Accelerated microwave-assisted hydrothermal/solvothermal processing: Fundamentals, morphologies, and applications
Autor(a) principal: | |
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Data de Publicação: | 2018 |
Outros Autores: | , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1007/s10832-018-0128-z http://hdl.handle.net/11449/170780 |
Resumo: | This article is designed to serve as a roadmap for understanding the fundamentals, the key advantages and the potential applications of microwave-assisted hydrothermal/solvothermal (MAH/S) processing. MAH/S synthesis is a versatile chemical method for preparing a diversity of materials such as metals, semiconductors, electroceramics, graphene and their composites as bulk powders, thin films, or single crystals. The key to improve performance of these materials is achieving controlled morphologies (0 to 3D dimensionality) that favor desirable physical-chemical phenomena at the surface, and in the bulk of these advanced materials. The main features related to the improvement of the thermal and non-thermal effects associated with the use of microwave power concurrently with hydrothermal or solvothermal methods are discussed. Furthermore, the main crystal growth mechanisms (Ostwald ripening and oriented attachment) of these solids in solution under MAH/S treatment are described. Products synthesized by the MAH/S, particularly of interest in the development of gas sensors, batteries, fuel cells, solar cells and photocatalysts are emphasized. We conclude by envisaging new future directions for the use of this rapid and versatile processing approach. |
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Accelerated microwave-assisted hydrothermal/solvothermal processing: Fundamentals, morphologies, and applicationsCompositesCrystal growthGrapheneMetal oxidesMicrowaveNanostructuresThis article is designed to serve as a roadmap for understanding the fundamentals, the key advantages and the potential applications of microwave-assisted hydrothermal/solvothermal (MAH/S) processing. MAH/S synthesis is a versatile chemical method for preparing a diversity of materials such as metals, semiconductors, electroceramics, graphene and their composites as bulk powders, thin films, or single crystals. The key to improve performance of these materials is achieving controlled morphologies (0 to 3D dimensionality) that favor desirable physical-chemical phenomena at the surface, and in the bulk of these advanced materials. The main features related to the improvement of the thermal and non-thermal effects associated with the use of microwave power concurrently with hydrothermal or solvothermal methods are discussed. Furthermore, the main crystal growth mechanisms (Ostwald ripening and oriented attachment) of these solids in solution under MAH/S treatment are described. Products synthesized by the MAH/S, particularly of interest in the development of gas sensors, batteries, fuel cells, solar cells and photocatalysts are emphasized. We conclude by envisaging new future directions for the use of this rapid and versatile processing approach.Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Laboratory of Materials for Sustainability IBILCE São Paulo State Univeristy – UNESPInterdisciplinary Laboratory of Ceramics IQ São Paulo State University – UNESPLaboratory of Materials for Sustainability IBILCE São Paulo State Univeristy – UNESPInterdisciplinary Laboratory of Ceramics IQ São Paulo State University – UNESPFAPESP: 2014/17343-0FAPESP: 2015/05916-9FAPESP: 2015/50526-4Universidade Estadual Paulista (Unesp)Zito, Cecilia A. [UNESP]Orlandi, Marcelo O. [UNESP]Volanti, Diogo P. [UNESP]2018-12-11T16:52:23Z2018-12-11T16:52:23Z2018-06-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/article271-292application/pdfhttp://dx.doi.org/10.1007/s10832-018-0128-zJournal of Electroceramics, v. 40, n. 4, p. 271-292, 2018.1573-86631385-3449http://hdl.handle.net/11449/17078010.1007/s10832-018-0128-z2-s2.0-850437164762-s2.0-85043716476.pdf23547399804067250000-0001-9315-9392Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of Electroceramics0,4270,427info:eu-repo/semantics/openAccess2023-11-27T06:16:32Zoai:repositorio.unesp.br:11449/170780Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T18:53:10.791324Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Accelerated microwave-assisted hydrothermal/solvothermal processing: Fundamentals, morphologies, and applications |
