A Tetranuclear Silver-Thiourea Cluster
Autor(a) principal: | |
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Data de Publicação: | 2015 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1007/s10870-015-0608-9 http://hdl.handle.net/11449/172103 |
Resumo: | During the synthesis of the bioactive complex [Ag(phen)(μ-tu)]<inf>2</inf>(NO<inf>3</inf>)<inf>2</inf> (1), some crystals of a new compound were isolated. This crystalline compound, [Ag<inf>4</inf>(μ-tu)<inf>5</inf>(tu)<inf>6</inf>](NO<inf>3</inf>)<inf>4</inf>·7Phen (2) (tu = thiourea, Phen = 1,10-phenanthroline), is a novelty for at least two reasons: (i) it is the first tetranuclear silver and thiourea cluster; (ii) it is the first crystal structure with seven neutral, and uncoordinated, phen molecules. Phen molecules pack forming an infinite column, and the tu ligands form an intricate network of hydrogen bonds with the Phen and nitrate entities. |
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Repositório Institucional da UNESP |
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A Tetranuclear Silver-Thiourea ClusterSilver and thiourea clusterSupramolecular interactionsDuring the synthesis of the bioactive complex [Ag(phen)(μ-tu)]<inf>2</inf>(NO<inf>3</inf>)<inf>2</inf> (1), some crystals of a new compound were isolated. This crystalline compound, [Ag<inf>4</inf>(μ-tu)<inf>5</inf>(tu)<inf>6</inf>](NO<inf>3</inf>)<inf>4</inf>·7Phen (2) (tu = thiourea, Phen = 1,10-phenanthroline), is a novelty for at least two reasons: (i) it is the first tetranuclear silver and thiourea cluster; (ii) it is the first crystal structure with seven neutral, and uncoordinated, phen molecules. Phen molecules pack forming an infinite column, and the tu ligands form an intricate network of hydrogen bonds with the Phen and nitrate entities.Departamento de Química Geral e Inorgânica, Instituto de Química, UNESP-Univ Estadual PaulistaDepartment of Chemistry, CICECO, University of AveiroDepartamento de Química Geral e Inorgânica, Instituto de Química, UNESP-Univ Estadual PaulistaUniversidade Estadual Paulista (Unesp)Fernandes, José A. [UNESP]Segura, Daniel F.Netto, Adelino V. G.Frem, Regina C. G.Mauro, Antonio E. [UNESP]Paz, Filipe A. Almeida [UNESP]2018-12-11T16:58:40Z2018-12-11T16:58:40Z2015-09-30info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article410-418application/pdfhttp://dx.doi.org/10.1007/s10870-015-0608-9Journal of Chemical Crystallography, v. 45, n. 8-9, p. 410-418, 2015.1074-1542http://hdl.handle.net/11449/17210310.1007/s10870-015-0608-92-s2.0-849425904512-s2.0-84942590451.pdf792767705365081985341388134171610000-0002-0057-79640000-0003-1574-681XScopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of Chemical Crystallography0,209info:eu-repo/semantics/openAccess2023-12-19T06:24:22Zoai:repositorio.unesp.br:11449/172103Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T20:45:59.780534Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
A Tetranuclear Silver-Thiourea Cluster |
title |
A Tetranuclear Silver-Thiourea Cluster |
spellingShingle |
A Tetranuclear Silver-Thiourea Cluster Fernandes, José A. [UNESP] Silver and thiourea cluster Supramolecular interactions |
title_short |
A Tetranuclear Silver-Thiourea Cluster |
title_full |
A Tetranuclear Silver-Thiourea Cluster |
title_fullStr |
A Tetranuclear Silver-Thiourea Cluster |
title_full_unstemmed |
A Tetranuclear Silver-Thiourea Cluster |
title_sort |
A Tetranuclear Silver-Thiourea Cluster |
author |
Fernandes, José A. [UNESP] |
author_facet |
Fernandes, José A. [UNESP] Segura, Daniel F. Netto, Adelino V. G. Frem, Regina C. G. Mauro, Antonio E. [UNESP] Paz, Filipe A. Almeida [UNESP] |
author_role |
author |
author2 |
Segura, Daniel F. Netto, Adelino V. G. Frem, Regina C. G. Mauro, Antonio E. [UNESP] Paz, Filipe A. Almeida [UNESP] |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
Universidade Estadual Paulista (Unesp) |
dc.contributor.author.fl_str_mv |
Fernandes, José A. [UNESP] Segura, Daniel F. Netto, Adelino V. G. Frem, Regina C. G. Mauro, Antonio E. [UNESP] Paz, Filipe A. Almeida [UNESP] |
dc.subject.por.fl_str_mv |
Silver and thiourea cluster Supramolecular interactions |
topic |
Silver and thiourea cluster Supramolecular interactions |
description |
During the synthesis of the bioactive complex [Ag(phen)(μ-tu)]<inf>2</inf>(NO<inf>3</inf>)<inf>2</inf> (1), some crystals of a new compound were isolated. This crystalline compound, [Ag<inf>4</inf>(μ-tu)<inf>5</inf>(tu)<inf>6</inf>](NO<inf>3</inf>)<inf>4</inf>·7Phen (2) (tu = thiourea, Phen = 1,10-phenanthroline), is a novelty for at least two reasons: (i) it is the first tetranuclear silver and thiourea cluster; (ii) it is the first crystal structure with seven neutral, and uncoordinated, phen molecules. Phen molecules pack forming an infinite column, and the tu ligands form an intricate network of hydrogen bonds with the Phen and nitrate entities. |
publishDate |
2015 |
dc.date.none.fl_str_mv |
2015-09-30 2018-12-11T16:58:40Z 2018-12-11T16:58:40Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1007/s10870-015-0608-9 Journal of Chemical Crystallography, v. 45, n. 8-9, p. 410-418, 2015. 1074-1542 http://hdl.handle.net/11449/172103 10.1007/s10870-015-0608-9 2-s2.0-84942590451 2-s2.0-84942590451.pdf 7927677053650819 8534138813417161 0000-0002-0057-7964 0000-0003-1574-681X |
url |
http://dx.doi.org/10.1007/s10870-015-0608-9 http://hdl.handle.net/11449/172103 |
identifier_str_mv |
Journal of Chemical Crystallography, v. 45, n. 8-9, p. 410-418, 2015. 1074-1542 10.1007/s10870-015-0608-9 2-s2.0-84942590451 2-s2.0-84942590451.pdf 7927677053650819 8534138813417161 0000-0002-0057-7964 0000-0003-1574-681X |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Journal of Chemical Crystallography 0,209 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
410-418 application/pdf |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1808129245154639872 |