Assessment of moisture adsorption and desorption isotherms, hysteresis phenomenon and thermodynamic analysis of habanero chili (Capsicum chinense) powder
Autor(a) principal: | |
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Data de Publicação: | 2023 |
Outros Autores: | , , , |
Tipo de documento: | Artigo |
Idioma: | eng |
Título da fonte: | Repositório Institucional da UNESP |
Texto Completo: | http://dx.doi.org/10.24275/rmiq/Alim3044 http://hdl.handle.net/11449/248736 |
Resumo: | Moisture adsorption and desorption isotherms (MSIs) of habanero chili powder were determined at dierent temperatures (20- 55 °C) and water activities (aw; 0.10-0.90) using the Dynamic Vapor Sorption (DVS) method and applying the conditions typically used during the storage, packaging, and drying of habanero chili. The MSIs were sigmoidal (Type II); the best fit models were GAB and Peleg. The sorption capacity of habanero chili powder decreased with increasing temperature and constant aw, becoming less hygroscopic. The hysteresis phenomenon was observed for all the temperatures evaluated. Thermodynamic properties were strongly dependent on the equilibrium moisture content (EMC). The net and total isosteric heat were higher for desorption than for adsorption, in both, they decreased as EMC increased. Sorption entrop and Gibbs free energy also decreased with rising EMC. Furthermore, the sorption surface area (SSA) decreased with increasing temperature. This information is essential to know the optimal storage and processing conditions to preserve the quality and prolong the shelf life of habanero chili powder. |
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Assessment of moisture adsorption and desorption isotherms, hysteresis phenomenon and thermodynamic analysis of habanero chili (Capsicum chinense) powderEvaluación de las isotermas de adsorción y desorción de humedad, fenómeno de hysteresis y análisis termodinámico del chile habanero (Capsicum chinense) en polvoDynamic vapor sorptionHabanero chili powderMathematical modelingMoisture sorption isothermsThermodynamic analysisMoisture adsorption and desorption isotherms (MSIs) of habanero chili powder were determined at dierent temperatures (20- 55 °C) and water activities (aw; 0.10-0.90) using the Dynamic Vapor Sorption (DVS) method and applying the conditions typically used during the storage, packaging, and drying of habanero chili. The MSIs were sigmoidal (Type II); the best fit models were GAB and Peleg. The sorption capacity of habanero chili powder decreased with increasing temperature and constant aw, becoming less hygroscopic. The hysteresis phenomenon was observed for all the temperatures evaluated. Thermodynamic properties were strongly dependent on the equilibrium moisture content (EMC). The net and total isosteric heat were higher for desorption than for adsorption, in both, they decreased as EMC increased. Sorption entrop and Gibbs free energy also decreased with rising EMC. Furthermore, the sorption surface area (SSA) decreased with increasing temperature. This information is essential to know the optimal storage and processing conditions to preserve the quality and prolong the shelf life of habanero chili powder.División de Estudios de Posgrado e Investigación Instituto Tecnológico de Orizaba, VeracruzDepartment of Food Engineering and Technology Sao Paulo State University-UNESP, Sao Jose do Rio PretoDepartment of Food Engineering and Technology Sao Paulo State University-UNESP, Sao Jose do Rio PretoInstituto Tecnológico de OrizabaUniversidade Estadual Paulista (UNESP)Luna-Flores, M.Peña-Juarez, M. G.Bello-Ramírez, A. M.Telis-Romero, J. [UNESP]Luna-Solano, G.2023-07-29T13:52:18Z2023-07-29T13:52:18Z2023-01-01info:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/articlehttp://dx.doi.org/10.24275/rmiq/Alim3044Revista Mexicana de Ingeniera Quimica, v. 22, n. 1, 2023.2395-84721665-2738http://hdl.handle.net/11449/24873610.24275/rmiq/Alim30442-s2.0-85153485944Scopusreponame:Repositório Institucional da UNESPinstname:Universidade Estadual Paulista (UNESP)instacron:UNESPengRevista Mexicana de Ingeniera Quimicainfo:eu-repo/semantics/openAccess2023-07-29T13:52:18Zoai:repositorio.unesp.br:11449/248736Repositório InstitucionalPUBhttp://repositorio.unesp.br/oai/requestopendoar:29462024-08-05T19:46:20.019864Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP)false |
dc.title.none.fl_str_mv |
Assessment of moisture adsorption and desorption isotherms, hysteresis phenomenon and thermodynamic analysis of habanero chili (Capsicum chinense) powder Evaluación de las isotermas de adsorción y desorción de humedad, fenómeno de hysteresis y análisis termodinámico del chile habanero (Capsicum chinense) en polvo |
title |
