Identification of organic contaminants in vinasse and in soil and groundwater from fertigated sugarcane crop areas using target and suspect screening strategies
Autor(a) principal: | |
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Data de Publicação: | 2021 |
Outros Autores: | , , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.1016/j.scitotenv.2020.143237 http://hdl.handle.net/11449/208125 |
Resumo: | This work evaluated for the first time the sustainability of vinasse reuse as a fertilizer in sugarcane crops by assessing the occurrence of organic contaminants and their potential for dissemination to soils and groundwater in fertigated areas. A comprehensive screening of organic contaminants was performed in vinasse, soil and groundwater using target analysis, to investigate the occurrence of multiple-class antibiotics, in combination with suspect screening using NORMAN Digital Sample Freezing Platform. Even though antibiotics are used in the ethanol production process and were expected to be ubiquitous contaminants, they were not detected in any of the samples. Nevertheless, the HRMS-based wide-scope suspect screening (including >7800 substances such as pharmaceuticals, agrochemicals, preservatives and industrial chemicals) allowed the tentative identification of 56 compounds, mostly pesticides, food additives, industrial and naturally occurring substances. Results showed no overlap between the compounds detected in vinasse and environmental samples, suggesting that the pollutants found in soil and groundwater might come from alternative sources other than vinasse reuse. |
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Identification of organic contaminants in vinasse and in soil and groundwater from fertigated sugarcane crop areas using target and suspect screening strategiesAntibioticsNORMAN Digital Sample Freezing PlatformOrganic contaminantsSoil amendmentSuspect screeningVinasse fertigationThis work evaluated for the first time the sustainability of vinasse reuse as a fertilizer in sugarcane crops by assessing the occurrence of organic contaminants and their potential for dissemination to soils and groundwater in fertigated areas. A comprehensive screening of organic contaminants was performed in vinasse, soil and groundwater using target analysis, to investigate the occurrence of multiple-class antibiotics, in combination with suspect screening using NORMAN Digital Sample Freezing Platform. Even though antibiotics are used in the ethanol production process and were expected to be ubiquitous contaminants, they were not detected in any of the samples. Nevertheless, the HRMS-based wide-scope suspect screening (including >7800 substances such as pharmaceuticals, agrochemicals, preservatives and industrial chemicals) allowed the tentative identification of 56 compounds, mostly pesticides, food additives, industrial and naturally occurring substances. Results showed no overlap between the compounds detected in vinasse and environmental samples, suggesting that the pollutants found in soil and groundwater might come from alternative sources other than vinasse reuse.Centres de Recerca de CatalunyaFundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Generalitat de CatalunyaSão Paulo State University (Unesp) Institute of ChemistrySão Paulo State University (Unesp) Bioenergy Research Institute (IPBEN)Catalan Institution for Research and Advanced Studies (ICREA)Catalan Institute for Water Research (ICRA), Emili Grahit 101University of GironaSão Paulo State University (Unesp) Institute of ChemistrySão Paulo State University (Unesp) Bioenergy Research Institute (IPBEN)FAPESP: 2016/06352-4FAPESP: 2018/15739-5Generalitat de Catalunya: SGR ICRA-ENV 2017 1124Universidade Estadual Paulista (Unesp)Catalan Institution for Research and Advanced Studies (ICREA)Catalan Institute for Water Research (ICRA)University of Gironada Silva, Josiel José [UNESP]da Silva, Bianca Ferreira [UNESP]Stradiotto, Nelson Ramos [UNESP]Petrović, MiraGros, MeritxellGago-Ferrero, Pablo2021-06-25T11:06:44Z2021-06-25T11:06:44Z2021-03-20info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://dx.doi.org/10.1016/j.scitotenv.2020.143237Science of the Total Environment, v. 761.1879-10260048-9697http://hdl.handle.net/11449/20812510.1016/j.scitotenv.2020.1432372-s2.0-85095833287Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengScience of the Total Environmentinfo:eu-repo/semantics/openAccess2021-10-23T18:56:44Zoai:repositorio.unesp.br:11449/208125Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T22:24:41.291139Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Identification of organic contaminants in vinasse and in soil and groundwater from fertigated sugarcane crop areas using target and suspect screening strategies |
