Evaluation of the phenyl-bonded silica-based sorbent for pre-concentration of the booster antifouling biocides zinc pyrithione, zineb and ziram using solid-phase extraction technique and inductively coupled plasma mass spectrometry

Detalhes bibliográficos
Autor(a) principal: Rolisola, Ana Marta Cavinato Marchini [UNESP]
Data de Publicação: 2020
Outros Autores: Menegário, Amauri Antônio [UNESP], Yabuki, Lauren Nozomi Marques [UNESP], Polese, Luciana [UNESP], Kiang, Chang Hung [UNESP]
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.26850/1678-4618EQJ.V45.4.2020.P21-31
http://hdl.handle.net/11449/208102
Resumo: A robust method of solid-phase extraction technique with use of the phenyl-bonded silica-based sorbent (Si-PH sorbent) for pre-concentration of three booster antifouling biocides: Zinc pyrithione, Zineb and Ziram in ultrapure water fortified and estuarine water sample was evaluated for zinc determination by collision cell technology-inductively coupled plasma-mass spectrometry (CCT-ICP-MS). Decontamination process to remove metals and prevent (trans-) metallization of the Si-PH sorbent with 20 mL of nitric acid 0.006 mol L-1 was performed. This proposed solid-phase extraction efficiency of three booster antifouling biocides by the phenyl-bonded silica-based sorbent (Si-PH sorbent) was evaluated in 40 mL of ultrapure water fortified sample (40 μg L-1 of the zinc biocides). The adsorption of zinc pyrithione, Zineb and Ziram were 94.2 ± 0.1%, 85.13 ± 0.04% and 93.35 ± 0.09%, respectively. The limit of detection and limit of quantification values obtained were 0.66 μg L-1 and 2.19 μg L-1, respectively. Good recoveries of zinc pyrithione (85 ± 2%), Zineb (89 ± 5%) and Ziram (111 ± 2%) in the elution step for booster antifouling biocides from the fortified estuarine water were obtained.
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spelling Evaluation of the phenyl-bonded silica-based sorbent for pre-concentration of the booster antifouling biocides zinc pyrithione, zineb and ziram using solid-phase extraction technique and inductively coupled plasma mass spectrometryA robust method of solid-phase extraction technique with use of the phenyl-bonded silica-based sorbent (Si-PH sorbent) for pre-concentration of three booster antifouling biocides: Zinc pyrithione, Zineb and Ziram in ultrapure water fortified and estuarine water sample was evaluated for zinc determination by collision cell technology-inductively coupled plasma-mass spectrometry (CCT-ICP-MS). Decontamination process to remove metals and prevent (trans-) metallization of the Si-PH sorbent with 20 mL of nitric acid 0.006 mol L-1 was performed. This proposed solid-phase extraction efficiency of three booster antifouling biocides by the phenyl-bonded silica-based sorbent (Si-PH sorbent) was evaluated in 40 mL of ultrapure water fortified sample (40 μg L-1 of the zinc biocides). The adsorption of zinc pyrithione, Zineb and Ziram were 94.2 ± 0.1%, 85.13 ± 0.04% and 93.35 ± 0.09%, respectively. The limit of detection and limit of quantification values obtained were 0.66 μg L-1 and 2.19 μg L-1, respectively. Good recoveries of zinc pyrithione (85 ± 2%), Zineb (89 ± 5%) and Ziram (111 ± 2%) in the elution step for booster antifouling biocides from the fortified estuarine water were obtained.São Paulo State University (Unesp) Enviromental Studies CenterSão Paulo State University (Unesp) Institute of Geosciences and Exact SciencesSão Paulo State University (Unesp) Enviromental Studies CenterSão Paulo State University (Unesp) Institute of Geosciences and Exact SciencesUniversidade Estadual Paulista (Unesp)Rolisola, Ana Marta Cavinato Marchini [UNESP]Menegário, Amauri Antônio [UNESP]Yabuki, Lauren Nozomi Marques [UNESP]Polese, Luciana [UNESP]Kiang, Chang Hung [UNESP]2021-06-25T11:06:22Z2021-06-25T11:06:22Z2020-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article21-31http://dx.doi.org/10.26850/1678-4618EQJ.V45.4.2020.P21-31Ecletica Quimica, v. 45, n. 4, p. 21-31, 2020.1678-46180100-4670http://hdl.handle.net/11449/20810210.26850/1678-4618EQJ.V45.4.2020.P21-312-s2.0-850949492741989662459244838Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengEcletica Quimicainfo:eu-repo/semantics/openAccess2024-04-10T19:22:25Zoai:repositorio.unesp.br:11449/208102Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T18:45:38.488634Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Evaluation of the phenyl-bonded silica-based sorbent for pre-concentration of the booster antifouling biocides zinc pyrithione, zineb and ziram using solid-phase extraction technique and inductively coupled plasma mass spectrometry
