Wireless Tags with Hybrid Nanomaterials for Volatile Amine Detection

Detalhes bibliográficos
Autor(a) principal: Andre, Rafaela S.
Data de Publicação: 2021
Outros Autores: Ngo, Quynh P., Fugikawa-Santos, Lucas [UNESP], Correa, Daniel S., Swager, Timothy M.
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1021/acssensors.1c00812
http://hdl.handle.net/11449/221887
Resumo: Quality control in the production and processing of raw meat is currently one of the biggest concerns for food industry and would benefit from portable and wireless sensors capable of detecting the onset of spoilage. Raw meat is a natural source of biogenic and volatile amines as byproducts of decarboxylation reactions, and the levels of these compounds can be utilized as quality control parameters. We report herein a hybrid chemiresistor sensor based on inorganic nanofibers of SiO2:ZnO (an n-type material) and single-walled carbon nanotubes functionalized with 3,5-dinitrophenyls (a p-type material) with dosimetric sensitivity ∼40 times higher for amines than for other volatile organic compounds, which also provides excellent selectivity. The hybrid nanomaterial-based chemiresistor sensory material was used to convert radio-frequency identification tags into chemically actuated resonant devices, which constitute wireless sensors that can be potentially employed in packaging to report on the quality of meat. Specifically, the as-developed wireless tags report on cumulative amine exposure inside the meat package, showing a decrease in radio-frequency signals to the point wherein the sensor ceased to be smartphone-readable. These hybrid material-modified wireless tags offer a path to scalable, affordable, portable, and wireless chemical sensor technology for food quality monitoring without the need to open the packaging.
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spelling Wireless Tags with Hybrid Nanomaterials for Volatile Amine Detectionamine sensingcarbon nanotubesinorganic nanofibersradio-frequency identificationwireless sensingQuality control in the production and processing of raw meat is currently one of the biggest concerns for food industry and would benefit from portable and wireless sensors capable of detecting the onset of spoilage. Raw meat is a natural source of biogenic and volatile amines as byproducts of decarboxylation reactions, and the levels of these compounds can be utilized as quality control parameters. We report herein a hybrid chemiresistor sensor based on inorganic nanofibers of SiO2:ZnO (an n-type material) and single-walled carbon nanotubes functionalized with 3,5-dinitrophenyls (a p-type material) with dosimetric sensitivity ∼40 times higher for amines than for other volatile organic compounds, which also provides excellent selectivity. The hybrid nanomaterial-based chemiresistor sensory material was used to convert radio-frequency identification tags into chemically actuated resonant devices, which constitute wireless sensors that can be potentially employed in packaging to report on the quality of meat. Specifically, the as-developed wireless tags report on cumulative amine exposure inside the meat package, showing a decrease in radio-frequency signals to the point wherein the sensor ceased to be smartphone-readable. These hybrid material-modified wireless tags offer a path to scalable, affordable, portable, and wireless chemical sensor technology for food quality monitoring without the need to open the packaging.Department of Chemistry Institute for Soldier Nanotechnologies Massachusetts Institute of Technology Cambridge, 77 Massachusetts AvenueDepartment of Materials Science and Engineering Massachusetts Institute of Technology Cambridge, 77 Massachusetts AvenueNanotechnology National Laboratory for Agriculture (LNNA) Embrapa Instrumentação, São PauloInstitute of Geosciences and Exact Sciences São Paulo State University (UNESP), São PauloInstitute of Geosciences and Exact Sciences São Paulo State University (UNESP), São PauloCambridgeEmpresa Brasileira de Pesquisa Agropecuária (EMBRAPA)Universidade Estadual Paulista (UNESP)Andre, Rafaela S.Ngo, Quynh P.Fugikawa-Santos, Lucas [UNESP]Correa, Daniel S.Swager, Timothy M.2022-04-28T19:41:05Z2022-04-28T19:41:05Z2021-06-25info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article2457-2464http://dx.doi.org/10.1021/acssensors.1c00812ACS Sensors, v. 6, n. 6, p. 2457-2464, 2021.2379-3694http://hdl.handle.net/11449/22188710.1021/acssensors.1c008122-s2.0-85109024662Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengACS Sensorsinfo:eu-repo/semantics/openAccess2022-04-28T19:41:05Zoai:repositorio.unesp.br:11449/221887Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T19:49:39.345046Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Wireless Tags with Hybrid Nanomaterials for Volatile Amine Detection
title Wireless Tags with Hybrid Nanomaterials for Volatile Amine Detection
spellingShingle Wireless Tags with Hybrid Nanomaterials for Volatile Amine Detection
Andre, Rafaela S.