title |
Identification of organic contaminants in vinasse and in soil and groundwater from fertigated sugarcane crop areas using target and suspect screening strategies |
spellingShingle |
Identification of organic contaminants in vinasse and in soil and groundwater from fertigated sugarcane crop areas using target and suspect screening strategies da Silva, Josiel José [UNESP] Antibiotics NORMAN Digital Sample Freezing Platform Organic contaminants Soil amendment Suspect screening Vinasse fertigation |
title_short |
Identification of organic contaminants in vinasse and in soil and groundwater from fertigated sugarcane crop areas using target and suspect screening strategies |
title_full |
Identification of organic contaminants in vinasse and in soil and groundwater from fertigated sugarcane crop areas using target and suspect screening strategies |
title_fullStr |
Identification of organic contaminants in vinasse and in soil and groundwater from fertigated sugarcane crop areas using target and suspect screening strategies |
title_full_unstemmed |
Identification of organic contaminants in vinasse and in soil and groundwater from fertigated sugarcane crop areas using target and suspect screening strategies |
title_sort |
Identification of organic contaminants in vinasse and in soil and groundwater from fertigated sugarcane crop areas using target and suspect screening strategies |
author |
da Silva, Josiel José [UNESP] |
author_facet |
da Silva, Josiel José [UNESP] da Silva, Bianca Ferreira [UNESP] Stradiotto, Nelson Ramos [UNESP] Petrović, Mira Gros, Meritxell Gago-Ferrero, Pablo |
author_role |
author |
author2 |
da Silva, Bianca Ferreira [UNESP] Stradiotto, Nelson Ramos [UNESP] Petrović, Mira Gros, Meritxell Gago-Ferrero, Pablo |
author2_role |
author author author author author |
dc.contributor.none.fl_str_mv |
Universidade Estadual Paulista (Unesp) Catalan Institution for Research and Advanced Studies (ICREA) Catalan Institute for Water Research (ICRA) University of Girona |
dc.contributor.author.fl_str_mv |
da Silva, Josiel José [UNESP] da Silva, Bianca Ferreira [UNESP] Stradiotto, Nelson Ramos [UNESP] Petrović, Mira Gros, Meritxell Gago-Ferrero, Pablo |
dc.subject.por.fl_str_mv |
Antibiotics NORMAN Digital Sample Freezing Platform Organic contaminants Soil amendment Suspect screening Vinasse fertigation |
topic |
Antibiotics NORMAN Digital Sample Freezing Platform Organic contaminants Soil amendment Suspect screening Vinasse fertigation |
description |
This work evaluated for the first time the sustainability of vinasse reuse as a fertilizer in sugarcane crops by assessing the occurrence of organic contaminants and their potential for dissemination to soils and groundwater in fertigated areas. A comprehensive screening of organic contaminants was performed in vinasse, soil and groundwater using target analysis, to investigate the occurrence of multiple-class antibiotics, in combination with suspect screening using NORMAN Digital Sample Freezing Platform. Even though antibiotics are used in the ethanol production process and were expected to be ubiquitous contaminants, they were not detected in any of the samples. Nevertheless, the HRMS-based wide-scope suspect screening (including >7800 substances such as pharmaceuticals, agrochemicals, preservatives and industrial chemicals) allowed the tentative identification of 56 compounds, mostly pesticides, food additives, industrial and naturally occurring substances. Results showed no overlap between the compounds detected in vinasse and environmental samples, suggesting that the pollutants found in soil and groundwater might come from alternative sources other than vinasse reuse. |
publishDate |
2021 |
dc.date.none.fl_str_mv |
2021-06-25T11:06:44Z 2021-06-25T11:06:44Z 2021-03-20 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.1016/j.scitotenv.2020.143237 Science of the Total Environment, v. 761. 1879-1026 0048-9697 http://hdl.handle.net/11449/208125 10.1016/j.scitotenv.2020.143237 2-s2.0-85095833287 |
url |
http://dx.doi.org/10.1016/j.scitotenv.2020.143237 http://hdl.handle.net/11449/208125 |
identifier_str_mv |
Science of the Total Environment, v. 761. 1879-1026 0048-9697 10.1016/j.scitotenv.2020.143237 2-s2.0-85095833287 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Science of the Total Environment |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1808129424848060416 |