Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos

Detalhes bibliográficos
Autor(a) principal: SILVA, William Ramos da
Data de Publicação: 2016
Tipo de documento: Dissertação
Idioma: por
Título da fonte: Biblioteca Digital de Teses e Dissertações da UFRPE
Texto Completo: http://www.tede2.ufrpe.br:8080/tede2/handle/tede2/5363
Resumo: The generation of residues through mining is a potential risk of contamination of soil, water, plants and animals. For decades, the municipality of Santo Amaro da Purificação - BA has suffered the impacts caused by improper and inadequate release of thousands of tons of siderurgy slag contaminated mainly by Cd and Pb, and exposure of these contaminants to the population through the distribution of this material to landfills in squares, streets and homes. The city is now known for presenting the greatest human contamination by Pb in the world. In order to understand the impacts of residues in soil and the risk of human contamination from contaminated soil, this study investigated the phytoextraction by maize and castor as a technique for remediation of these soils and to evaluate the risk of human contamination by heavy metals added to the soil by waste. For this, an experiment was conducted in a greenhouse with the use of the two plant species and soil application of inducing agents Phytoextraction (NTA and citric acid). After the cultivation, they evaluated the levels of As, Cd, Pb and Zn in soil and plant to evaluate the potential remediation technique. Fractionation of metals in the soil and bioaccessibility tests to assess the risk of contamination were also performed. The application of chelating agents citric acid and NTA and increased absorption of heavy metals by maize and castor. Despite the removal of metals by application of citric acid is smaller, this is more suitable due to its higher degradability and assist in inhibiting the phytotoxicity of the metals. Corn showed better phytoextraction ability to As, Cd, Pb and Zn in the study. The castor, despite having high concentrations of metals translocated, presented accumulation in roots, can be used as phytoextabiletion plant and generating economic benefits for the production of non-edible vegetable oil. The presence of metal contaminants from the ground indiscriminately in the area of the former COBRAC presents a high risk of contamination of humans through exposure of metals.
id URPE_a9d99170b85477c8a9149b8aaf388f1a
oai_identifier_str oai:tede2:tede2/5363
network_acronym_str URPE
network_name_str Biblioteca Digital de Teses e Dissertações da UFRPE
repository_id_str
spelling NASCIMENTO, Clístenes Williams Araújo doBIONDI, Caroline MirandaFRACETTO, Felipe José Curyhttp://lattes.cnpq.br/5033735462082389SILVA, William Ramos da2016-08-17T11:10:50Z2016-07-29SILVA, William Ramos da. Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos. 2016. 58 f. Dissertação (Programa de Pós-Graduação em Ciência do Solo) - Universidade Federal Rural de Pernambuco, Recife.http://www.tede2.ufrpe.br:8080/tede2/handle/tede2/5363The generation of residues through mining is a potential risk of contamination of soil, water, plants and animals. For decades, the municipality of Santo Amaro da Purificação - BA has suffered the impacts caused by improper and inadequate release of thousands of tons of siderurgy slag contaminated mainly by Cd and Pb, and exposure of these contaminants to the population through the distribution of this material to landfills in squares, streets and homes. The city is now known for presenting the greatest human contamination by Pb in the world. In order to understand the impacts of residues in soil and the risk of human contamination from contaminated soil, this study investigated the phytoextraction by maize and castor as a technique for remediation of these soils and to evaluate the risk of human contamination by heavy metals added to the soil by waste. For this, an experiment was conducted in a greenhouse with the use of the two plant species and soil application of inducing agents Phytoextraction (NTA and citric acid). After the cultivation, they evaluated the levels of As, Cd, Pb and Zn in soil and plant to evaluate the potential remediation technique. Fractionation of metals in the soil and bioaccessibility tests to assess the risk of contamination were also performed. The application of chelating agents citric acid and NTA and increased absorption of heavy metals by maize and castor. Despite the removal of metals by application of citric acid is smaller, this is more suitable due to its higher degradability and assist in inhibiting the phytotoxicity of the metals. Corn showed better phytoextraction ability to As, Cd, Pb and Zn in the study. The castor, despite having high concentrations of metals translocated, presented accumulation in roots, can be used as phytoextabiletion plant and generating economic benefits for the production of non-edible vegetable oil. The presence of metal contaminants from the ground indiscriminately in the area of the former COBRAC presents a high risk of contamination of humans through exposure of metals.A geração de resíduos