Inorganofunctionalization of Ti(IV) and Zr(IV) on the MCM-41 Surface and its Interaction with a Mixed Valence Complex to use as Isoniazid Sensing
Autor(a) principal: | |
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Data de Publicação: | 2021 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1007/s10904-021-02025-x http://hdl.handle.net/11449/207767 |
Resumo: | In this work, it describes the preparation of Titanium and Zirconium functionalized MCM-41 and subsequent chemical modification with nickel hexacyanoferrate. The obtained materials (MTiNiH and MZrNiH) were characterized by Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), X-ray Dispersive Energy Spectroscopy (EDS), Porosity and Surface Area and Voltammetry Cyclic (VC). The cyclic voltammogram of MTiNiH and MZrNiH modified graphite paste were sensitive to isoniazid concentrations. The MTiNiH modified graphite pulp electrode showed an analytical curve with a linear response of 2.0 × 10–5 to 5.0 × 10–4 mol L−1 and detection limit of 6.12 × 10–6 mol L−1 and MZrNiH modified electrode showed an analytical curve with a linear response of 3.0 × 10–5 to 3.0 × 10–4 mol L−1 and detection limit of 1.66 × 10–5 mol L−1. After catalytic electro-oxidation of isoniazid, a study of the main interferents was performed and the recovery of isoniazid in a synthetic urine sample was also evaluated. The MTiNiH and MZrNiH materials stand out for presenting good detection limit and recovery efficiency in real samples. Therefore, these materials can be considered is a strong candidate for the construction of electrochemical sensors for quick and easy detection of isoniazid. |
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Repositório Institucional da UNESP |
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Inorganofunctionalization of Ti(IV) and Zr(IV) on the MCM-41 Surface and its Interaction with a Mixed Valence Complex to use as Isoniazid SensingCyclic voltammetryIsoniazidMesoporous silicaNickel hexacyanoferrateIn this work, it describes the preparation of Titanium and Zirconium functionalized MCM-41 and subsequent chemical modification with nickel hexacyanoferrate. The obtained materials (MTiNiH and MZrNiH) were characterized by Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), X-ray Dispersive Energy Spectroscopy (EDS), Porosity and Surface Area and Voltammetry Cyclic (VC). The cyclic voltammogram of MTiNiH and MZrNiH modified graphite paste were sensitive to isoniazid concentrations. The MTiNiH modified graphite pulp electrode showed an analytical curve with a linear response of 2.0 × 10–5 to 5.0 × 10–4 mol L−1 and detection limit of 6.12 × 10–6 mol L−1 and MZrNiH modified electrode showed an analytical curve with a linear response of 3.0 × 10–5 to 3.0 × 10–4 mol L−1 and detection limit of 1.66 × 10–5 mol L−1. After catalytic electro-oxidation of isoniazid, a study of the main interferents was performed and the recovery of isoniazid in a synthetic urine sample was also evaluated. The MTiNiH and MZrNiH materials stand out for presenting good detection limit and recovery efficiency in real samples. Therefore, these materials can be considered is a strong candidate for the construction of electrochemical sensors for quick and easy detection of isoniazid.Department of Physics and Chemistry Faculty of Engineering of Ilha Solteira São Paulo State University “Júlio de Mesquita Filho”–UNESP, Av. Brasil, 56Department of Chemistry Faculty of Philosophy Sciences and Letters of Ribeirão Preto University of São Paulo Ribeirão Preto–USP, Av. BandeirantesDepartment of Physics Institute of Geosciences and Exact Sciences São Paulo State University “Júlio de Mesquita Filho”–UNESP, Av. 24-ADepartment of Physics and Chemistry Faculty of Engineering of Ilha Solteira São Paulo State University “Júlio de Mesquita Filho”–UNESP, Av. Brasil, 56Department of Physics Institute of Geosciences and Exact Sciences São Paulo State University “Júlio de Mesquita Filho”–UNESP, Av. 24-AUniversidade Estadual Paulista (Unesp)Universidade de São Paulo (USP)de Souza Magossi, Maiara [UNESP]Fernandes, Daniela Silvestrini [UNESP]dos Santos Franco, Fernanda [UNESP]dos Santos Felipe, Alexsandro [UNESP]de Vicente, Fábio Simões [UNESP]do Carmo, Devaney Ribeiro [UNESP]2021-06-25T11:00:43Z2021-06-25T11:00:43Z2021-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://dx.doi.org/10.1007/s10904-021-02025-xJournal of Inorganic and Organometallic Polymers and Materials.1574-14511574-1443http://hdl.handle.net/11449/20776710.1007/s10904-021-02025-x2-s2.0-85106408682Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of Inorganic and Organometallic Polymers and Materialsinfo:eu-repo/semantics/openAccess2024-07-10T14:07:29Zoai:repositorio.unesp.br:11449/207767Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T16:27:09.368930Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Inorganofunctionalization of Ti(IV) and Zr(IV) on the MCM-41 Surface and its Interaction with a Mixed Valence Complex to use as Isoniazid Sensing |
