Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniques
Autor(a) principal: | |
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Data de Publicação: | 2021 |
Outros Autores: | , , , , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.21577/0100-4042.20170723 http://hdl.handle.net/11449/222258 |
Resumo: | Natural deep eutectic solvents (NADES) based on xylitol, citric acid, and malic acid were synthesized and used in ultrasound-assisted extraction (UAE) and heating-bath extraction of phosphate rock and mineral supplement samples. Arsenic, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Na, P and Zn were determined by inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma optical emission spectrometry (ICP OES). The results showed the NADES as promising solvents for extraction of inorganic matrices compared to reference values and concentrations obtained using microwave-assisted acid digestion (MW-AD). Significant differences were observed for some elements, suggesting different chemical interactions between the synthesized NADES and each monitored element. For analytes extraction of phosphate rock, UAE presented the best results for As, Cr and P. Zinc was extracted with UAE and heating bath. Concerning mineral supplement, no significant differences were observed for Ca (UAE), Cd (UAE and heating bath), K (UAE and heating bath), Mn (UAE and heating bath), Na (UAE and heating bath), and P (UAE and heating bath). The NADES is a greener and a potentially alternative for the sample preparation compared to the official methods of analysis, can being used as selective extractor solvent in conventional sample preparation methods. |
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Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniquesSolventes eutÉticos naturais profundos (nades) no preparo de amostras de rocha fosfÁtica e suplemento mineral para determinaÇÃo elementar por tÉcnicas de plasmaGreen chemistryInorganic compositionInorganic samplesNADESSample preparationNatural deep eutectic solvents (NADES) based on xylitol, citric acid, and malic acid were synthesized and used in ultrasound-assisted extraction (UAE) and heating-bath extraction of phosphate rock and mineral supplement samples. Arsenic, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Na, P and Zn were determined by inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma optical emission spectrometry (ICP OES). The results showed the NADES as promising solvents for extraction of inorganic matrices compared to reference values and concentrations obtained using microwave-assisted acid digestion (MW-AD). Significant differences were observed for some elements, suggesting different chemical interactions between the synthesized NADES and each monitored element. For analytes extraction of phosphate rock, UAE presented the best results for As, Cr and P. Zinc was extracted with UAE and heating bath. Concerning mineral supplement, no significant differences were observed for Ca (UAE), Cd (UAE and heating bath), K (UAE and heating bath), Mn (UAE and heating bath), Na (UAE and heating bath), and P (UAE and heating bath). The NADES is a greener and a potentially alternative for the sample preparation compared to the official methods of analysis, can being used as selective extractor solvent in conventional sample preparation methods.Departamento de Química e Ciências Ambientais Instituto Nacional de Tecnologias Alternativas para Detecção Avaliação Toxicológica e Remoção de Contaminantes Emergentes e Radioativos Universidade Estadual Paulista “Júlio de Mesquita Filho”Departamento de Química Universidade Federal de São CarlosDepartamento de Química Universidade Federal do ParanáEmbrapa Pecuária SudesteDepartamento de Química e Ciências Ambientais Instituto Nacional de Tecnologias Alternativas para Detecção Avaliação Toxicológica e Remoção de Contaminantes Emergentes e Radioativos Universidade Estadual Paulista “Júlio de Mesquita Filho”Universidade Estadual Paulista (UNESP)Universidade Federal de São Carlos (UFSCar)Universidade Federal do Paraná (UFPR)Empresa Brasileira de Pesquisa Agropecuária (EMBRAPA)Santana, Ana P.R. [UNESP]Andrade, Daniel F.Guimarães, Taciana G.S. [UNESP]Amaral, Clarice D.B.Oliveirac, Andrea [UNESP]Nogueira, Ana R.A.Gonzaleza, Mario H. [UNESP]2022-04-28T19:43:36Z2022-04-28T19:43:36Z2021-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article689-695http://dx.doi.org/10.21577/0100-4042.20170723Quimica Nova, v. 44, n. 6, p. 689-695, 2021.1678-70640100-4042http://hdl.handle.net/11449/22225810.21577/0100-4042.201707232-s2.0-85113294499Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPporQuimica Novainfo:eu-repo/semantics/openAccess2022-04-28T19:43:37Zoai:repositorio.unesp.br:11449/222258Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T20:03:57.318132Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniques Solventes eutÉticos naturais profundos (nades) no preparo de amostras de rocha fosfÁtica e suplemento mineral para determinaÇÃo elementar por tÉcnicas de plasma |