amine sensing
carbon nanotubes
inorganic nanofibers
radio-frequency identification
wireless sensing
title_short Wireless Tags with Hybrid Nanomaterials for Volatile Amine Detection
title_full Wireless Tags with Hybrid Nanomaterials for Volatile Amine Detection
title_fullStr Wireless Tags with Hybrid Nanomaterials for Volatile Amine Detection
title_full_unstemmed Wireless Tags with Hybrid Nanomaterials for Volatile Amine Detection
title_sort Wireless Tags with Hybrid Nanomaterials for Volatile Amine Detection
author Andre, Rafaela S.
author_facet Andre, Rafaela S.
Ngo, Quynh P.
Fugikawa-Santos, Lucas [UNESP]
Correa, Daniel S.
Swager, Timothy M.
author_role author
author2 Ngo, Quynh P.
Fugikawa-Santos, Lucas [UNESP]
Correa, Daniel S.
Swager, Timothy M.
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Cambridge
Empresa Brasileira de Pesquisa Agropecuária (EMBRAPA)
Universidade Estadual Paulista (UNESP)
dc.contributor.author.fl_str_mv Andre, Rafaela S.
Ngo, Quynh P.
Fugikawa-Santos, Lucas [UNESP]
Correa, Daniel S.
Swager, Timothy M.
dc.subject.por.fl_str_mv amine sensing
carbon nanotubes
inorganic nanofibers
radio-frequency identification
wireless sensing
topic amine sensing
carbon nanotubes
inorganic nanofibers
radio-frequency identification
wireless sensing
description Quality control in the production and processing of raw meat is currently one of the biggest concerns for food industry and would benefit from portable and wireless sensors capable of detecting the onset of spoilage. Raw meat is a natural source of biogenic and volatile amines as byproducts of decarboxylation reactions, and the levels of these compounds can be utilized as quality control parameters. We report herein a hybrid chemiresistor sensor based on inorganic nanofibers of SiO2:ZnO (an n-type material) and single-walled carbon nanotubes functionalized with 3,5-dinitrophenyls (a p-type material) with dosimetric sensitivity ∼40 times higher for amines than for other volatile organic compounds, which also provides excellent selectivity. The hybrid nanomaterial-based chemiresistor sensory material was used to convert radio-frequency identification tags into chemically actuated resonant devices, which constitute wireless sensors that can be potentially employed in packaging to report on the quality of meat. Specifically, the as-developed wireless tags report on cumulative amine exposure inside the meat package, showing a decrease in radio-frequency signals to the point wherein the sensor ceased to be smartphone-readable. These hybrid material-modified wireless tags offer a path to scalable, affordable, portable, and wireless chemical sensor technology for food quality monitoring without the need to open the packaging.
publishDate 2021
dc.date.none.fl_str_mv 2021-06-25
2022-04-28T19:41:05Z
2022-04-28T19:41:05Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1021/acssensors.1c00812
ACS Sensors, v. 6, n. 6, p. 2457-2464, 2021.
2379-3694
http://hdl.handle.net/11449/221887
10.1021/acssensors.1c00812
2-s2.0-85109024662
url http://dx.doi.org/10.1021/acssensors.1c00812
http://hdl.handle.net/11449/221887
identifier_str_mv ACS Sensors, v. 6, n. 6, p. 2457-2464, 2021.
2379-3694
10.1021/acssensors.1c00812
2-s2.0-85109024662
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv ACS Sensors
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 2457-2464
dc.source.none.fl_str_mv Scopus
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
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