Layer-by-layer composite film of nickel phthalocyanine and montmorillonite clay for synergistic effect on electrochemical detection of dopamine

Detalhes bibliográficos
Autor(a) principal: Lucena, Nathalia C. de
Data de Publicação: 2018
Outros Autores: Miyazaki, Celina M., Shimizu, Flavio M., Constantino, Carlos J. L. [UNESP], Ferreira, Marystela
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1016/j.apsusc.2017.12.117
http://hdl.handle.net/11449/166019
Resumo: Dopamine (DA) abnormal levels are related to diseases which makes important the development of fast, reliable, low-cost and sensitive devices for diagnosis and pharmaceutical controls. Nanostructured film composite of sodium montmorillonite clay (Na+MMT) and nickel phthalocyanine (NiTsPc) was selfassembled by layer-by-layer (LbL) technique and applied as electrochemical sensor for DA in the presence of common natural interferents as ascorbic acid (AA) and uric acid (UA). Three different LbL architecture films were investigated: LbL films of clay (PEI/Na+MMT) and phthalocyanine (PEI/NiTsPc) in a bilayer structure with a conventional polyelectrolyte (PEI) and a composite film formed by both materials to verify the synergistic effect in the LbL film in a quadri-layer assembly (PEI/Na+MMT/PEI/NiTsPc). Structural characterization indicated molecular level interactions between the layers forming the LbL films. The ITO/(PEI/Na+MMT/PEI/NiTsPc)(10) electrode exhibited a LOD of 1.0 mu mol L-1 and linear range 5-150 mu mol L-1. (C) 2017 Elsevier B.V. All rights reserved.
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spelling Layer-by-layer composite film of nickel phthalocyanine and montmorillonite clay for synergistic effect on electrochemical detection of dopamineDopamineLayer-by-layerNickel phthalocyanineMontmorillonite clayElectrochemical sensorDopamine (DA) abnormal levels are related to diseases which makes important the development of fast, reliable, low-cost and sensitive devices for diagnosis and pharmaceutical controls. Nanostructured film composite of sodium montmorillonite clay (Na+MMT) and nickel phthalocyanine (NiTsPc) was selfassembled by layer-by-layer (LbL) technique and applied as electrochemical sensor for DA in the presence of common natural interferents as ascorbic acid (AA) and uric acid (UA). Three different LbL architecture films were investigated: LbL films of clay (PEI/Na+MMT) and phthalocyanine (PEI/NiTsPc) in a bilayer structure with a conventional polyelectrolyte (PEI) and a composite film formed by both materials to verify the synergistic effect in the LbL film in a quadri-layer assembly (PEI/Na+MMT/PEI/NiTsPc). Structural characterization indicated molecular level interactions between the layers forming the LbL films. The ITO/(PEI/Na+MMT/PEI/NiTsPc)(10) electrode exhibited a LOD of 1.0 mu mol L-1 and linear range 5-150 mu mol L-1. (C) 2017 Elsevier B.V. All rights reserved.Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Univ Fed Sao Carlos, Sorocaba, SP, BrazilUniv Sao Paulo, Sao Carlos, SP, BrazilUniv Estadual Paulista, FCT, Presidente Prudente, SP, BrazilUniv Estadual Paulista, FCT, Presidente Prudente, SP, BrazilFAPESP: 2014/15093-7FAPESP: 2015/15033-6FAPESP: 2016/19387FAPESP: 2012/15543-7FAPESP: 2013/14262-7Elsevier B.V.Universidade Federal de São Carlos (UFSCar)Universidade de São Paulo (USP)Universidade Estadual Paulista (Unesp)Lucena, Nathalia C. deMiyazaki, Celina M.Shimizu, Flavio M.Constantino, Carlos J. L. [UNESP]Ferreira, Marystela2018-11-29T08:01:21Z2018-11-29T08:01:21Z2018-04-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article957-966application/pdfhttp://dx.doi.org/10.1016/j.apsusc.2017.12.117Applied Surface Science. Amsterdam: Elsevier Science Bv, v. 436, p. 957-966, 2018.0169-4332http://hdl.handle.net/11449/16601910.1016/j.apsusc.2017.12.117WOS:000425723100113WOS000425723100113.pdfWeb of Sciencereponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengApplied Surface Scienceinfo:eu-repo/semantics/openAccess2024-06-19T12:44:22Zoai:repositorio.unesp.br:11449/166019Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T15:09:43.619632Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Layer-by-layer composite film of nickel phthalocyanine and montmorillonite clay for synergistic effect on electrochemical detection of dopamine
title Layer-by-layer composite film of nickel phthalocyanine and montmorillonite clay for synergistic effect on electrochemical detection of dopamine
spellingShingle Layer-by-layer composite film of nickel phthalocyanine and montmorillonite clay for synergistic effect on electrochemical detection of dopamine
Lucena, Nathalia C. de
Dopamine
Layer-by-layer
Nickel phthalocyanine
Montmorillonite clay
Electrochemical sensor
title_short Layer-by-layer composite film of nickel phthalocyanine and montmorillonite clay for synergistic effect on electrochemical detection of dopamine
title_full Layer-by-layer composite film of nickel phthalocyanine and montmorillonite clay for synergistic effect on electrochemical detection of dopamine
title_fullStr Layer-by-layer composite film of nickel phthalocyanine and montmorillonite clay for synergistic effect on electrochemical detection of dopamine
title_full_unstemmed Layer-by-layer composite film of nickel phthalocyanine and montmorillonite clay for synergistic effect on electrochemical detection of dopamine
title_sort Layer-by-layer composite film of nickel phthalocyanine and montmorillonite clay for synergistic effect on electrochemical detection of dopamine
author Lucena, Nathalia C. de
author_facet Lucena, Nathalia C. de
Miyazaki, Celina M.