através da mineração representa um risco potencial de contaminação do solo, recursos hídricos, plantas e animais. Durante décadas, o município de Santo Amaro da Purificação – BA tem sofrido os impactos causados pela liberação indevida e inadequada de milhares de toneladas de escória de siderurgia, contaminada principalmente por Cd e Pb, e pela exposição destes contaminantes à população através da distribuição desse material para aterros em praças, ruas e residências. A cidade hoje é conhecida por apresentar a maior contaminação humana por Pb no mundo. Com a intenção de entender os impactos causados pelos resíduos nos solos, bem como os riscos de contaminação humana por solo contaminado, o presente trabalho objetivou estudar a fitoextração por milho e mamona como uma técnica para remediação desses solos e avaliar o risco de contaminação humana pelos metais pesados adicionados ao solo pelos resíduos. Para isto, foi realizado um experimento em casa de vegetação com a utilização das duas espécies vegetais e aplicação ao solo de agentes indutores da fitoextração (ácido cítrico e NTA). Após o período de cultivo, foram avaliados os teores de As, Cd, Pb e Zn no solo e na planta para avaliar o potencial da técnica de remediação. Fracionamento dos metais no solo e testes de bioacessibilidade para avaliar o risco de contaminação foram também efetuados. A aplicação dos agentes quelantes ácido cítrico e NTA aumentou a absorção de metais pesados por milho e mamona. Apesar da remoção dos metais com aplicação de ácido cítrico ser menor, este é mais indicado por apresentar maior degradabilidade e auxiliar na inibição da fitotoxicidade dos metais. O milho apresentou melhor capacidade fitoextratora para As, Cd, Pb e Zn no solo em estudo. A mamona, apesar de não ter translocado concentrações altas dos metais, apresentou acúmulo nas raízes, podendo ser utilizada como planta fitoestabilizadora e geradora de benefícios econômicos pela produção de óleo vegetal não comestível. A presença de metais contaminantes do solo de forma indiscriminada na área da antiga COBRAC apresenta risco elevado de contaminação dos seres humanos através da exposição dos metais.Submitted by (lucia.rodrigues@ufrpe.br) on 2016-08-17T11:10:50Z No. of bitstreams: 1 William Ramos da Silva.pdf: 1949081 bytes, checksum: c61378bed7319d565cc47084de59c025 (MD5)Made available in DSpace on 2016-08-17T11:10:50Z (GMT). No. of bitstreams: 1 William Ramos da Silva.pdf: 1949081 bytes, checksum: c61378bed7319d565cc47084de59c025 (MD5) Previous issue date: 2016-07-29Conselho Nacional de Pesquisa e Desenvolvimento Científico e Tecnológico - CNPqapplication/pdfporUniversidade Federal Rural de PernambucoPrograma de Pós-Graduação em Ciência do SoloUFRPEBrasilDepartamento de AgronomiaFitoextraçãoContaminação do soloMetal pesadoSoilContaminationHeavy metalsChelating agentsAGRONOMIA::CIENCIA DO SOLOFitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicosinfo:eu-repo/semantics/publishedVersioninfo:eu-repo/semantics/masterThesis8551734419043507650600600600600-6800553879972229205-5919840527232375671-2555911436985713659info:eu-repo/semantics/openAccessreponame:Biblioteca Digital de Teses e Dissertações da UFRPEinstname:Universidade Federal Rural de Pernambuco (UFRPE)instacron:UFRPELICENSElicense.txtlicense.txttext/plain; charset=utf-82165http://www.tede2.ufrpe.br:8080/tede2/bitstream/tede2/5363/1/license.txtbd3efa91386c1718a7f26a329fdcb468MD51ORIGINALWilliam Ramos da Silva.pdfWilliam Ramos da Silva.pdfapplication/pdf1949081http://www.tede2.ufrpe.br:8080/tede2/bitstream/tede2/5363/2/William+Ramos+da+Silva.pdfc61378bed7319d565cc47084de59c025MD52tede2/53632019-07-12 10:08:22.488oai:tede2: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Biblioteca Digital de Teses e Dissertaçõeshttp://www.tede2.ufrpe.br:8080/tede/PUBhttp://www.tede2.ufrpe.br:8080/oai/requestbdtd@ufrpe.br ||bdtd@ufrpe.bropendoar:2024-05-28T12:32:57.392738Biblioteca Digital de Teses e Dissertações da UFRPE - Universidade Federal Rural de Pernambuco (UFRPE)false
dc.title.por.fl_str_mv Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos
title Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos
spellingShingle Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos
SILVA, William Ramos da
Fitoextração
Contaminação do solo
Metal pesado
Soil
Contamination
Heavy metals
Chelating agents
AGRONOMIA::CIENCIA DO SOLO
title_short Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos
title_full Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos
title_fullStr Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos
title_full_unstemmed Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos
title_sort Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos
author SILVA, William Ramos da
author_facet SILVA, William Ramos da
author_role author
dc.contributor.advisor1.fl_str_mv NASCIMENTO, Clístenes Williams Araújo do
dc.contributor.referee1.fl_str_mv BIONDI, Caroline Miranda
dc.contributor.referee2.fl_str_mv FRACETTO, Felipe José Cury
dc.contributor.authorLattes.fl_str_mv http://lattes.cnpq.br/5033735462082389
dc.contributor.author.fl_str_mv SILVA, William Ramos da
