Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniques

Detalhes bibliográficos
Autor(a) principal: Santana, Ana P.R. [UNESP]
Data de Publicação: 2021
Outros Autores: Andrade, Daniel F., Guimarães, Taciana G.S. [UNESP], Amaral, Clarice D.B., Oliveirac, Andrea [UNESP], Nogueira, Ana R.A., Gonzaleza, Mario H. [UNESP]
Tipo de documento: Artigo
Idioma: por
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.21577/0100-4042.20170723
http://hdl.handle.net/11449/222258
Resumo: Natural deep eutectic solvents (NADES) based on xylitol, citric acid, and malic acid were synthesized and used in ultrasound-assisted extraction (UAE) and heating-bath extraction of phosphate rock and mineral supplement samples. Arsenic, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Na, P and Zn were determined by inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma optical emission spectrometry (ICP OES). The results showed the NADES as promising solvents for extraction of inorganic matrices compared to reference values and concentrations obtained using microwave-assisted acid digestion (MW-AD). Significant differences were observed for some elements, suggesting different chemical interactions between the synthesized NADES and each monitored element. For analytes extraction of phosphate rock, UAE presented the best results for As, Cr and P. Zinc was extracted with UAE and heating bath. Concerning mineral supplement, no significant differences were observed for Ca (UAE), Cd (UAE and heating bath), K (UAE and heating bath), Mn (UAE and heating bath), Na (UAE and heating bath), and P (UAE and heating bath). The NADES is a greener and a potentially alternative for the sample preparation compared to the official methods of analysis, can being used as selective extractor solvent in conventional sample preparation methods.
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spelling Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniquesSolventes eutÉticos naturais profundos (nades) no preparo de amostras de rocha fosfÁtica e suplemento mineral para determinaÇÃo elementar por tÉcnicas de plasmaGreen chemistryInorganic compositionInorganic samplesNADESSample preparationNatural deep eutectic solvents (NADES) based on xylitol, citric acid, and malic acid were synthesized and used in ultrasound-assisted extraction (UAE) and heating-bath extraction of phosphate rock and mineral supplement samples. Arsenic, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Na, P and Zn were determined by inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma optical emission spectrometry (ICP OES). The results showed the NADES as promising solvents for extraction of inorganic matrices compared to reference values and concentrations obtained using microwave-assisted acid digestion (MW-AD). Significant differences were observed for some elements, suggesting different chemical interactions between the synthesized NADES and each monitored element. For analytes extraction of phosphate rock, UAE presented the best results for As, Cr and P. Zinc was extracted with UAE and heating bath. Concerning mineral supplement, no significant differences were observed for Ca (UAE), Cd (UAE and heating bath), K (UAE and heating bath), Mn (UAE and heating bath), Na (UAE and heating bath), and P (UAE and heating bath). The NADES is a greener and a potentially alternative for the sample preparation compared to the official methods of analysis, can being used as selective extractor solvent in conventional sample preparation methods.Departamento de Química e Ciências Ambientais Instituto Nacional de Tecnologias Alternativas para Detecção Avaliação Toxicológica e Remoção de Contaminantes Emergentes e Radioativos Universidade Estadual Paulista “Júlio de Mesquita Filho”Departamento de Química Universidade Federal de São CarlosDepartamento de Química Universidade Federal do ParanáEmbrapa Pecuária SudesteDepartamento de Química e Ciências Ambientais Instituto Nacional de Tecnologias Alternativas para Detecção Avaliação Toxicológica e Remoção de Contaminantes Emergentes e Radioativos Universidade Estadual Paulista “Júlio de Mesquita Filho”Universidade Estadual Paulista (UNESP)Universidade Federal de São Carlos (UFSCar)Universidade Federal do Paraná (UFPR)Empresa Brasileira de Pesquisa Agropecuária (EMBRAPA)Santana, Ana P.R. [UNESP]Andrade, Daniel F.Guimarães, Taciana G.S. [UNESP]Amaral, Clarice D.B.Oliveirac, Andrea [UNESP]Nogueira, Ana R.A.Gonzaleza, Mario H. [UNESP]2022-04-28T19:43:36Z2022-04-28T19:43:36Z2021-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article689-695http://dx.doi.org/10.21577/0100-4042.20170723Quimica Nova, v. 44, n. 6, p. 689-695, 2021.1678-70640100-4042http://hdl.handle.net/11449/22225810.21577/0100-4042.201707232-s2.0-85113294499Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPporQuimica Novainfo:eu-repo/semantics/openAccess2022-04-28T19:43:37Zoai:repositorio.unesp.br:11449/222258Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462022-04-28T19:43:37Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniques
Solventes eutÉticos naturais profundos (nades) no preparo de amostras de rocha fosfÁtica e suplemento mineral para determinaÇÃo elementar por tÉcnicas de plasma
title Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniques
spellingShingle Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniques
Santana, Ana P.R. [UNESP]
Green chemistry
Inorganic composition
Inorganic samples
NADES
Sample preparation
title_short Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniques
title_full Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniques
title_fullStr Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniques
title_full_unstemmed Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniques
title_sort Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniques
author Santana, Ana P.R. [UNESP]
author_facet Santana, Ana P.R. [UNESP]
Andrade, Daniel F.