title |
Accelerated microwave-assisted hydrothermal/solvothermal processing: Fundamentals, morphologies, and applications |
spellingShingle |
Accelerated microwave-assisted hydrothermal/solvothermal processing: Fundamentals, morphologies, and applications Zito, Cecilia A. [UNESP] Composites Crystal growth Graphene Metal oxides Microwave Nanostructures |
title_short |
Accelerated microwave-assisted hydrothermal/solvothermal processing: Fundamentals, morphologies, and applications |
title_full |
Accelerated microwave-assisted hydrothermal/solvothermal processing: Fundamentals, morphologies, and applications |
title_fullStr |
Accelerated microwave-assisted hydrothermal/solvothermal processing: Fundamentals, morphologies, and applications |
title_full_unstemmed |
Accelerated microwave-assisted hydrothermal/solvothermal processing: Fundamentals, morphologies, and applications |
title_sort |
Accelerated microwave-assisted hydrothermal/solvothermal processing: Fundamentals, morphologies, and applications |
author |
Zito, Cecilia A. [UNESP] |
author_facet |
Zito, Cecilia A. [UNESP] Orlandi, Marcelo O. [UNESP] Volanti, Diogo P. [UNESP] |
author_role |
author |
author2 |
Orlandi, Marcelo O. [UNESP] Volanti, Diogo P. [UNESP] |
author2_role |
author author |
dc.contributor.none.fl_str_mv |
Universidade Estadual Paulista (Unesp) |
dc.contributor.author.fl_str_mv |
Zito, Cecilia A. [UNESP] Orlandi, Marcelo O. [UNESP] Volanti, Diogo P. [UNESP] |
dc.subject.por.fl_str_mv |
Composites Crystal growth Graphene Metal oxides Microwave Nanostructures |
topic |
Composites Crystal growth Graphene Metal oxides Microwave Nanostructures |
description |
This article is designed to serve as a roadmap for understanding the fundamentals, the key advantages and the potential applications of microwave-assisted hydrothermal/solvothermal (MAH/S) processing. MAH/S synthesis is a versatile chemical method for preparing a diversity of materials such as metals, semiconductors, electroceramics, graphene and their composites as bulk powders, thin films, or single crystals. The key to improve performance of these materials is achieving controlled morphologies (0 to 3D dimensionality) that favor desirable physical-chemical phenomena at the surface, and in the bulk of these advanced materials. The main features related to the improvement of the thermal and non-thermal effects associated with the use of microwave power concurrently with hydrothermal or solvothermal methods are discussed. Furthermore, the main crystal growth mechanisms (Ostwald ripening and oriented attachment) of these solids in solution under MAH/S treatment are described. Products synthesized by the MAH/S, particularly of interest in the development of gas sensors, batteries, fuel cells, solar cells and photocatalysts are emphasized. We conclude by envisaging new future directions for the use of this rapid and versatile processing approach. |
publishDate |
2018 |
dc.date.none.fl_str_mv |
2018-12-11T16:52:23Z 2018-12-11T16:52:23Z 2018-06-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1007/s10832-018-0128-z Journal of Electroceramics, v. 40, n. 4, p. 271-292, 2018. 1573-8663 1385-3449 http://hdl.handle.net/11449/170780 10.1007/s10832-018-0128-z 2-s2.0-85043716476 2-s2.0-85043716476.pdf 2354739980406725 0000-0001-9315-9392 |
url |
http://dx.doi.org/10.1007/s10832-018-0128-z http://hdl.handle.net/11449/170780 |
identifier_str_mv |
Journal of Electroceramics, v. 40, n. 4, p. 271-292, 2018. 1573-8663 1385-3449 10.1007/s10832-018-0128-z 2-s2.0-85043716476 2-s2.0-85043716476.pdf 2354739980406725 0000-0001-9315-9392 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Journal of Electroceramics 0,427 0,427 |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.format.none.fl_str_mv |
271-292 application/pdf |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1808128994706456576 |