Nanocompósitos multifuncionas de fibroína reforçados com biocelulose
Autor(a) principal: | |
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Data de Publicação: | 2013 |
Tipo de documento: | Trabalho de conclusão de curso |
Idioma: | por |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://hdl.handle.net/11449/132456 http://www.athena.biblioteca.unesp.br/exlibris/bd/capelo/2015-12-22/000744038.pdf |
Resumo: | This work shows the preparation and characterization of the new nanocomposites based on fibroin and biocellulose. Bacterial cellulose (BC) is an exopolysaccharide produced by bacteria of the genus Gluconacetobacter, which it has identical chemical structure of the cellulose from plants and it has gained attention in the field of research for its unique properties as excellent mechanical properties when dry and hydrated , higher capacity of water retention, moldability , biodegradability and excellent biological affinity . Silk fibroin (SF) is a structural protein present in the cocoon of the silkworm, Bombyx mori, has been identified as suitable for developing optical devices, tissue engineering application, enzyme immobilization, controlled release drug agent biopolymer. Silk fibroin/bacterial cellulose nanocomposite films were prepared impregnating different cellulose charges (0.5 %, 1.0 %, 1.5 %, 2.5 %, 5.0 % and 10.0 %) weight/weight. According mechanical tests and water and Paynes's cup permeability showed that SF/BC 1% nanocomposite has the most relevant results. Poliethylenoglicol (PEG) containing SF films improved optical and mechanical properties when compared to pristine SF film. New SF/BC nanocomposites could be applied in Medicine, as biodegradable packaging and flexible substrates for OLEDs. |
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Nanocompósitos multifuncionas de fibroína reforçados com bioceluloseQuímica inorgânicaBicho-da-sedaEngenharia tecidualSedaThis work shows the preparation and characterization of the new nanocomposites based on fibroin and biocellulose. Bacterial cellulose (BC) is an exopolysaccharide produced by bacteria of the genus Gluconacetobacter, which it has identical chemical structure of the cellulose from plants and it has gained attention in the field of research for its unique properties as excellent mechanical properties when dry and hydrated , higher capacity of water retention, moldability , biodegradability and excellent biological affinity . Silk fibroin (SF) is a structural protein present in the cocoon of the silkworm, Bombyx mori, has been identified as suitable for developing optical devices, tissue engineering application, enzyme immobilization, controlled release drug agent biopolymer. Silk fibroin/bacterial cellulose nanocomposite films were prepared impregnating different cellulose charges (0.5 %, 1.0 %, 1.5 %, 2.5 %, 5.0 % and 10.0 %) weight/weight. According mechanical tests and water and Paynes's cup permeability showed that SF/BC 1% nanocomposite has the most relevant results. Poliethylenoglicol (PEG) containing SF films improved optical and mechanical properties when compared to pristine SF film. New SF/BC nanocomposites could be applied in Medicine, as biodegradable packaging and flexible substrates for OLEDs.Este trabalho apresenta preparação e caracterização de novos nanocompósitos baseados em fibroína e biocelulose. A celulose bacteriana (CB) é um exopolissacarideo produzido por bactérias do gênero Gluconacetobacter, que possui estrutura química idêntica a celulose vegetal e tem ganhado atenção no campo de pesquisa por suas propriedades únicas como, excelente propriedade mecânica quando seca e hidratada, porosidade, maior capacidade de retenção de água, moldabilidade, biodegradabilidade e excelente afinidade biológica.A fibroína, uma proteína estrutural presente no casulo do bicho da seda,Bombyx mori,foi recentemente identificado como um biopolímero adequado para o desenvolvimentode dispositivos ópticos, uso em engenharia de tecidos, imobilização de enzimas, agente de liberação controlada de drogas e regeneração tecidual. Foram feitos filmes de fibroína agregando-se diferentes cargas de CB, 0,5%, 1,0%, 1,5%, 2,5%, 5,0% e 10,0%. Osestudos ópticos mostraram que a carga de celulose prejudicou a transparência do material. Caracterizações térmicas, morfológicas e estruturais comprovaramque os dois materiais interagem entre si, gerando novas propriedades. Ensaios mecânicos mostraram que a carga de 1% de celulose foi a que manteve as propriedades do novo filme mais parecidas com as membranas de Cb e Fb isoladas. Posteriormente foi feita a agregação do plastificante polietileno glicol, com diferentes massas molares, em uma matriz de fibroína. Os filmes mostraram excelentes propriedades ópticas, além de boas propriedades mecânicas. Os novos materiais se mostraram viáveis para aplicações biomédicas, bem como para embalagens e dispositivos ópticos.Universidade Estadual Paulista (Unesp)Ribeiro, Sidney José Lima [UNESP]Barud, Hernane [UNESP]Universidade Estadual Paulista (Unesp)Amaral, Thais Silva do [UNESP]2016-01-13T13:26:15Z2016-01-13T13:26:15Z2013info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/bachelorThesis49f.application/pdfAMARAL, Thais Silva do. Nanocompósitos multifuncionas de fibroína reforçados com biocelulose: Thais Silva do Amaral. -. 