160464 Journal Of Nanomaterials. New York: Hindawi Publishing Corporation, 5 p., 2013. 1687-4110 http://hdl.handle.net/11449/111533 10.1155/2013/160464 WOS:000327306600001 WOS000327306600001.pdf 9822212808651415 0000-0002-0114-6795 |
url |
http://dx.doi.org/10.1155/2013/160464 http://hdl.handle.net/11449/111533 |
identifier_str_mv |
Journal Of Nanomaterials. New York: Hindawi Publishing Corporation, 5 p., 2013. 1687-4110 10.1155/2013/160464 WOS:000327306600001 WOS000327306600001.pdf 9822212808651415 0000-0002-0114-6795 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Journal of Nanomaterials 2.207 0,360 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
5 application/pdf |
dc.publisher.none.fl_str_mv |
Hindawi Publishing Corporation |
publisher.none.fl_str_mv |
Hindawi Publishing Corporation |
dc.source.none.fl_str_mv |
Web of Science reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1808129269817147392 |