title |
Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniques |
spellingShingle |
Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniques Santana, Ana P.R. [UNESP] Green chemistry Inorganic composition Inorganic samples NADES Sample preparation |
title_short |
Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniques |
title_full |
Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniques |
title_fullStr |
Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniques |
title_full_unstemmed |
Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniques |
title_sort |
Natural deep eutectic Solvents (NADES) in sample preparation of phosphate rock and mineral supplement for elementary determination by plasma-based techniques |
author |
Santana, Ana P.R. [UNESP] |
author_facet |
Santana, Ana P.R. [UNESP] Andrade, Daniel F. Guimarães, Taciana G.S. [UNESP] Amaral, Clarice D.B. Oliveirac, Andrea [UNESP] Nogueira, Ana R.A. Gonzaleza, Mario H. [UNESP] |
author_role |
author |
author2 |
Andrade, Daniel F. Guimarães, Taciana G.S. [UNESP] Amaral, Clarice D.B. Oliveirac, Andrea [UNESP] Nogueira, Ana R.A. Gonzaleza, Mario H. [UNESP] |
author2_role |
author author author author author author |
dc.contributor.none.fl_str_mv |
Universidade Estadual Paulista (UNESP) Universidade Federal de São Carlos (UFSCar) Universidade Federal do Paraná (UFPR) Empresa Brasileira de Pesquisa Agropecuária (EMBRAPA) |
dc.contributor.author.fl_str_mv |
Santana, Ana P.R. [UNESP] Andrade, Daniel F. Guimarães, Taciana G.S. [UNESP] Amaral, Clarice D.B. Oliveirac, Andrea [UNESP] Nogueira, Ana R.A. Gonzaleza, Mario H. [UNESP] |
dc.subject.por.fl_str_mv |
Green chemistry Inorganic composition Inorganic samples NADES Sample preparation |
topic |
Green chemistry Inorganic composition Inorganic samples NADES Sample preparation |
description |
Natural deep eutectic solvents (NADES) based on xylitol, citric acid, and malic acid were synthesized and used in ultrasound-assisted extraction (UAE) and heating-bath extraction of phosphate rock and mineral supplement samples. Arsenic, Ca, Cd, Cr, Cu, Fe, K, Mg, Mn, Na, P and Zn were determined by inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma optical emission spectrometry (ICP OES). The results showed the NADES as promising solvents for extraction of inorganic matrices compared to reference values and concentrations obtained using microwave-assisted acid digestion (MW-AD). Significant differences were observed for some elements, suggesting different chemical interactions between the synthesized NADES and each monitored element. For analytes extraction of phosphate rock, UAE presented the best results for As, Cr and P. Zinc was extracted with UAE and heating bath. Concerning mineral supplement, no significant differences were observed for Ca (UAE), Cd (UAE and heating bath), K (UAE and heating bath), Mn (UAE and heating bath), Na (UAE and heating bath), and P (UAE and heating bath). The NADES is a greener and a potentially alternative for the sample preparation compared to the official methods of analysis, can being used as selective extractor solvent in conventional sample preparation methods. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-01-01 2022-04-28T19:43:36Z 2022-04-28T19:43:36Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.21577/0100-4042.20170723 Quimica Nova, v. 44, n. 6, p. 689-695, 2021. 1678-7064 0100-4042 http://hdl.handle.net/11449/222258 10.21577/0100-4042.20170723 2-s2.0-85113294499 |
url |
http://dx.doi.org/10.21577/0100-4042.20170723 http://hdl.handle.net/11449/222258 |
identifier_str_mv |
Quimica Nova, v. 44, n. 6, p. 689-695, 2021. 1678-7064 0100-4042 10.21577/0100-4042.20170723 2-s2.0-85113294499 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
Quimica Nova |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
689-695 |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
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1808129156300406784 |