Detection of H2facilitated by ionic liquid gating of tungsten oxide films

Detalhes bibliográficos
Autor(a) principal: Barbosa, Martin S. [UNESP]
Data de Publicação: 2022
Outros Autores: Da Silva, Ranilson A. [UNESP], Santato, Clara, Orlandi, Marcelo O. [UNESP]
Tipo de documento: Artigo
Idioma: eng
Título da fonte: Repositório Institucional da UNESP
Texto Completo: http://dx.doi.org/10.1116/6.0001405
http://hdl.handle.net/11449/222998
Resumo: Molecular hydrogen (H2) shows promise as a future renewable energy carrier. However, due to safety concerns, its reliable detection in different atmospheres is an important issue. Here, we propose a hydrogen sensor based on ion-gated transistors exploiting the interface between tungsten oxide and ionic liquids. Two different approaches to gas sensors (metal oxide gas sensor and ionic liquid-based electrochemical sensor) are integrated in a single device. We demonstrate that ionic liquid gating enhances the effect of H2 on the tungsten oxide transistor channel. The transistor current response permits the detection of H2 in an O2-free environment with the device operating in room temperature. After H2 sensing, the initial properties of the tungsten oxide channel can be recovered by exposure to O2.
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spelling Detection of H2facilitated by ionic liquid gating of tungsten oxide filmsMolecular hydrogen (H2) shows promise as a future renewable energy carrier. However, due to safety concerns, its reliable detection in different atmospheres is an important issue. Here, we propose a hydrogen sensor based on ion-gated transistors exploiting the interface between tungsten oxide and ionic liquids. Two different approaches to gas sensors (metal oxide gas sensor and ionic liquid-based electrochemical sensor) are integrated in a single device. We demonstrate that ionic liquid gating enhances the effect of H2 on the tungsten oxide transistor channel. The transistor current response permits the detection of H2 in an O2-free environment with the device operating in room temperature. After H2 sensing, the initial properties of the tungsten oxide channel can be recovered by exposure to O2.Instituto de Química Universidade Federal de Goiás (UFG), Av. Esperança, s/n - Chácaras de Recreio Samambaia, GoiâniaDepartamento de Física Engenharia e Matemática São Paulo State University (UNESP), Rua Professor Degni, 55Département de Génie Physique Polytechnique Montréal, C.P. 6079, Succ. Centre-VilleDepartamento de Física Engenharia e Matemática São Paulo State University (UNESP), Rua Professor Degni, 55Universidade Federal de Goiás (UFG)Universidade Estadual Paulista (UNESP)Polytechnique MontréalBarbosa, Martin S. [UNESP]Da Silva, Ranilson A. [UNESP]Santato, ClaraOrlandi, Marcelo O. [UNESP]2022-04-28T19:47:56Z2022-04-28T19:47:56Z2022-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://dx.doi.org/10.1116/6.0001405Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films, v. 40, n. 1, 2022.1520-85590734-2101http://hdl.handle.net/11449/22299810.1116/6.00014052-s2.0-85120733400Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengJournal of Vacuum Science and Technology A: Vacuum, Surfaces and Filmsinfo:eu-repo/semantics/openAccess2022-04-28T19:47:56Zoai:repositorio.unesp.br:11449/222998Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462022-04-28T19:47:56Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false
dc.title.none.fl_str_mv Detection of H2facilitated by ionic liquid gating of tungsten oxide films
title Detection of H2facilitated by ionic liquid gating of tungsten oxide films
spellingShingle Detection of H2facilitated by ionic liquid gating of tungsten oxide films
Barbosa, Martin S. [UNESP]
title_short Detection of H2facilitated by ionic liquid gating of tungsten oxide films
title_full Detection of H2facilitated by ionic liquid gating of tungsten oxide films
title_fullStr Detection of H2facilitated by ionic liquid gating of tungsten oxide films
title_full_unstemmed Detection of H2facilitated by ionic liquid gating of tungsten oxide films
title_sort Detection of H2facilitated by ionic liquid gating of tungsten oxide films
author Barbosa, Martin S. [UNESP]
author_facet Barbosa, Martin S. [UNESP]
Da Silva, Ranilson A. [UNESP]
Santato, Clara
Orlandi, Marcelo O. [UNESP]
author_role author
author2 Da Silva, Ranilson A. [UNESP]
Santato, Clara
Orlandi, Marcelo O. [UNESP]
author2_role author
author
author
dc.contributor.none.fl_str_mv Universidade Federal de Goiás (UFG)
Universidade Estadual Paulista (UNESP)
Polytechnique Montréal
dc.contributor.author.fl_str_mv Barbosa, Martin S. [UNESP]
Da Silva, Ranilson A. [UNESP]
Santato, Clara
Orlandi, Marcelo O. [UNESP]
description Molecular hydrogen (H2) shows promise as a future renewable energy carrier. However, due to safety concerns, its reliable detection in different atmospheres is an important issue. Here, we propose a hydrogen sensor based on ion-gated transistors exploiting the interface between tungsten oxide and ionic liquids. Two different approaches to gas sensors (metal oxide gas sensor and ionic liquid-based electrochemical sensor) are integrated in a single device. We demonstrate that ionic liquid gating enhances the effect of H2 on the tungsten oxide transistor channel. The transistor current response permits the detection of H2 in an O2-free environment with the device operating in room temperature. After H2 sensing, the initial properties of the tungsten oxide channel can be recovered by exposure to O2.
publishDate 2022
dc.date.none.fl_str_mv 2022-04-28T19:47:56Z
2022-04-28T19:47:56Z
2022-01-01
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/article
format article
status_str publishedVersion
dc.identifier.uri.fl_str_mv http://dx.doi.org/10.1116/6.0001405
Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films, v. 40, n. 1, 2022.
1520-8559
0734-2101
http://hdl.handle.net/11449/222998
10.1116/6.0001405
2-s2.0-85120733400
url http://dx.doi.org/10.1116/6.0001405
http://hdl.handle.net/11449/222998
identifier_str_mv Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films, v. 40, n. 1, 2022.
1520-8559
0734-2101
10.1116/6.0001405
2-s2.0-85120733400
dc.language.iso.fl_str_mv eng
language eng
dc.relation.none.fl_str_mv Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.source.none.fl_str_mv Scopus
reponame:Repositório Institucional da UNESP
instname:Universidade Estadual Paulista (UNESP)
instacron:UNESP
instname_str Universidade Estadual Paulista (UNESP)
instacron_str UNESP
institution UNESP
reponame_str Repositório Institucional da UNESP
collection Repositório Institucional da UNESP
repository.name.fl_str_mv Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)
repository.mail.fl_str_mv
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