Compostos heterometálicos. Interação do tricarbonil com ligação W-Hg, [WCl(CO)3(bipy)(HgCl)], com tiouréias
Autor(a) principal: | |
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Data de Publicação: | 1997 |
Outros Autores: | , , |
Tipo de documento: | Artigo |
Idioma: | por |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1590/S0100-46701997000100007 http://hdl.handle.net/11449/33587 |
Resumo: | Reactions of [WC1(CO)(3)(bipy)(HgCl)], [bipy = 2,2 -bipyridine], with thioureas were performed giving compounds of the type [WCl(CO)(3)(bipy)(HgCl)L], [L = thiourea (tu); N-methylthiourea (mtu); N,N-dimethyithiourea (dmtu)] in which the coordination sphere of the tungsten atom remained unchanged. The coordination of the thioureas to mercury atom was proved to occur in accord to infrared spectra, through the sulphur atom. |
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Compostos heterometálicos. Interação do tricarbonil com ligação W-Hg, [WCl(CO)3(bipy)(HgCl)], com tiouréiasHeterometallic compounds. Interaction of the tricarbonyl containing W-Hg bond, [WCl(CO)(3)(bipy)(HgCl)], with thioureas.heterometallictricarbonylthioureainfrared spectroscopyReactions of [WC1(CO)(3)(bipy)(HgCl)], [bipy = 2,2 -bipyridine], with thioureas were performed giving compounds of the type [WCl(CO)(3)(bipy)(HgCl)L], [L = thiourea (tu); N-methylthiourea (mtu); N,N-dimethyithiourea (dmtu)] in which the coordination sphere of the tungsten atom remained unchanged. The coordination of the thioureas to mercury atom was proved to occur in accord to infrared spectra, through the sulphur atom.Federacao Fac Isoladas Araraquara, FEFIARA, BR-24802320 Araraquara, SP, BrazilUNESP, Inst Quim, Dept Quim Geral & Inorgan, BR-14800900 Araraquara, SP, BrazilUNESP, Inst Quim, Dept Quim Geral & Inorgan, BR-14800900 Araraquara, SP, BrazilEditora UnespFederacao Fac Isoladas AraraquaraUniversidade Estadual Paulista (Unesp)Muraoka, T. K.Mauro, Antonio Eduardo [UNESP]Nogueira, Vânia Martins [UNESP]Haddad, P. S.2014-05-20T15:22:38Z2014-05-20T15:22:38Z1997-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article75-82http://dx.doi.org/10.1590/S0100-46701997000100007Ecletica Química. São Paulo: Editora Unesp, v. 22, p. 75-82, 1997.0100-4670http://hdl.handle.net/11449/3358710.1590/S0100-46701997000100007S0100-46701997000100007WOS:00007457220000733002239708144488980849254118153Web of Sciencereponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPporEclética Químicainfo:eu-repo/semantics/openAccess2021-10-23T08:59:33Zoai:repositorio.unesp.br:11449/33587Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T22:30:18.299439Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Compostos heterometálicos. Interação do tricarbonil com ligação W-Hg, [WCl(CO)3(bipy)(HgCl)], com tiouréias Heterometallic compounds. Interaction of the tricarbonyl containing W-Hg bond, [WCl(CO)(3)(bipy)(HgCl)], with thioureas. |
title |
Compostos heterometálicos. Interação do tricarbonil com ligação W-Hg, [WCl(CO)3(bipy)(HgCl)], com tiouréias |
spellingShingle |
Compostos heterometálicos. Interação do tricarbonil com ligação W-Hg, [WCl(CO)3(bipy)(HgCl)], com tiouréias Muraoka, T. K. heterometallic tricarbonyl thiourea infrared spectroscopy |
title_short |
Compostos heterometálicos. Interação do tricarbonil com ligação W-Hg, [WCl(CO)3(bipy)(HgCl)], com tiouréias |
title_full |
Compostos heterometálicos. Interação do tricarbonil com ligação W-Hg, [WCl(CO)3(bipy)(HgCl)], com tiouréias |
title_fullStr |
Compostos heterometálicos. Interação do tricarbonil com ligação W-Hg, [WCl(CO)3(bipy)(HgCl)], com tiouréias |
title_full_unstemmed |
Compostos heterometálicos. Interação do tricarbonil com ligação W-Hg, [WCl(CO)3(bipy)(HgCl)], com tiouréias |
title_sort |
Compostos heterometálicos. Interação do tricarbonil com ligação W-Hg, [WCl(CO)3(bipy)(HgCl)], com tiouréias |
author |
Muraoka, T. K. |
author_facet |
Muraoka, T. K. Mauro, Antonio Eduardo [UNESP] Nogueira, Vânia Martins [UNESP] Haddad, P. S. |
author_role |
author |
author2 |
Mauro, Antonio Eduardo [UNESP] Nogueira, Vânia Martins [UNESP] Haddad, P. S. |
author2_role |
author author author |
dc.contributor.none.fl_str_mv |
Federacao Fac Isoladas Araraquara Universidade Estadual Paulista (Unesp) |
dc.contributor.author.fl_str_mv |
Muraoka, T. K. Mauro, Antonio Eduardo [UNESP] Nogueira, Vânia Martins [UNESP] Haddad, P. S. |
dc.subject.por.fl_str_mv |
heterometallic tricarbonyl thiourea infrared spectroscopy |
topic |
heterometallic tricarbonyl thiourea infrared spectroscopy |
description |
Reactions of [WC1(CO)(3)(bipy)(HgCl)], [bipy = 2,2 -bipyridine], with thioureas were performed giving compounds of the type [WCl(CO)(3)(bipy)(HgCl)L], [L = thiourea (tu); N-methylthiourea (mtu); N,N-dimethyithiourea (dmtu)] in which the coordination sphere of the tungsten atom remained unchanged. The coordination of the thioureas to mercury atom was proved to occur in accord to infrared spectra, through the sulphur atom. |
publishDate |
1997 |
dc.date.none.fl_str_mv |
1997-01-01 2014-05-20T15:22:38Z 2014-05-20T15:22:38Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1590/S0100-46701997000100007 Ecletica Química. São Paulo: Editora Unesp, v. 22, p. 75-82, 1997. 0100-4670 http://hdl.handle.net/11449/33587 10.1590/S0100-46701997000100007 S0100-46701997000100007 WOS:000074572200007 3300223970814448 8980849254118153 |
url |
http://dx.doi.org/10.1590/S0100-46701997000100007 http://hdl.handle.net/11449/33587 |
identifier_str_mv |
Ecletica Química. São Paulo: Editora Unesp, v. 22, p. 75-82, 1997. 0100-4670 10.1590/S0100-46701997000100007 S0100-46701997000100007 WOS:000074572200007 3300223970814448 8980849254118153 |
dc.language.iso.fl_str_mv |
por |
language |
por |
dc.relation.none.fl_str_mv |
Eclética Química |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
75-82 |
dc.publisher.none.fl_str_mv |
Editora Unesp |
publisher.none.fl_str_mv |
Editora Unesp |
dc.source.none.fl_str_mv |
Web of Science reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1808129432911609856 |