title Evaluation of the phenyl-bonded silica-based sorbent for pre-concentration of the booster antifouling biocides zinc pyrithione, zineb and ziram using solid-phase extraction technique and inductively coupled plasma mass spectrometry
spellingShingle Evaluation of the phenyl-bonded silica-based sorbent for pre-concentration of the booster antifouling biocides zinc pyrithione, zineb and ziram using solid-phase extraction technique and inductively coupled plasma mass spectrometry
Rolisola, Ana Marta Cavinato Marchini [UNESP]
title_short Evaluation of the phenyl-bonded silica-based sorbent for pre-concentration of the booster antifouling biocides zinc pyrithione, zineb and ziram using solid-phase extraction technique and inductively coupled plasma mass spectrometry
title_full Evaluation of the phenyl-bonded silica-based sorbent for pre-concentration of the booster antifouling biocides zinc pyrithione, zineb and ziram using solid-phase extraction technique and inductively coupled plasma mass spectrometry
title_fullStr Evaluation of the phenyl-bonded silica-based sorbent for pre-concentration of the booster antifouling biocides zinc pyrithione, zineb and ziram using solid-phase extraction technique and inductively coupled plasma mass spectrometry
title_full_unstemmed Evaluation of the phenyl-bonded silica-based sorbent for pre-concentration of the booster antifouling biocides zinc pyrithione, zineb and ziram using solid-phase extraction technique and inductively coupled plasma mass spectrometry
title_sort Evaluation of the phenyl-bonded silica-based sorbent for pre-concentration of the booster antifouling biocides zinc pyrithione, zineb and ziram using solid-phase extraction technique and inductively coupled plasma mass spectrometry
author Rolisola, Ana Marta Cavinato Marchini [UNESP]
author_facet Rolisola, Ana Marta Cavinato Marchini [UNESP]
Menegário, Amauri Antônio [UNESP]
Yabuki, Lauren Nozomi Marques [UNESP]
Polese, Luciana [UNESP]
Kiang, Chang Hung [UNESP]
author_role author
author2 Menegário, Amauri Antônio [UNESP]
Yabuki, Lauren Nozomi Marques [UNESP]
Polese, Luciana [UNESP]
Kiang, Chang Hung [UNESP]
author2_role author
author
author
author
dc.contributor.none.fl_str_mv Universidade Estadual Paulista (Unesp)
dc.contributor.author.fl_str_mv Rolisola, Ana Marta Cavinato Marchini [UNESP]
Menegário, Amauri Antônio [UNESP]
Yabuki, Lauren Nozomi Marques [UNESP]
Polese, Luciana [UNESP]
Kiang, Chang Hung [UNESP]
description A robust method of solid-phase extraction technique with use of the phenyl-bonded silica-based sorbent (Si-PH sorbent) for pre-concentration of three booster antifouling biocides: Zinc pyrithione, Zineb and Ziram in ultrapure water fortified and estuarine water sample was evaluated for zinc determination by collision cell technology-inductively coupled plasma-mass spectrometry (CCT-ICP-MS). Decontamination process to remove metals and prevent (trans-) metallization of the Si-PH sorbent with 20 mL of nitric acid 0.006 mol L-1 was performed. This proposed solid-phase extraction efficiency of three booster antifouling biocides by the phenyl-bonded silica-based sorbent (Si-PH sorbent) was evaluated in 40 mL of ultrapure water fortified sample (40 μg L-1 of the zinc biocides). The adsorption of zinc pyrithione, Zineb and Ziram were 94.2 ± 0.1%, 85.13 ± 0.04% and 93.35 ± 0.09%, respectively. The limit of detection and limit of quantification values obtained were 0.66 μg L-1 and 2.19 μg L-1, respectively. Good recoveries of zinc pyrithione (85 ± 2%), Zineb (89 ± 5%) and Ziram (111 ± 2%) in the elution step for booster antifouling biocides from the fortified estuarine water were obtained.
publishDate 2020
dc.date.none.fl_str_mv 2020-01-01
2021-06-25T11:06:22Z
2021-06-25T11:06:22Z
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.26850/1678-4618EQJ.V45.4.2020.P21-31
Ecletica Quimica, v. 45, n. 4, p. 21-31, 2020.
1678-4618
0100-4670
http://hdl.handle.net/11449/208102
10.26850/1678-4618EQJ.V45.4.2020.P21-31
2-s2.0-85094949274
1989662459244838
url http://dx.doi.org/10.26850/1678-4618EQJ.V45.4.2020.P21-31
http://hdl.handle.net/11449/208102
identifier_str_mv Ecletica Quimica, v. 45, n. 4, p. 21-31, 2020.
1678-4618
0100-4670
10.26850/1678-4618EQJ.V45.4.2020.P21-31
2-s2.0-85094949274
1989662459244838
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Ecletica Quimica
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv 21-31
dc.source.none.fl_str_mv Scopus
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
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