Impact of reduced graphene oxide on the ethanol sensing performance of hollow SnO2 nanoparticles under humid atmosphere

• Autor(a) principal: Zito, Cecilia A. [UNESP]
• Data de Publicação: 2017
• Outros Autores: Perfecto, Tarcísio M. [UNESP], Volanti, Diogo P. [UNESP]
• Tipo de documento: Artigo
• Idioma: eng
• Título da fonte: Repositório Institucional da UNESP
• Texto Completo: http://dx.doi.org/10.1016/j.snb.2017.01.015; http://hdl.handle.net/11449/169333
• topic: Humidity; Nanocomposites; One-pot synthesis; Oxolation; Reduced graphene oxide; Tin oxide

The interference of humidity is a key factor to be considered in metal oxide semiconductors gas sensing performance. However, an efficient gas detection under humid conditions is a challenge. Herein, we report the effect of reduced graphene oxide (RGO) on volatile organic compounds (VOCs) sensing performance of hollow SnO2nanoparticles (NPs) under wet atmosphere. For this purpose, RGO-SnO2nanocomposite was obtained by a one-pot microwave-assisted solvothermal synthesis. The sensing tests for VOCs were conducted under dry air and at a relative humidity (RH) between 24 and 98%. The samples exhibited better response toward ethanol than to other VOCs such as acetone, benzene, methanol, m-xylene, and toluene, at the optimum operating temperature of 300 °C. Furthermore, RGO-SnO2nanocomposite showed an enhanced ethanol response in comparison with pure hollow SnO2NPs. Even under 98% of RH, the RGO-SnO2nanocomposite showed a response of 43.0 toward 100 ppm of ethanol with a response time of 8 s. The excellent sensor performance is related to the hollow structure of SnO2NPs, and the heterojunction between RGO and SnO2. Therefore, the RGO content can be a promising approach to minimize the humidity effect on SnO2ethanol sensing performance.