Shimizu, Flavio M.
Constantino, Carlos J. L. [UNESP]
Ferreira, Marystela
author_role author
author2 Miyazaki, Celina M.
Shimizu, Flavio M.
Constantino, Carlos J. L. [UNESP]
Ferreira, Marystela
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Universidade Federal de São Carlos (UFSCar)
Universidade de São Paulo (USP)
Universidade Estadual Paulista (Unesp)
dc.contributor.author.fl_str_mv Lucena, Nathalia C. de
Miyazaki, Celina M.
Shimizu, Flavio M.
Constantino, Carlos J. L. [UNESP]
Ferreira, Marystela
dc.subject.por.fl_str_mv Dopamine
Layer-by-layer
Nickel phthalocyanine
Montmorillonite clay
Electrochemical sensor
topic Dopamine
Layer-by-layer
Nickel phthalocyanine
Montmorillonite clay
Electrochemical sensor
description Dopamine (DA) abnormal levels are related to diseases which makes important the development of fast, reliable, low-cost and sensitive devices for diagnosis and pharmaceutical controls. Nanostructured film composite of sodium montmorillonite clay (Na+MMT) and nickel phthalocyanine (NiTsPc) was selfassembled by layer-by-layer (LbL) technique and applied as electrochemical sensor for DA in the presence of common natural interferents as ascorbic acid (AA) and uric acid (UA). Three different LbL architecture films were investigated: LbL films of clay (PEI/Na+MMT) and phthalocyanine (PEI/NiTsPc) in a bilayer structure with a conventional polyelectrolyte (PEI) and a composite film formed by both materials to verify the synergistic effect in the LbL film in a quadri-layer assembly (PEI/Na+MMT/PEI/NiTsPc). Structural characterization indicated molecular level interactions between the layers forming the LbL films. The ITO/(PEI/Na+MMT/PEI/NiTsPc)(10) electrode exhibited a LOD of 1.0 mu mol L-1 and linear range 5-150 mu mol L-1. (C) 2017 Elsevier B.V. All rights reserved.
publishDate 2018
dc.date.none.fl_str_mv 2018-11-29T08:01:21Z
2018-11-29T08:01:21Z
2018-04-01
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1016/j.apsusc.2017.12.117
Applied Surface Science. Amsterdam: Elsevier Science Bv, v. 436, p. 957-966, 2018.
0169-4332
http://hdl.handle.net/11449/166019
10.1016/j.apsusc.2017.12.117
WOS:000425723100113
WOS000425723100113.pdf
url http://dx.doi.org/10.1016/j.apsusc.2017.12.117
http://hdl.handle.net/11449/166019
identifier_str_mv Applied Surface Science. Amsterdam: Elsevier Science Bv, v. 436, p. 957-966, 2018.
0169-4332
10.1016/j.apsusc.2017.12.117
WOS:000425723100113
WOS000425723100113.pdf
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Applied Surface Science
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 957-966
application/pdf
dc.publisher.none.fl_str_mv Elsevier B.V.
publisher.none.fl_str_mv Elsevier B.V.
dc.source.none.fl_str_mv Web of Science
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
_version_ 1808128469549187072

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