Guimarães, Taciana G.S. [UNESP]
Amaral, Clarice D.B.
Oliveirac, Andrea [UNESP]
Nogueira, Ana R.A.
Gonzaleza, Mario H. [UNESP]
author_role author
author2 Andrade, Daniel F.
Guimarães, Taciana G.S. [UNESP]
Amaral, Clarice D.B.
Oliveirac, Andrea [UNESP]
Nogueira, Ana R.A.
Gonzaleza, Mario H. [UNESP]
author2_role author
author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade Estadual Paulista (UNESP)
Universidade Federal de São Carlos (UFSCar)
Universidade Federal do Paraná (UFPR)
Empresa Brasileira de Pesquisa Agropecuária (EMBRAPA)
dc.contributor.author.fl_str_mv Santana, Ana P.R. [UNESP]
Andrade, Daniel F.
Guimarães, Taciana G.S. [UNESP]
Amaral, Clarice D.B.
Oliveirac, Andrea [UNESP]
Nogueira, Ana R.A.
Gonzaleza, Mario H. [UNESP]
dc.subject.por.fl_str_mv Green chemistry
Inorganic composition
Inorganic samples
NADES
Sample preparation
topic Green chemistry
Inorganic composition
Inorganic samples
NADES
Sample preparation
description Natural deep eutectic solvents (NADES) based on xylitol, citric acid, and malic acid were synthesized and used in ultrasound-assisted extraction (UAE) and heating-bath extraction of phosphate rock and mineral supplement samples. Arsenic, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Na, P and Zn were determined by inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma optical emission spectrometry (ICP OES). The results showed the NADES as promising solvents for extraction of inorganic matrices compared to reference values and concentrations obtained using microwave-assisted acid digestion (MW-AD). Significant differences were observed for some elements, suggesting different chemical interactions between the synthesized NADES and each monitored element. For analytes extraction of phosphate rock, UAE presented the best results for As, Cr and P. Zinc was extracted with UAE and heating bath. Concerning mineral supplement, no significant differences were observed for Ca (UAE), Cd (UAE and heating bath), K (UAE and heating bath), Mn (UAE and heating bath), Na (UAE and heating bath), and P (UAE and heating bath). The NADES is a greener and a potentially alternative for the sample preparation compared to the official methods of analysis, can being used as selective extractor solvent in conventional sample preparation methods.
publishDate 2021
dc.date.none.fl_str_mv 2021-01-01
2022-04-28T19:43:36Z
2022-04-28T19:43:36Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.21577/0100-4042.20170723
Quimica Nova, v. 44, n. 6, p. 689-695, 2021.
1678-7064
0100-4042
http://hdl.handle.net/11449/222258
10.21577/0100-4042.20170723
2-s2.0-85113294499
url http://dx.doi.org/10.21577/0100-4042.20170723
http://hdl.handle.net/11449/222258
identifier_str_mv Quimica Nova, v. 44, n. 6, p. 689-695, 2021.
1678-7064
0100-4042
10.21577/0100-4042.20170723
2-s2.0-85113294499
dc.language.iso.fl_str_mv por
language por
dc.relation.none.fl_str_mv Quimica Nova
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 689-695
dc.source.none.fl_str_mv Scopus
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
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