Nanocompósitos multifuncionas de fibroína reforçados com biocelulose

Detalhes bibliográficos
Autor(a) principal: Amaral, Thais Silva do [UNESP]
Data de Publicação: 2013
Tipo de documento: Trabalho de conclusão de curso
Idioma: por
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://hdl.handle.net/11449/132456
http://www.athena.biblioteca.unesp.br/exlibris/bd/capelo/2015-12-22/000744038.pdf
Resumo: This work shows the preparation and characterization of the new nanocomposites based on fibroin and biocellulose. Bacterial cellulose (BC) is an exopolysaccharide produced by bacteria of the genus Gluconacetobacter, which it has identical chemical structure of the cellulose from plants and it has gained attention in the field of research for its unique properties as excellent mechanical properties when dry and hydrated , higher capacity of water retention, moldability , biodegradability and excellent biological affinity . Silk fibroin (SF) is a structural protein present in the cocoon of the silkworm, Bombyx mori, has been identified as suitable for developing optical devices, tissue engineering application, enzyme immobilization, controlled release drug agent biopolymer. Silk fibroin/bacterial cellulose nanocomposite films were prepared impregnating different cellulose charges (0.5 %, 1.0 %, 1.5 %, 2.5 %, 5.0 % and 10.0 %) weight/weight. According mechanical tests and water and Paynes's cup permeability showed that SF/BC 1% nanocomposite has the most relevant results. Poliethylenoglicol (PEG) containing SF films improved optical and mechanical properties when compared to pristine SF film. New SF/BC nanocomposites could be applied in Medicine, as biodegradable packaging and flexible substrates for OLEDs.
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spelling Nanocompósitos multifuncionas de fibroína reforçados com bioceluloseQuímica inorgânicaBicho-da-sedaEngenharia tecidualSedaThis work shows the preparation and characterization of the new nanocomposites based on fibroin and biocellulose. Bacterial cellulose (BC) is an exopolysaccharide produced by bacteria of the genus Gluconacetobacter, which it has identical chemical structure of the cellulose from plants and it has gained attention in the field of research for its unique properties as excellent mechanical properties when dry and hydrated , higher capacity of water retention, moldability , biodegradability and excellent biological affinity . Silk fibroin (SF) is a structural protein present in the cocoon of the silkworm, Bombyx mori, has been identified as suitable for developing optical devices, tissue engineering application, enzyme immobilization, controlled release drug agent biopolymer. Silk fibroin/bacterial cellulose nanocomposite films were prepared impregnating different cellulose charges (0.5 %, 1.0 %, 1.5 %, 2.5 %, 5.0 % and 10.0 %) weight/weight. According mechanical tests and water and Paynes's cup permeability showed that SF/BC 1% nanocomposite has the most relevant results. Poliethylenoglicol (PEG) containing SF films improved optical and mechanical properties when compared to pristine SF film. New SF/BC nanocomposites could be applied in Medicine, as biodegradable packaging and flexible substrates for OLEDs.Este trabalho apresenta preparação e caracterização de novos nanocompósitos baseados em fibroína e biocelulose. A celulose bacteriana (CB) é um exopolissacarideo produzido por bactérias do gênero Gluconacetobacter, que possui estrutura química idêntica a celulose vegetal e tem ganhado atenção no campo de pesquisa por suas propriedades únicas como, excelente propriedade mecânica quando seca e hidratada, porosidade, maior capacidade de retenção de água, moldabilidade, biodegradabilidade e excelente afinidade biológica.A fibroína, uma proteína estrutural presente no casulo do bicho da seda,Bombyx mori,foi recentemente identificado como um biopolímero adequado para o desenvolvimentode dispositivos ópticos, uso em engenharia de tecidos, imobilização de enzimas, agente de liberação controlada de drogas e regeneração tecidual. Foram feitos filmes de fibroína agregando-se diferentes cargas de CB, 0,5%, 1,0%, 1,5%, 2,5%, 5,0% e 10,0%. Osestudos ópticos mostraram que a carga de celulose prejudicou a transparência do material. Caracterizações térmicas, morfológicas e estruturais comprovaramque os dois materiais interagem entre si, gerando novas propriedades. Ensaios mecânicos mostraram que a carga de 1% de celulose foi a que manteve as propriedades do novo filme mais parecidas com as membranas de Cb e Fb isoladas. Posteriormente foi feita a agregação do plastificante polietileno glicol, com diferentes massas molares, em uma matriz de fibroína. Os filmes mostraram excelentes propriedades ópticas, além de boas propriedades mecânicas. Os novos materiais se mostraram viáveis para aplicações biomédicas, bem como para embalagens e dispositivos ópticos.Universidade Estadual Paulista (Unesp)Ribeiro, Sidney José Lima [UNESP]Barud, Hernane [UNESP]Universidade Estadual Paulista (Unesp)Amaral, Thais Silva do [UNESP]2016-01-13T13:26:15Z2016-01-13T13:26:15Z2013info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/bachelorThesis49f.application/pdfAMARAL, Thais Silva do. Nanocompósitos multifuncionas de fibroína reforçados com biocelulose: Thais Silva do Amaral. -. 