One-pot synthesis of telluroketene acetals and haloketene acetals using sp(2) geminated hetero organobismetallic intermediates

Detalhes bibliográficos
Autor(a) principal: Guerrero, Palimecio G.
Data de Publicação: 2012
Outros Autores: Oliveira, Paulo R. de, Baroni, Adriano C. M., Marques, Francisco A., Labes, Ricardo, Dabdoub, Miguel J. [UNESP]
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1016/j.tetlet.2012.01.065
http://hdl.handle.net/11449/194735
Resumo: A novel one-pot synthesis of 1,1-dihalo-1-alkenes and 1,1-bis(butyltelluro)-1-alkenes was developed from hydrozirconation of alkynylzinc bromide with Cp2Zr(H)Cl and subsequent capture of the Zn/Zr 1,1-heterodimetallo-1-alkene intermediates with halogen and tellurium electrophiles. These protocols, which include multiple reactions in a one-pot procedure, allow the preparation of the potentially useful haloketene acetals and telluroketene acetals from terminal alkynes, under mild conditions and in a good yield. (C) 2012 Elsevier Ltd. All rights reserved.
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spelling One-pot synthesis of telluroketene acetals and haloketene acetals using sp(2) geminated hetero organobismetallic intermediatesZn/Zr sp(2) organobismetallicTelluroketene acetalsHaloketene acetalsOne-potA novel one-pot synthesis of 1,1-dihalo-1-alkenes and 1,1-bis(butyltelluro)-1-alkenes was developed from hydrozirconation of alkynylzinc bromide with Cp2Zr(H)Cl and subsequent capture of the Zn/Zr 1,1-heterodimetallo-1-alkene intermediates with halogen and tellurium electrophiles. These protocols, which include multiple reactions in a one-pot procedure, allow the preparation of the potentially useful haloketene acetals and telluroketene acetals from terminal alkynes, under mild conditions and in a good yield. (C) 2012 Elsevier Ltd. All rights reserved.Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)Fundacao AraucariaParand Fed Univ Technol, Dept Biol & Chem, DAQBi, UTFPR, Curitiba, Parana, BrazilUniv Fed Mato Grosso do Sul, Dept Biochem & Pharm, UFMS, Campo Grande, MS, BrazilUniv Fed Parana, Dept Chem, UFPR, BR-80060000 Curitiba, Parana, BrazilSao Paulo State Univ, Dept Chem, USP, Ribeirao Preto, SP, BrazilSao Paulo State Univ, Dept Chem, USP, Ribeirao Preto, SP, BrazilElsevier B.V.Parand Fed Univ TechnolUniversidade Federal de Mato Grosso do Sul (UFMS)Universidade Federal do Paraná (UFPR)Universidade Estadual Paulista (Unesp)Guerrero, Palimecio G.Oliveira, Paulo R. deBaroni, Adriano C. M.Marques, Francisco A.Labes, RicardoDabdoub, Miguel J. [UNESP]2020-12-10T16:36:02Z2020-12-10T16:36:02Z2012-03-28info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article1582-1586http://dx.doi.org/10.1016/j.tetlet.2012.01.065Tetrahedron Letters. Oxford: Pergamon-elsevier Science Ltd, v. 53, n. 13, p. 1582-1586, 2012.0040-4039http://hdl.handle.net/11449/19473510.1016/j.tetlet.2012.01.065WOS:000301692400013Web of Sciencereponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengTetrahedron Lettersinfo:eu-repo/semantics/openAccess2021-10-22T20:28:29Zoai:repositorio.unesp.br:11449/194735Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T21:29:57.889919Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv One-pot synthesis of telluroketene acetals and haloketene acetals using sp(2) geminated hetero organobismetallic intermediates
title One-pot synthesis of telluroketene acetals and haloketene acetals using sp(2) geminated hetero organobismetallic intermediates
spellingShingle One-pot synthesis of telluroketene acetals and haloketene acetals using sp(2) geminated hetero organobismetallic intermediates
Guerrero, Palimecio G.
Zn/Zr sp(2) organobismetallic
Telluroketene acetals
Haloketene acetals
One-pot
title_short One-pot synthesis of telluroketene acetals and haloketene acetals using sp(2) geminated hetero organobismetallic intermediates
title_full One-pot synthesis of telluroketene acetals and haloketene acetals using sp(2) geminated hetero organobismetallic intermediates
title_fullStr One-pot synthesis of telluroketene acetals and haloketene acetals using sp(2) geminated hetero organobismetallic intermediates
title_full_unstemmed One-pot synthesis of telluroketene acetals and haloketene acetals using sp(2) geminated hetero organobismetallic intermediates
title_sort One-pot synthesis of telluroketene acetals and haloketene acetals using sp(2) geminated hetero organobismetallic intermediates
author Guerrero, Palimecio G.
author_facet Guerrero, Palimecio G.
Oliveira, Paulo R. de
Baroni, Adriano C. M.
Marques, Francisco A.
Labes, Ricardo
Dabdoub, Miguel J. [UNESP]
author_role author
author2 Oliveira, Paulo R. de
Baroni, Adriano C. M.
Marques, Francisco A.
Labes, Ricardo
Dabdoub, Miguel J. [UNESP]
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Parand Fed Univ Technol
Universidade Federal de Mato Grosso do Sul (UFMS)
Universidade Federal do Paraná (UFPR)
Universidade Estadual Paulista (Unesp)
dc.contributor.author.fl_str_mv Guerrero, Palimecio G.
Oliveira, Paulo R. de
Baroni, Adriano C. M.
Marques, Francisco A.
Labes, Ricardo
Dabdoub, Miguel J. [UNESP]
dc.subject.por.fl_str_mv Zn/Zr sp(2) organobismetallic
Telluroketene acetals
Haloketene acetals
One-pot
topic Zn/Zr sp(2) organobismetallic
Telluroketene acetals
Haloketene acetals
One-pot
description A novel one-pot synthesis of 1,1-dihalo-1-alkenes and 1,1-bis(butyltelluro)-1-alkenes was developed from hydrozirconation of alkynylzinc bromide with Cp2Zr(H)Cl and subsequent capture of the Zn/Zr 1,1-heterodimetallo-1-alkene intermediates with halogen and tellurium electrophiles. These protocols, which include multiple reactions in a one-pot procedure, allow the preparation of the potentially useful haloketene acetals and telluroketene acetals from terminal alkynes, under mild conditions and in a good yield. (C) 2012 Elsevier Ltd. All rights reserved.
publishDate 2012
dc.date.none.fl_str_mv 2012-03-28
2020-12-10T16:36:02Z
2020-12-10T16:36:02Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1016/j.tetlet.2012.01.065
Tetrahedron Letters. Oxford: Pergamon-elsevier Science Ltd, v. 53, n. 13, p. 1582-1586, 2012.
0040-4039
http://hdl.handle.net/11449/194735
10.1016/j.tetlet.2012.01.065
WOS:000301692400013
url http://dx.doi.org/10.1016/j.tetlet.2012.01.065
http://hdl.handle.net/11449/194735
identifier_str_mv Tetrahedron Letters. Oxford: Pergamon-elsevier Science Ltd, v. 53, n. 13, p. 1582-1586, 2012.
0040-4039
10.1016/j.tetlet.2012.01.065
WOS:000301692400013
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Tetrahedron Letters
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 1582-1586
dc.publisher.none.fl_str_mv Elsevier B.V.
publisher.none.fl_str_mv Elsevier B.V.
dc.source.none.fl_str_mv Web of Science
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
_version_ 1808129326491631616

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