A Tetranuclear Silver-Thiourea Cluster

Detalhes bibliográficos
Autor(a) principal: Fernandes, José A. [UNESP]
Data de Publicação: 2015
Outros Autores: Segura, Daniel F., Netto, Adelino V. G., Frem, Regina C. G., Mauro, Antonio E. [UNESP], Paz, Filipe A. Almeida [UNESP]
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1007/s10870-015-0608-9
http://hdl.handle.net/11449/172103
Resumo: During the synthesis of the bioactive complex [Ag(phen)(μ-tu)]<inf>2</inf>(NO<inf>3</inf>)<inf>2</inf> (1), some crystals of a new compound were isolated. This crystalline compound, [Ag<inf>4</inf>(μ-tu)<inf>5</inf>(tu)<inf>6</inf>](NO<inf>3</inf>)<inf>4</inf>·7Phen (2) (tu = thiourea, Phen = 1,10-phenanthroline), is a novelty for at least two reasons: (i) it is the first tetranuclear silver and thiourea cluster; (ii) it is the first crystal structure with seven neutral, and uncoordinated, phen molecules. Phen molecules pack forming an infinite column, and the tu ligands form an intricate network of hydrogen bonds with the Phen and nitrate entities.
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spelling A Tetranuclear Silver-Thiourea ClusterSilver and thiourea clusterSupramolecular interactionsDuring the synthesis of the bioactive complex [Ag(phen)(μ-tu)]<inf>2</inf>(NO<inf>3</inf>)<inf>2</inf> (1), some crystals of a new compound were isolated. This crystalline compound, [Ag<inf>4</inf>(μ-tu)<inf>5</inf>(tu)<inf>6</inf>](NO<inf>3</inf>)<inf>4</inf>·7Phen (2) (tu = thiourea, Phen = 1,10-phenanthroline), is a novelty for at least two reasons: (i) it is the first tetranuclear silver and thiourea cluster; (ii) it is the first crystal structure with seven neutral, and uncoordinated, phen molecules. Phen molecules pack forming an infinite column, and the tu ligands form an intricate network of hydrogen bonds with the Phen and nitrate entities.Departamento de Química Geral e Inorgânica, Instituto de Química, UNESP-Univ Estadual PaulistaDepartment of Chemistry, CICECO, University of AveiroDepartamento de Química Geral e Inorgânica, Instituto de Química, UNESP-Univ Estadual PaulistaUniversidade Estadual Paulista (Unesp)Fernandes, José A. [UNESP]Segura, Daniel F.Netto, Adelino V. G.Frem, Regina C. G.Mauro, Antonio E. [UNESP]Paz, Filipe A. Almeida [UNESP]2018-12-11T16:58:40Z2018-12-11T16:58:40Z2015-09-30info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article410-418application/pdfhttp://dx.doi.org/10.1007/s10870-015-0608-9Journal of Chemical Crystallography, v. 45, n. 8-9, p. 410-418, 2015.1074-1542http://hdl.handle.net/11449/17210310.1007/s10870-015-0608-92-s2.0-849425904512-s2.0-84942590451.pdf792767705365081985341388134171610000-0002-0057-79640000-0003-1574-681XScopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of Chemical Crystallography0,209info:eu-repo/semantics/openAccess2023-12-19T06:24:22Zoai:repositorio.unesp.br:11449/172103Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T20:45:59.780534Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv A Tetranuclear Silver-Thiourea Cluster
title A Tetranuclear Silver-Thiourea Cluster
spellingShingle A Tetranuclear Silver-Thiourea Cluster
Fernandes, José A. [UNESP]
Silver and thiourea cluster
Supramolecular interactions
title_short A Tetranuclear Silver-Thiourea Cluster
title_full A Tetranuclear Silver-Thiourea Cluster
title_fullStr A Tetranuclear Silver-Thiourea Cluster
title_full_unstemmed A Tetranuclear Silver-Thiourea Cluster
title_sort A Tetranuclear Silver-Thiourea Cluster
author Fernandes, José A. [UNESP]
author_facet Fernandes, José A. [UNESP]
Segura, Daniel F.
Netto, Adelino V. G.
Frem, Regina C. G.
Mauro, Antonio E. [UNESP]
Paz, Filipe A. Almeida [UNESP]
author_role author
author2 Segura, Daniel F.
Netto, Adelino V. G.
Frem, Regina C. G.
Mauro, Antonio E. [UNESP]
Paz, Filipe A. Almeida [UNESP]
author2_role author
author
author
author
author
dc.contributor.none.fl_str_mv Universidade Estadual Paulista (Unesp)
dc.contributor.author.fl_str_mv Fernandes, José A. [UNESP]
Segura, Daniel F.
Netto, Adelino V. G.
Frem, Regina C. G.
Mauro, Antonio E. [UNESP]
Paz, Filipe A. Almeida [UNESP]
dc.subject.por.fl_str_mv Silver and thiourea cluster
Supramolecular interactions
topic Silver and thiourea cluster
Supramolecular interactions
description During the synthesis of the bioactive complex [Ag(phen)(μ-tu)]<inf>2</inf>(NO<inf>3</inf>)<inf>2</inf> (1), some crystals of a new compound were isolated. This crystalline compound, [Ag<inf>4</inf>(μ-tu)<inf>5</inf>(tu)<inf>6</inf>](NO<inf>3</inf>)<inf>4</inf>·7Phen (2) (tu = thiourea, Phen = 1,10-phenanthroline), is a novelty for at least two reasons: (i) it is the first tetranuclear silver and thiourea cluster; (ii) it is the first crystal structure with seven neutral, and uncoordinated, phen molecules. Phen molecules pack forming an infinite column, and the tu ligands form an intricate network of hydrogen bonds with the Phen and nitrate entities.
publishDate 2015
dc.date.none.fl_str_mv 2015-09-30
2018-12-11T16:58:40Z
2018-12-11T16:58:40Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1007/s10870-015-0608-9
Journal of Chemical Crystallography, v. 45, n. 8-9, p. 410-418, 2015.
1074-1542
http://hdl.handle.net/11449/172103
10.1007/s10870-015-0608-9
2-s2.0-84942590451
2-s2.0-84942590451.pdf
7927677053650819
8534138813417161
0000-0002-0057-7964
0000-0003-1574-681X
url http://dx.doi.org/10.1007/s10870-015-0608-9
http://hdl.handle.net/11449/172103
identifier_str_mv Journal of Chemical Crystallography, v. 45, n. 8-9, p. 410-418, 2015.
1074-1542
10.1007/s10870-015-0608-9
2-s2.0-84942590451
2-s2.0-84942590451.pdf
7927677053650819
8534138813417161
0000-0002-0057-7964
0000-0003-1574-681X
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Journal of Chemical Crystallography
0,209
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 410-418
application/pdf
dc.source.none.fl_str_mv Scopus
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
_version_ 1808129245154639872

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