Pressurized Liquid Extraction (PLE) and QuEChERS evaluation for the analysis of antibiotics in agricultural soils
Autor(a) principal: | |
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Data de Publicação: | 2020 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1016/j.mex.2020.101171 http://hdl.handle.net/11449/208245 |
Resumo: | Vinasse, a liquid waste which originates from the production of ethanol fuel from sugarcane, has been widely used as soil amendment in Brazil. An important concern that arises from vinasse reuse is the dissemination of antibiotics to the environment through crop soils. This work evaluated the performance of Pressurized Liquid Extraction (PLE) and QuEChERS (quick, easy, cheap, effective, rugged and safe) to extract several multiple-class antibiotics, such as cephalosporins, fluoroquinolones, ionophores, lincosamides, macrolides, quinolones, streptogramin, sulfonamides, tetracyclines and others, from agricultural soils. The performance of several parameters was evaluated for both PLE and QuEChERS, such as the extraction temperature (for PLE), solvents composition, pH and the addition of EDTA. Both methods were able to extract most target antibiotics. However, QuEChERS showed higher recoveries for macrolides and nitroimidazoles, while PLE was more suitable for fluoroquinolones and ionophores (i.e. monensin). The use of citrate-phosphate buffer at pH 7.0, in combination with methanol for PLE and with acetonitrile for QuEChERS, provided the highest antibiotic recoveries for both methods. The use of EDTA did not increase antibiotic recovery rates for QuEChERS, while the temperature had almost no influence on the extraction efficiency in PLE. • Citrate-phosphate buffer at pH 7.0 provided higher antibiotic recoveries for QuEChERS and PLE. • The combination buffer-methanol provided higher recoveries for PLE. • QuEChERS and PLE methods were able to extract most of the target antibiotics. |
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Pressurized Liquid Extraction (PLE) and QuEChERS evaluation for the analysis of antibiotics in agricultural soilsAgricultural soilAntibiotic Soil ExtractionAntibioticsPressurized Liquid ExtractionQuEChERSVinasseVinasse, a liquid waste which originates from the production of ethanol fuel from sugarcane, has been widely used as soil amendment in Brazil. An important concern that arises from vinasse reuse is the dissemination of antibiotics to the environment through crop soils. This work evaluated the performance of Pressurized Liquid Extraction (PLE) and QuEChERS (quick, easy, cheap, effective, rugged and safe) to extract several multiple-class antibiotics, such as cephalosporins, fluoroquinolones, ionophores, lincosamides, macrolides, quinolones, streptogramin, sulfonamides, tetracyclines and others, from agricultural soils. The performance of several parameters was evaluated for both PLE and QuEChERS, such as the extraction temperature (for PLE), solvents composition, pH and the addition of EDTA. Both methods were able to extract most target antibiotics. However, QuEChERS showed higher recoveries for macrolides and nitroimidazoles, while PLE was more suitable for fluoroquinolones and ionophores (i.e. monensin). The use of citrate-phosphate buffer at pH 7.0, in combination with methanol for PLE and with acetonitrile for QuEChERS, provided the highest antibiotic recoveries for both methods. The use of EDTA did not increase antibiotic recovery rates for QuEChERS, while the temperature had almost no influence on the extraction efficiency in PLE. • Citrate-phosphate buffer at pH 7.0 provided higher antibiotic recoveries for QuEChERS and PLE. • The combination buffer-methanol provided higher recoveries for PLE. • QuEChERS and PLE methods were able to extract most of the target antibiotics.Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Institute of Chemistry São Paulo State University (UNESP)Bioenergy Research Institute (IPBEN) São Paulo State University (UNESP)Catalan Institution for Research and Advanced Studies (ICREA)Catalan Institute for Water Research (ICRA), Emili Grahit 101University of GironaInstitute of Chemistry São Paulo State University (UNESP)Bioenergy Research Institute (IPBEN) São Paulo State University (UNESP)FAPESP: 2016/06352-4FAPESP: 2018/15739-5Universidade Estadual Paulista (Unesp)Catalan Institution for Research and Advanced Studies (ICREA)Catalan Institute for Water Research (ICRA)University of Gironada Silva, Josiel José [UNESP]da Silva, Bianca Ferreira [UNESP]Stradiotto, Nelson Ramos [UNESP]Petrovic, MiraGago-Ferrero, PabloGros, Meritxell2021-06-25T11:08:50Z2021-06-25T11:08:50Z2020-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://dx.doi.org/10.1016/j.mex.2020.101171MethodsX, v. 7.2215-0161http://hdl.handle.net/11449/20824510.1016/j.mex.2020.1011712-s2.0-85097680261Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengMethodsXinfo:eu-repo/semantics/openAccess2021-10-23T18:56:55Zoai:repositorio.unesp.br:11449/208245Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T18:39:07.662515Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Pressurized Liquid Extraction (PLE) and QuEChERS evaluation for the analysis of antibiotics in agricultural soils |