2013. 49f. , 2013.http://hdl.handle.net/11449/132456000744038http://www.athena.biblioteca.unesp.br/exlibris/bd/capelo/2015-12-22/000744038.pdf64460474630346540000-0003-3286-9440Alephreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPporinfo:eu-repo/semantics/openAccess2024-01-11T06:24:58Zoai:repositorio.unesp.br:11449/132456Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T22:39:43.316182Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Nanocompósitos multifuncionas de fibroína reforçados com biocelulose
title Nanocompósitos multifuncionas de fibroína reforçados com biocelulose
spellingShingle Nanocompósitos multifuncionas de fibroína reforçados com biocelulose
Amaral, Thais Silva do [UNESP]
Química inorgânica
Bicho-da-seda
Engenharia tecidual
Seda
title_short Nanocompósitos multifuncionas de fibroína reforçados com biocelulose
title_full Nanocompósitos multifuncionas de fibroína reforçados com biocelulose
title_fullStr Nanocompósitos multifuncionas de fibroína reforçados com biocelulose
title_full_unstemmed Nanocompósitos multifuncionas de fibroína reforçados com biocelulose
title_sort Nanocompósitos multifuncionas de fibroína reforçados com biocelulose
author Amaral, Thais Silva do [UNESP]
author_facet Amaral, Thais Silva do [UNESP]
author_role author
dc.contributor.none.fl_str_mv Ribeiro, Sidney José Lima [UNESP]
Barud, Hernane [UNESP]
Universidade Estadual Paulista (Unesp)
dc.contributor.author.fl_str_mv Amaral, Thais Silva do [UNESP]
dc.subject.por.fl_str_mv Química inorgânica
Bicho-da-seda
Engenharia tecidual
Seda
topic Química inorgânica
Bicho-da-seda
Engenharia tecidual
Seda
description This work shows the preparation and characterization of the new nanocomposites based on fibroin and biocellulose. Bacterial cellulose (BC) is an exopolysaccharide produced by bacteria of the genus Gluconacetobacter, which it has identical chemical structure of the cellulose from plants and it has gained attention in the field of research for its unique properties as excellent mechanical properties when dry and hydrated , higher capacity of water retention, moldability , biodegradability and excellent biological affinity . Silk fibroin (SF) is a structural protein present in the cocoon of the silkworm, Bombyx mori, has been identified as suitable for developing optical devices, tissue engineering application, enzyme immobilization, controlled release drug agent biopolymer. Silk fibroin/bacterial cellulose nanocomposite films were prepared impregnating different cellulose charges (0.5 %, 1.0 %, 1.5 %, 2.5 %, 5.0 % and 10.0 %) weight/weight. According mechanical tests and water and Paynes's cup permeability showed that SF/BC 1% nanocomposite has the most relevant results. Poliethylenoglicol (PEG) containing SF films improved optical and mechanical properties when compared to pristine SF film. New SF/BC nanocomposites could be applied in Medicine, as biodegradable packaging and flexible substrates for OLEDs.
publishDate 2013
dc.date.none.fl_str_mv 2013
2016-01-13T13:26:15Z
2016-01-13T13:26:15Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/bachelorThesis
format bachelorThesis
status_str publishedVersion
dc.identifier.uri.fl_str_mv AMARAL, Thais Silva do. Nanocompósitos multifuncionas de fibroína reforçados com biocelulose: Thais Silva do Amaral. -. 2013. 49f. , 2013.
http://hdl.handle.net/11449/132456
000744038
http://www.athena.biblioteca.unesp.br/exlibris/bd/capelo/2015-12-22/000744038.pdf
6446047463034654
0000-0003-3286-9440
identifier_str_mv AMARAL, Thais Silva do. Nanocompósitos multifuncionas de fibroína reforçados com biocelulose: Thais Silva do Amaral. -. 2013. 49f. , 2013.
000744038
6446047463034654
0000-0003-3286-9440
url http://hdl.handle.net/11449/132456
http://www.athena.biblioteca.unesp.br/exlibris/bd/capelo/2015-12-22/000744038.pdf
dc.language.iso.fl_str_mv por
language por
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 49f.
application/pdf
dc.publisher.none.fl_str_mv Universidade Estadual Paulista (Unesp)
publisher.none.fl_str_mv Universidade Estadual Paulista (Unesp)
dc.source.none.fl_str_mv Aleph
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
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