2013. 49f. , 2013.http://hdl.handle.net/11449/132456000744038http://www.athena.biblioteca.unesp.br/exlibris/bd/capelo/2015-12-22/000744038.pdf64460474630346540000-0003-3286-9440Alephreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPporinfo:eu-repo/semantics/openAccess2024-01-11T06:24:58Zoai:repositorio.unesp.br:11449/132456Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T22:39:43.316182Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Nanocompósitos multifuncionas de fibroína reforçados com biocelulose |
title |
Nanocompósitos multifuncionas de fibroína reforçados com biocelulose |
spellingShingle |
Nanocompósitos multifuncionas de fibroína reforçados com biocelulose Amaral, Thais Silva do [UNESP] Química inorgânica Bicho-da-seda Engenharia tecidual Seda |
title_short |
Nanocompósitos multifuncionas de fibroína reforçados com biocelulose |
title_full |
Nanocompósitos multifuncionas de fibroína reforçados com biocelulose |
title_fullStr |
Nanocompósitos multifuncionas de fibroína reforçados com biocelulose |
title_full_unstemmed |
Nanocompósitos multifuncionas de fibroína reforçados com biocelulose |
title_sort |
Nanocompósitos multifuncionas de fibroína reforçados com biocelulose |
author |
Amaral, Thais Silva do [UNESP] |
author_facet |
Amaral, Thais Silva do [UNESP] |
author_role |
author |
dc.contributor.none.fl_str_mv |
Ribeiro, Sidney José Lima [UNESP] Barud, Hernane [UNESP] Universidade Estadual Paulista (Unesp) |
dc.contributor.author.fl_str_mv |
Amaral, Thais Silva do [UNESP] |
dc.subject.por.fl_str_mv |
Química inorgânica Bicho-da-seda Engenharia tecidual Seda |
topic |
Química inorgânica Bicho-da-seda Engenharia tecidual Seda |
description |
This work shows the preparation and characterization of the new nanocomposites based on fibroin and biocellulose. Bacterial cellulose (BC) is an exopolysaccharide produced by bacteria of the genus Gluconacetobacter, which it has identical chemical structure of the cellulose from plants and it has gained attention in the field of research for its unique properties as excellent mechanical properties when dry and hydrated , higher capacity of water retention, moldability , biodegradability and excellent biological affinity . Silk fibroin (SF) is a structural protein present in the cocoon of the silkworm, Bombyx mori, has been identified as suitable for developing optical devices, tissue engineering application, enzyme immobilization, controlled release drug agent biopolymer. Silk fibroin/bacterial cellulose nanocomposite films were prepared impregnating different cellulose charges (0.5 %, 1.0 %, 1.5 %, 2.5 %, 5.0 % and 10.0 %) weight/weight. According mechanical tests and water and Paynes's cup permeability showed that SF/BC 1% nanocomposite has the most relevant results. Poliethylenoglicol (PEG) containing SF films improved optical and mechanical properties when compared to pristine SF film. New SF/BC nanocomposites could be applied in Medicine, as biodegradable packaging and flexible substrates for OLEDs. |
publishDate |
2013 |
dc.date.none.fl_str_mv |
2013 2016-01-13T13:26:15Z 2016-01-13T13:26:15Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/bachelorThesis |
format |
bachelorThesis |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
AMARAL, Thais Silva do. Nanocompósitos multifuncionas de fibroína reforçados com biocelulose: Thais Silva do Amaral. -. 2013. 49f. , 2013. http://hdl.handle.net/11449/132456 000744038 http://www.athena.biblioteca.unesp.br/exlibris/bd/capelo/2015-12-22/000744038.pdf 6446047463034654 0000-0003-3286-9440 |
identifier_str_mv |
AMARAL, Thais Silva do. Nanocompósitos multifuncionas de fibroína reforçados com biocelulose: Thais Silva do Amaral. -. 2013. 49f. , 2013. 000744038 6446047463034654 0000-0003-3286-9440 |
url |
http://hdl.handle.net/11449/132456 http://www.athena.biblioteca.unesp.br/exlibris/bd/capelo/2015-12-22/000744038.pdf |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
49f. application/pdf |
dc.publisher.none.fl_str_mv |
Universidade Estadual Paulista (Unesp) |
publisher.none.fl_str_mv |
Universidade Estadual Paulista (Unesp) |
dc.source.none.fl_str_mv |
Aleph reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1808129448057241600 |