Assessment of moisture adsorption and desorption isotherms, hysteresis phenomenon and thermodynamic analysis of habanero chili (Capsicum chinense) powder |
spellingShingle |
Assessment of moisture adsorption and desorption isotherms, hysteresis phenomenon and thermodynamic analysis of habanero chili (Capsicum chinense) powder Luna-Flores, M. Dynamic vapor sorption Habanero chili powder Mathematical modeling Moisture sorption isotherms Thermodynamic analysis |
title_short |
Assessment of moisture adsorption and desorption isotherms, hysteresis phenomenon and thermodynamic analysis of habanero chili (Capsicum chinense) powder |
title_full |
Assessment of moisture adsorption and desorption isotherms, hysteresis phenomenon and thermodynamic analysis of habanero chili (Capsicum chinense) powder |
title_fullStr |
Assessment of moisture adsorption and desorption isotherms, hysteresis phenomenon and thermodynamic analysis of habanero chili (Capsicum chinense) powder |
title_full_unstemmed |
Assessment of moisture adsorption and desorption isotherms, hysteresis phenomenon and thermodynamic analysis of habanero chili (Capsicum chinense) powder |
title_sort |
Assessment of moisture adsorption and desorption isotherms, hysteresis phenomenon and thermodynamic analysis of habanero chili (Capsicum chinense) powder |
author |
Luna-Flores, M. |
author_facet |
Luna-Flores, M. Peña-Juarez, M. G. Bello-Ramírez, A. M. Telis-Romero, J. [UNESP] Luna-Solano, G. |
author_role |
author |
author2 |
Peña-Juarez, M. G. Bello-Ramírez, A. M. Telis-Romero, J. [UNESP] Luna-Solano, G. |
author2_role |
author author author author |
dc.contributor.none.fl_str_mv |
Instituto Tecnológico de Orizaba Universidade Estadual Paulista (UNESP) |
dc.contributor.author.fl_str_mv |
Luna-Flores, M. Peña-Juarez, M. G. Bello-Ramírez, A. M. Telis-Romero, J. [UNESP] Luna-Solano, G. |
dc.subject.por.fl_str_mv |
Dynamic vapor sorption Habanero chili powder Mathematical modeling Moisture sorption isotherms Thermodynamic analysis |
topic |
Dynamic vapor sorption Habanero chili powder Mathematical modeling Moisture sorption isotherms Thermodynamic analysis |
description |
Moisture adsorption and desorption isotherms (MSIs) of habanero chili powder were determined at dierent temperatures (20- 55 °C) and water activities (aw; 0.10-0.90) using the Dynamic Vapor Sorption (DVS) method and applying the conditions typically used during the storage, packaging, and drying of habanero chili. The MSIs were sigmoidal (Type II); the best fit models were GAB and Peleg. The sorption capacity of habanero chili powder decreased with increasing temperature and constant aw, becoming less hygroscopic. The hysteresis phenomenon was observed for all the temperatures evaluated. Thermodynamic properties were strongly dependent on the equilibrium moisture content (EMC). The net and total isosteric heat were higher for desorption than for adsorption, in both, they decreased as EMC increased. Sorption entrop and Gibbs free energy also decreased with rising EMC. Furthermore, the sorption surface area (SSA) decreased with increasing temperature. This information is essential to know the optimal storage and processing conditions to preserve the quality and prolong the shelf life of habanero chili powder. |
publishDate |
2023 |
dc.date.none.fl_str_mv |
2023-07-29T13:52:18Z 2023-07-29T13:52:18Z 2023-01-01 |
dc.type.status.fl_str_mv |
info:eu-repo/semantics/publishedVersion |
dc.type.driver.fl_str_mv |
info:eu-repo/semantics/article |
format |
article |
status_str |
publishedVersion |
dc.identifier.uri.fl_str_mv |
http://dx.doi.org/10.24275/rmiq/Alim3044 Revista Mexicana de Ingeniera Quimica, v. 22, n. 1, 2023. 2395-8472 1665-2738 http://hdl.handle.net/11449/248736 10.24275/rmiq/Alim3044 2-s2.0-85153485944 |
url |
http://dx.doi.org/10.24275/rmiq/Alim3044 http://hdl.handle.net/11449/248736 |
identifier_str_mv |
Revista Mexicana de Ingeniera Quimica, v. 22, n. 1, 2023. 2395-8472 1665-2738 10.24275/rmiq/Alim3044 2-s2.0-85153485944 |
dc.language.iso.fl_str_mv |
eng |
language |
eng |
dc.relation.none.fl_str_mv |
Revista Mexicana de Ingeniera Quimica |
dc.rights.driver.fl_str_mv |
info:eu-repo/semantics/openAccess |
eu_rights_str_mv |
openAccess |
dc.source.none.fl_str_mv |
Scopus reponame:Repositório Institucional da UNESP instname:Universidade Estadual Paulista (UNESP) instacron:UNESP |
instname_str |
Universidade Estadual Paulista (UNESP) |
instacron_str |
UNESP |
institution |
UNESP |
reponame_str |
Repositório Institucional da UNESP |
collection |
Repositório Institucional da UNESP |
repository.name.fl_str_mv |
Repositório Institucional da UNESP - Universidade Estadual Paulista (UNESP) |
repository.mail.fl_str_mv |
|
_version_ |
1808129116608659456 |