contributor_str_mv NASCIMENTO, Clístenes Williams Araújo do
BIONDI, Caroline Miranda
FRACETTO, Felipe José Cury
dc.subject.por.fl_str_mv Fitoextração
Contaminação do solo
Metal pesado
topic Fitoextração
Contaminação do solo
Metal pesado
Soil
Contamination
Heavy metals
Chelating agents
AGRONOMIA::CIENCIA DO SOLO
dc.subject.eng.fl_str_mv Soil
Contamination
Heavy metals
Chelating agents
dc.subject.cnpq.fl_str_mv AGRONOMIA::CIENCIA DO SOLO
description The generation of residues through mining is a potential risk of contamination of soil, water, plants and animals. For decades, the municipality of Santo Amaro da Purificação - BA has suffered the impacts caused by improper and inadequate release of thousands of tons of siderurgy slag contaminated mainly by Cd and Pb, and exposure of these contaminants to the population through the distribution of this material to landfills in squares, streets and homes. The city is now known for presenting the greatest human contamination by Pb in the world. In order to understand the impacts of residues in soil and the risk of human contamination from contaminated soil, this study investigated the phytoextraction by maize and castor as a technique for remediation of these soils and to evaluate the risk of human contamination by heavy metals added to the soil by waste. For this, an experiment was conducted in a greenhouse with the use of the two plant species and soil application of inducing agents Phytoextraction (NTA and citric acid). After the cultivation, they evaluated the levels of As, Cd, Pb and Zn in soil and plant to evaluate the potential remediation technique. Fractionation of metals in the soil and bioaccessibility tests to assess the risk of contamination were also performed. The application of chelating agents citric acid and NTA and increased absorption of heavy metals by maize and castor. Despite the removal of metals by application of citric acid is smaller, this is more suitable due to its higher degradability and assist in inhibiting the phytotoxicity of the metals. Corn showed better phytoextraction ability to As, Cd, Pb and Zn in the study. The castor, despite having high concentrations of metals translocated, presented accumulation in roots, can be used as phytoextabiletion plant and generating economic benefits for the production of non-edible vegetable oil. The presence of metal contaminants from the ground indiscriminately in the area of the former COBRAC presents a high risk of contamination of humans through exposure of metals.
publishDate 2016
dc.date.accessioned.fl_str_mv 2016-08-17T11:10:50Z
dc.date.issued.fl_str_mv 2016-07-29
dc.type.status.fl_str_mv info:eu-repo/semantics/publishedVersion
dc.type.driver.fl_str_mv info:eu-repo/semantics/masterThesis
format masterThesis
status_str publishedVersion
dc.identifier.citation.fl_str_mv SILVA, William Ramos da. Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos. 2016. 58 f. Dissertação (Programa de Pós-Graduação em Ciência do Solo) - Universidade Federal Rural de Pernambuco, Recife.
dc.identifier.uri.fl_str_mv http://www.tede2.ufrpe.br:8080/tede2/handle/tede2/5363
identifier_str_mv SILVA, William Ramos da. Fitoextração e Bioacessibilidade de As, Cd, Pb E Zn em solos contaminados por resíduos metalúrgicos. 2016. 58 f. Dissertação (Programa de Pós-Graduação em Ciência do Solo) - Universidade Federal Rural de Pernambuco, Recife.
url http://www.tede2.ufrpe.br:8080/tede2/handle/tede2/5363
dc.language.iso.fl_str_mv por
language por
dc.relation.program.fl_str_mv 8551734419043507650
dc.relation.confidence.fl_str_mv 600
600
600
600
dc.relation.department.fl_str_mv -6800553879972229205
dc.relation.cnpq.fl_str_mv -5919840527232375671
dc.relation.sponsorship.fl_str_mv -2555911436985713659
dc.rights.driver.fl_str_mv info:eu-repo/semantics/openAccess
eu_rights_str_mv openAccess
dc.format.none.fl_str_mv application/pdf
dc.publisher.none.fl_str_mv Universidade Federal Rural de Pernambuco
dc.publisher.program.fl_str_mv Programa de Pós-Graduação em Ciência do Solo
dc.publisher.initials.fl_str_mv UFRPE
dc.publisher.country.fl_str_mv Brasil
dc.publisher.department.fl_str_mv Departamento de Agronomia
publisher.none.fl_str_mv Universidade Federal Rural de Pernambuco
dc.source.none.fl_str_mv reponame:Biblioteca Digital de Teses e Dissertações da UFRPE
instname:Universidade Federal Rural de Pernambuco (UFRPE)
instacron:UFRPE
instname_str Universidade Federal Rural de Pernambuco (UFRPE)
instacron_str UFRPE
institution UFRPE
reponame_str Biblioteca Digital de Teses e Dissertações da UFRPE
collection Biblioteca Digital de Teses e Dissertações da UFRPE
bitstream.url.fl_str_mv http://www.tede2.ufrpe.br:8080/tede2/bitstream/tede2/5363/1/license.txt
http://www.tede2.ufrpe.br:8080/tede2/bitstream/tede2/5363/2/William+Ramos+da+Silva.pdf
bitstream.checksum.fl_str_mv bd3efa91386c1718a7f26a329fdcb468
c61378bed7319d565cc47084de59c025
bitstream.checksumAlgorithm.fl_str_mv MD5
MD5
repository.name.fl_str_mv Biblioteca Digital de Teses e Dissertações da UFRPE - Universidade Federal Rural de Pernambuco (UFRPE)
repository.mail.fl_str_mv bdtd@ufrpe.br ||bdtd@ufrpe.br
_version_ 1810102225057349632