The formation of anodic sulfide films on tin electrodes
Autor(a) principal: | |
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Data de Publicação: | 1990 |
Outros Autores: | |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1016/0010-938X(90)90184-7 http://hdl.handle.net/11449/230860 |
Resumo: | The electrodeposition of tin sulfide on polycrystaline tin from alkaline solution has been investigated using cyclic voltammetry. The first anodic peak in the cyclic voltammogram is associated with the deposition of a Sn S monolayer from the adsorption of hydrosulfide on the electrode surface. At more positive potentials there is a second anodic peak related to a SnS2 film over the electrode. The growth of the anodic film has been interpreted by the hopping-motion model for a high field assisted ionic migration process with the rate limiting energy barrier located at the metal/film interface. © 1990. |
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Repositório Institucional da UNESP |
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The formation of anodic sulfide films on tin electrodesanodic filmstin sulfideThe electrodeposition of tin sulfide on polycrystaline tin from alkaline solution has been investigated using cyclic voltammetry. The first anodic peak in the cyclic voltammogram is associated with the deposition of a Sn S monolayer from the adsorption of hydrosulfide on the electrode surface. At more positive potentials there is a second anodic peak related to a SnS2 film over the electrode. The growth of the anodic film has been interpreted by the hopping-motion model for a high field assisted ionic migration process with the rate limiting energy barrier located at the metal/film interface. © 1990.Depto de Química - Universidade Federal de São Carlos Caixa Postal 676 - 13560 - São Carlos - SP - BrasilDepto de Bioquímica e Microbiologia - IB - Campus de Rio Claro UNESP - Rio Claro - SP - BrasilUniversidade Federal de São Carlos (UFSCar)Universidade Estadual Paulista (UNESP)Bidóia, Edério D.de S. Bulhões, Luis Otávio2022-04-29T08:42:24Z2022-04-29T08:42:24Z1990-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article703-708http://dx.doi.org/10.1016/0010-938X(90)90184-7Corrosion Science, v. 31, n. C, p. 703-708, 1990.0010-938Xhttp://hdl.handle.net/11449/23086010.1016/0010-938X(90)90184-72-s2.0-0025645246Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengCorrosion Scienceinfo:eu-repo/semantics/openAccess2022-04-29T08:42:24Zoai:repositorio.unesp.br:11449/230860Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T23:28:13.454482Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
The formation of anodic sulfide films on tin electrodes |
title |
The formation of anodic sulfide films on tin electrodes |
spellingShingle |
The formation of anodic sulfide films on tin electrodes Bidóia, Edério D. anodic films tin sulfide |
title_short |
The formation of anodic sulfide films on tin electrodes |
title_full |
The formation of anodic sulfide films on tin electrodes |
title_fullStr |
The formation of anodic sulfide films on tin electrodes |
title_full_unstemmed |
The formation of anodic sulfide films on tin electrodes |
title_sort |
The formation of anodic sulfide films on tin electrodes |
author |
Bidóia, Edério D. |
author_facet |
Bidóia, Edério D. de S. Bulhões, Luis Otávio |
author_role |
author |
author2 |
de S. Bulhões, Luis Otávio |
author2_role |
author |
dc.contributor.none.fl_str_mv |
Universidade Federal de São Carlos (UFSCar) Universidade Estadual Paulista (UNESP) |
dc.contributor.author.fl_str_mv |
Bidóia, Edério D. de S. Bulhões, Luis Otávio |
dc.subject.por.fl_str_mv |
anodic films tin sulfide |
topic |
anodic films tin sulfide |
description |
The electrodeposition of tin sulfide on polycrystaline tin from alkaline solution has been investigated using cyclic voltammetry. The first anodic peak in the cyclic voltammogram is associated with the deposition of a Sn S monolayer from the adsorption of hydrosulfide on the electrode surface. At more positive potentials there is a second anodic peak related to a SnS2 film over the electrode. The growth of the anodic film has been interpreted by the hopping-motion model for a high field assisted ionic migration process with the rate limiting energy barrier located at the metal/film interface. © 1990. |
publishDate |
1990 |
dc.date.none.fl_str_mv |
1990-01-01 2022-04-29T08:42:24Z 2022-04-29T08:42:24Z |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1016/0010-938X(90)90184-7 Corrosion Science, v. 31, n. C, p. 703-708, 1990. 0010-938X http://hdl.handle.net/11449/230860 10.1016/0010-938X(90)90184-7 2-s2.0-0025645246 |
url |
http://dx.doi.org/10.1016/0010-938X(90)90184-7 http://hdl.handle.net/11449/230860 |
identifier_str_mv |
Corrosion Science, v. 31, n. C, p. 703-708, 1990. 0010-938X 10.1016/0010-938X(90)90184-7 2-s2.0-0025645246 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Corrosion Science |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
703-708 |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1808129523627065344 |