title |
Inorganofunctionalization of Ti(IV) and Zr(IV) on the MCM-41 Surface and its Interaction with a Mixed Valence Complex to use as Isoniazid Sensing |
spellingShingle |
Inorganofunctionalization of Ti(IV) and Zr(IV) on the MCM-41 Surface and its Interaction with a Mixed Valence Complex to use as Isoniazid Sensing de Souza Magossi, Maiara [UNESP] Cyclic voltammetry Isoniazid Mesoporous silica Nickel hexacyanoferrate |
title_short |
Inorganofunctionalization of Ti(IV) and Zr(IV) on the MCM-41 Surface and its Interaction with a Mixed Valence Complex to use as Isoniazid Sensing |
title_full |
Inorganofunctionalization of Ti(IV) and Zr(IV) on the MCM-41 Surface and its Interaction with a Mixed Valence Complex to use as Isoniazid Sensing |
title_fullStr |
Inorganofunctionalization of Ti(IV) and Zr(IV) on the MCM-41 Surface and its Interaction with a Mixed Valence Complex to use as Isoniazid Sensing |
title_full_unstemmed |
Inorganofunctionalization of Ti(IV) and Zr(IV) on the MCM-41 Surface and its Interaction with a Mixed Valence Complex to use as Isoniazid Sensing |
title_sort |
Inorganofunctionalization of Ti(IV) and Zr(IV) on the MCM-41 Surface and its Interaction with a Mixed Valence Complex to use as Isoniazid Sensing |
author |
de Souza Magossi, Maiara [UNESP] |
author_facet |
de Souza Magossi, Maiara [UNESP] Fernandes, Daniela Silvestrini [UNESP] dos Santos Franco, Fernanda [UNESP] dos Santos Felipe, Alexsandro [UNESP] de Vicente, Fábio Simões [UNESP] do Carmo, Devaney Ribeiro [UNESP] |
author_role |
author |
author2 |
Fernandes, Daniela Silvestrini [UNESP] dos Santos Franco, Fernanda [UNESP] dos Santos Felipe, Alexsandro [UNESP] de Vicente, Fábio Simões [UNESP] do Carmo, Devaney Ribeiro [UNESP] |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
Universidade Estadual Paulista (Unesp) Universidade de São Paulo (USP) |
dc.contributor.author.fl_str_mv |
de Souza Magossi, Maiara [UNESP] Fernandes, Daniela Silvestrini [UNESP] dos Santos Franco, Fernanda [UNESP] dos Santos Felipe, Alexsandro [UNESP] de Vicente, Fábio Simões [UNESP] do Carmo, Devaney Ribeiro [UNESP] |
dc.subject.por.fl_str_mv |
Cyclic voltammetry Isoniazid Mesoporous silica Nickel hexacyanoferrate |
topic |
Cyclic voltammetry Isoniazid Mesoporous silica Nickel hexacyanoferrate |
description |
In this work, it describes the preparation of Titanium and Zirconium functionalized MCM-41 and subsequent chemical modification with nickel hexacyanoferrate. The obtained materials (MTiNiH and MZrNiH) were characterized by Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), X-ray Dispersive Energy Spectroscopy (EDS), Porosity and Surface Area and Voltammetry Cyclic (VC). The cyclic voltammogram of MTiNiH and MZrNiH modified graphite paste were sensitive to isoniazid concentrations. The MTiNiH modified graphite pulp electrode showed an analytical curve with a linear response of 2.0 × 10–5 to 5.0 × 10–4 mol L−1 and detection limit of 6.12 × 10–6 mol L−1 and MZrNiH modified electrode showed an analytical curve with a linear response of 3.0 × 10–5 to 3.0 × 10–4 mol L−1 and detection limit of 1.66 × 10–5 mol L−1. After catalytic electro-oxidation of isoniazid, a study of the main interferents was performed and the recovery of isoniazid in a synthetic urine sample was also evaluated. The MTiNiH and MZrNiH materials stand out for presenting good detection limit and recovery efficiency in real samples. Therefore, these materials can be considered is a strong candidate for the construction of electrochemical sensors for quick and easy detection of isoniazid. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-06-25T11:00:43Z 2021-06-25T11:00:43Z 2021-01-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1007/s10904-021-02025-x Journal of Inorganic and Organometallic Polymers and Materials. 1574-1451 1574-1443 http://hdl.handle.net/11449/207767 10.1007/s10904-021-02025-x 2-s2.0-85106408682 |
url |
http://dx.doi.org/10.1007/s10904-021-02025-x http://hdl.handle.net/11449/207767 |
identifier_str_mv |
Journal of Inorganic and Organometallic Polymers and Materials. 1574-1451 1574-1443 10.1007/s10904-021-02025-x 2-s2.0-85106408682 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Journal of Inorganic and Organometallic Polymers and Materials |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1808128654174060544 |