title |
Pressurized Liquid Extraction (PLE) and QuEChERS evaluation for the analysis of antibiotics in agricultural soils |
spellingShingle |
Pressurized Liquid Extraction (PLE) and QuEChERS evaluation for the analysis of antibiotics in agricultural soils da Silva, Josiel José [UNESP] Agricultural soil Antibiotic Soil Extraction Antibiotics Pressurized Liquid Extraction QuEChERS Vinasse |
title_short |
Pressurized Liquid Extraction (PLE) and QuEChERS evaluation for the analysis of antibiotics in agricultural soils |
title_full |
Pressurized Liquid Extraction (PLE) and QuEChERS evaluation for the analysis of antibiotics in agricultural soils |
title_fullStr |
Pressurized Liquid Extraction (PLE) and QuEChERS evaluation for the analysis of antibiotics in agricultural soils |
title_full_unstemmed |
Pressurized Liquid Extraction (PLE) and QuEChERS evaluation for the analysis of antibiotics in agricultural soils |
title_sort |
Pressurized Liquid Extraction (PLE) and QuEChERS evaluation for the analysis of antibiotics in agricultural soils |
author |
da Silva, Josiel José [UNESP] |
author_facet |
da Silva, Josiel José [UNESP] da Silva, Bianca Ferreira [UNESP] Stradiotto, Nelson Ramos [UNESP] Petrovic, Mira Gago-Ferrero, Pablo Gros, Meritxell |
author_role |
author |
author2 |
da Silva, Bianca Ferreira [UNESP] Stradiotto, Nelson Ramos [UNESP] Petrovic, Mira Gago-Ferrero, Pablo Gros, Meritxell |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
Universidade Estadual Paulista (Unesp) Catalan Institution for Research and Advanced Studies (ICREA) Catalan Institute for Water Research (ICRA) University of Girona |
dc.contributor.author.fl_str_mv |
da Silva, Josiel José [UNESP] da Silva, Bianca Ferreira [UNESP] Stradiotto, Nelson Ramos [UNESP] Petrovic, Mira Gago-Ferrero, Pablo Gros, Meritxell |
dc.subject.por.fl_str_mv |
Agricultural soil Antibiotic Soil Extraction Antibiotics Pressurized Liquid Extraction QuEChERS Vinasse |
topic |
Agricultural soil Antibiotic Soil Extraction Antibiotics Pressurized Liquid Extraction QuEChERS Vinasse |
description |
Vinasse, a liquid waste which originates from the production of ethanol fuel from sugarcane, has been widely used as soil amendment in Brazil. An important concern that arises from vinasse reuse is the dissemination of antibiotics to the environment through crop soils. This work evaluated the performance of Pressurized Liquid Extraction (PLE) and QuEChERS (quick, easy, cheap, effective, rugged and safe) to extract several multiple-class antibiotics, such as cephalosporins, fluoroquinolones, ionophores, lincosamides, macrolides, quinolones, streptogramin, sulfonamides, tetracyclines and others, from agricultural soils. The performance of several parameters was evaluated for both PLE and QuEChERS, such as the extraction temperature (for PLE), solvents composition, pH and the addition of EDTA. Both methods were able to extract most target antibiotics. However, QuEChERS showed higher recoveries for macrolides and nitroimidazoles, while PLE was more suitable for fluoroquinolones and ionophores (i.e. monensin). The use of citrate-phosphate buffer at pH 7.0, in combination with methanol for PLE and with acetonitrile for QuEChERS, provided the highest antibiotic recoveries for both methods. The use of EDTA did not increase antibiotic recovery rates for QuEChERS, while the temperature had almost no influence on the extraction efficiency in PLE. • Citrate-phosphate buffer at pH 7.0 provided higher antibiotic recoveries for QuEChERS and PLE. • The combination buffer-methanol provided higher recoveries for PLE. • QuEChERS and PLE methods were able to extract most of the target antibiotics. |
publishDate |
2020 |
dc.date.none.fl_str_mv |
2020-01-01 2021-06-25T11:08:50Z 2021-06-25T11:08:50Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1016/j.mex.2020.101171 MethodsX, v. 7. 2215-0161 http://hdl.handle.net/11449/208245 10.1016/j.mex.2020.101171 2-s2.0-85097680261 |
url |
http://dx.doi.org/10.1016/j.mex.2020.101171 http://hdl.handle.net/11449/208245 |
identifier_str_mv |
MethodsX, v. 7. 2215-0161 10.1016/j.mex.2020.101171 2-s2.0-85097680261 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
MethodsX |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
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1808128959993348096 |